• 제목/요약/키워드: differential reactor

검색결과 99건 처리시간 0.022초

Differential column reactor에 있어서 고정화페니실린 아미다제의 반응속도론에 관한 연구 (Kinetic Study on the Immobilized Penicillin Amidase in a Differential Column Reactor)

  • Park, Jong-Moon;Park, Cha-Yong;Seong, Baik-Lin;Han, Moon-Hi
    • 한국미생물·생명공학회지
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    • 제9권3호
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    • pp.165-171
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    • 1981
  • E. coil ATCC 9637의 균체를 젤라틴과 DEAE-cellulose의 혼합 성형 후 글루트알데히드 가교법으로 제조론 고정화 penicillin amidase의 differential column reactor에서의 반응속도를 논의하였다. 이러한 반응조의 최적 조작조건은 효소충진량 1g, 기질농도30mM(0.1M 인산완충액, pH8.0), 유출속도 4 $m\ell$/min, 온도 4$0^{\circ}C$이었다. 이 최적조건에서 고정화효소의 일반적인 성질을 조사하였다. Km 상수는 4.8mM 이었고 specific activity 308 units/g 고정화 효소이 었다. 또한 고정화효소에서는 기질에 의한 효소반응 저해효과가 보이지 않았다. 이러한 differential column reactor에서는 column내에서의 pH 감소효과 및 외부 화산효과가 없어지기 때문에 이러한 외부적 영향을 받지 않는 고정화효소의 반응 속도론적 연구에 적합함을 알았다.

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Kinetic Analysis and Mathematical Modeling of Cr(VI) Removal in a Differential Reactor Packed with Ecklonia Biomass

  • Park, Dong-Hee;Yun, Yeoung-Sang;Lim, Seong-Rin;Park, Jong-Moon
    • Journal of Microbiology and Biotechnology
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    • 제16권11호
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    • pp.1720-1727
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    • 2006
  • To set up a kinetic model that can provide a theoretical basis for developing a new mathematical model of the Cr(VI) biosorption column using brown seaweed Ecklonia biomass, a differential reactor system was used in this study. Based on the fact that the removal process followed a redox reaction between Cr(VI) and the biomass, with no dispersion effect in the differential reactor, a new mathematical model was proposed to describe the removal of Cr(VI) from a liquid stream passing through the differential reactor. The reduction model of Cr(VI) by the differential reactor was zero order with respect to influent Cr(IlI) concentration, and first order with respect to both the biomass and influent Cr(VI) concentrations. The developed model described well the dynamics of Cr(VI) in the effluent. In conclusion, the developed model may be used for the design and performance prediction of the biosorption column process for Cr(VI) detoxification.

FURTHER EVALUATION OF A STOCHASTIC MODEL APPLIED TO MONOENERGETIC SPACE-TIME NUCLEAR REACTOR KINETICS

  • Ha, Pham Nhu Viet;Kim, Jong-Kyung
    • Nuclear Engineering and Technology
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    • 제43권6호
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    • pp.523-530
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    • 2011
  • In a previous study, the stochastic space-dependent kinetics model (SSKM) based on the forward stochastic model in stochastic kinetics theory and the Ito stochastic differential equations was proposed for treating monoenergetic space-time nuclear reactor kinetics in one dimension. The SSKM was tested against analog Monte Carlo calculations, however, for exemplary cases of homogeneous slab reactors with only one delayed-neutron precursor group. In this paper, the SSKM is improved and evaluated with more realistic and complicated cases regarding several delayed-neutron precursor groups and heterogeneous slab reactors in which the extraneous source or reactivity can be introduced locally. Furthermore, the source level and the initial conditions will also be adjusted to investigate the trends in the variances of the neutron population and fission product levels across the reactor. The results indicate that the improved SSKM is in good agreement with the Monte Carlo method and show how the variances in population dynamics can be controlled.

Experimental Determination of Differential Fast Neutron Spectra in a Reactor using Threshold Detectors

  • Kim, Dong-Hoon
    • Nuclear Engineering and Technology
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    • 제4권4호
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    • pp.280-293
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    • 1972
  • 원자로(TRIGA MARK-II)노심의 특정위치에서 0.5 Mev 이상의 고속중성자 스펙트럼을 발단검출기(Threshold detector)를 사용하여 실험적으로 측정하였다. 발단검출기의 실험적인 방사화자료로서 결정되는 일련의 적분방정식에 대한 근사해를 얻기 위하여 최소자승법의 개념을 이용한 급수전개법을 사용하였다. 상이한 가중함수 (weighting function)를 사용하므로서 해답에 미치는 영향을 각측정에서 분석 검토하였다. 이방법의 사용에 관련되는 수치계산을 수행하기 위하여 UNIVAC 1106전자계산기를 위한 계산코드를 준비하였다. 본 연구에서 얻은 미분적 고속중성자 스펙트럼은 독립적으로 다군 수송이론에 의하여 얻은 결과와 잘 일치하였다.

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Optimal control of a tubular reactor using the distributed-parameter method and the numerical method of lines

  • Choe, Young-Soon;Yang, Dae-Ryook;Lee, In-Beum;Chang, Kun-Soo
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1993년도 한국자동제어학술회의논문집(국제학술편); Seoul National University, Seoul; 20-22 Oct. 1993
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    • pp.312-315
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    • 1993
  • Optimal control theories based on the maximum principles have been evolved and applied to distributed parameter systems(DPSs) represented by partial differential equations (PDEs) and integral equations (IEs). This paper intends to show that an optimal control of a tubular reactor described by a one-dimensional partial differential equation was obtained using the distributed parameter control method for parabolic PDEs. In develping an algorithm which implements the calculation, the method of lines (MOL) was adopted through using a package called the DSS/2. For the tubular reactor system chosen for this paper, the optimal control method based on PDEs with the numerical MOL showed to be more efficient than the one based on IEs.

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Numerical Simulations of Subcritical Reactor Kinetics in Thermal Hydraulic Transient Phases

  • J. Yoo;Park, W. S.
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1998년도 춘계학술발표회논문집(1)
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    • pp.149-154
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    • 1998
  • A subcritical reactor driven by a linear proton accelerator has been considered as a nuclear waste incinerator at Korea Atomic Energy Research Institute(KAERI). Since the multiplication factor of a subcritical reactor is less than unity, to compensate exponentially decreasing fission neutrons from spallation reactions are essentially required for operating the reactor in its steady state. furthermore, the profile of accelerator beam currents is very important in controlling a subcritical reactor, because the reactor power varies in accordance of the profile of external neutrons. We have developed a code system to find numerical solutions of reactor kinetics equations, which are the simplest dynamic model for controlling reactors. In a due course of our previous numerical study of point kinetics equations for critical reactors, however, we learned that the same code system can be used in studying dynamic behavior of the subcritical reactor. Our major motivation of this paper is to investigate responses of subcritical reactors for small changes in thermal hydraulic parameters. Building a thermal hydraulic model for the subcritical reactor dynamics, we performed numerical simulations for dynamic responses of the reactor based on point kinetics equations with a source term. Linearizing a set of coupled differential equations for reactor responses, we focus our research interest on dynamic responses of the reactor to variations of the thermal hydraulic parameters in transient phases.

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충전층 메탄화 반응기의 수학적 모델 및 전산 수치해석 (Mathematical Model and Numerical Analysis for Packed Bed Methanation Reactors)

  • 지준화
    • 한국수소및신에너지학회논문집
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    • 제26권3호
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    • pp.260-270
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    • 2015
  • One-dimensional packed bed reactor model accounting for interfacial and intra-particle gradients was developed and based on it numerical analyses were performed to investigate the dynamic behavior of a commercial scale methanation reactor. Methanation reaction was almost complete near the reactor inlet and gases with equilibrated composition were discharged from the reactor. Both the intra-particle temperature gradient and differential surface temperature rise were found to be severe near the reactor inlet. To reduce the possible degradation or fracture of catalyst particles and prevent local overheating on the catalyst, addition of inert material can be an effective way.

INVESTIGATION OF REACTOR CONDITION MONITORING AND SINGULARITY DETECTION VIA WAVELET TRANSFORM AND DE-NOISING

  • Kim, Ok-Joo;Cho, Nan-Zin;Park, Chang-Je;Park, Moon-Ghu
    • Nuclear Engineering and Technology
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    • 제39권3호
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    • pp.221-230
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    • 2007
  • Wavelet theory was applied to detect a singularity in a reactor power signal. Compared to Fourier transform, wavelet transform has localization properties in space and frequency. Therefore, using wavelet transform after de-noising, singular points can easily be found. To test this theory, reactor power signals were generated using the HANARO(a Korean multi-purpose research reactor) dynamics model consisting of 39 nonlinear differential equations contaminated with Gaussian noise. Wavelet transform decomposition and de-noising procedures were applied to these signals. It was possible to detect singular events such as a sudden reactivity change and abrupt intrinsic property changes. Thus, this method could be profitably utilized in a real-time system for automatic event recognition(e.g., reactor condition monitoring).

외삽 차동형 탐촉자를 사용한 연구로용 핵연료봉의 와전류탐상 (Eddy Current Testing using Encircling Differential Probe for Research Reactor Fuel Rods)

  • 이윤상;김창규
    • 비파괴검사학회지
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    • 제21권5호
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    • pp.561-564
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    • 2001
  • 연구로인 하나로의 핵연료봉은 제조 시 피복층에 품질 관리 절차에서 규정한 크기 이상의 결함이 없도록 와전류탐상 검사를 하도록 되어 있다. 와전류탐상검사 절차를 수립하기 위하여 외삽 차동형 와전류탐촉자 및 표준시험편을 제작하였다. 임피던스 분석기를 사용하여 제작된 탐촉자에 대한 임피던스값을 측정하여 검사주파수 영역에서 최대감도를 얻도록 제작되었는지를 조사하였고, 이 탐촉자 및 MIZ-40A 와전류탐상기를 사용하여, 요구되는 결함 크기를 검출할 수 있는가를 조사하였다. 그 결과 이 탐촉자를 사용하여 길이 2mm 피복 두께 대비 깊이 10%인 인공 노치를 검출할 수 있었으며, 연구로용 핵연료봉의 제조 시 피복층에 존재하는 결함을 성공적으로 검사할 수 있었다.

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A FLOW AND PRESSURE DISTRIBUTION OF APR+ REACTOR UNDER THE 4-PUMP RUNNING CONDITIONS WITH A BALANCED FLOW RATE

  • Euh, D.J.;Kim, K.H.;Youn, Y.J.;Bae, J.H.;Chu, I.C.;Kim, J.T.;Kang, H.S.;Choi, H.S.;Lee, S.T.;Kwon, T.S.
    • Nuclear Engineering and Technology
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    • 제44권7호
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    • pp.735-744
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    • 2012
  • In order to quantify the flow distribution characteristics of APR+ reactor, a test was performed on a test facility, ACOP ($\underline{A}$PR+ $\underline{C}$ore Flow & $\underline{P}$ressure Test Facility), having a length scale of 1/5 referring to the prototype plant. The major parameters are core inlet flow and outlet pressure distribution and sectional pressure drops along the major flow path inside reactor vessel. To preserve the flow characteristics of prototype plant, the test facility was designed based on a preservation of major flow path geometry. An Euler number is considered as primary dimensionless parameter, which is conserved with a 1/40.9 of Reynolds number scaling ratio. ACOP simplifies each fuel assembly into a hydraulic simulator having the same axial flow resistance and lateral cross flow characteristics. In order to supply boundary condition to estimate thermal margins of the reactor, the distribution of inlet core flow and core exit pressure were measured in each of 257 fuel assembly simulators. In total, 584 points of static pressure and differential pressures were measured with a limited number of differential pressure transmitters by developing a sequential operation system of valves. In the current study, reactor flow characteristics under the balanced four-cold leg flow conditions at each of the cold legs were quantified, which is a part of the test matrix composing the APR+ flow distribution test program. The final identification of the reactor flow distribution was obtained by ensemble averaging 15 independent test data. The details of the design of the test facility, experiment, and data analysis are included in the current paper.