• Title/Summary/Keyword: differential permeability

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Magneto-thermo-elastic response of a rotating functionally graded cylinder

  • Hosseini, Mohammad;Dini, Ali
    • Structural Engineering and Mechanics
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    • v.56 no.1
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    • pp.137-156
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    • 2015
  • In this paper, an analytical solution of displacement, strain and stress field for rotating thick-walled cylinder made of functionally graded material subjected to the uniform external magnetic field and thermal field in plane strain state has been studied. Stress, strain and displacement field as a function of radial coordinates considering magneto-thermo-elasticity are derived analytically. According to the Maxwell electro-dynamic equations, Lorentz force in term of displacement is obtained in cylindrical coordinates. Also, symmetric temperature distribution along the thickness of hollow cylinder is obtained by solving Fourier heat transfer equation in cylindrical coordinates. Using equation of equilibrium and thermo-mechanical constitutive equations associated with Lorentz force, a second-order inhomogeneous differential equation in term of displacement is obtained and will be solved analytically. Except Poisson's ratio, other mechanical properties such as elasticity modulus, density, magnetic permeability coefficient, heat conduction coefficient and thermal expansion coefficient are assumed to vary through the thickness according to a power law. In results analysis, non-homogeneity parameter has been chosen arbitrary and inner and outer surface of cylinder are assumed to be rich metal and rich ceramic, respectively. The effect of rotation, thermal, magnetic field and non-homogeneity parameter of functionally graded material which indicates percentages of cylinder's constituents are studied on displacement, Von Mises equivalent stress and Von Mises equivalent strain fields.

The Experimental Study on the Progress of Concrete Carbonation According to the Service Life (콘크리트의 사용연한에 따른 중성화의 진행에 관한 실험적 연구)

  • Lee, Joon-Gu;Park, Kwang-Soo;Shin, Su-Gyun;Kim, Kwan-Ho;Park, Mi-Hyun
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2001.10a
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    • pp.123-128
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    • 2001
  • This study was performed to find out variation of carbonation progress of agricultural hydraulic concrete structures along the used years with using Thermo Gravimetric analysis/Differential Thermal Analysis(TG/DTA) and Indicator(phenolphthalein). In this study some conclusions such as follows were derived. Firstly, The result that the age of structures and the content of $Ca(OH)_{2}\;and\;CaCO_{3}$ in concrete have proportional relationships was found in the method of TG/DTA. This relational functions could be used to estimate remain lifetime of structures, obtaining the limits of the content of $CaCO_{3}$ in concrete which reinforcement corrosion could be occurred with breaking protection cover of alkalinity. Second, if the result of strength, voids, permeability characteristics could be combined with this relational function this may be able to be used as a new more accurate assessment technique for the quality of concrete than current usual methods. Third, environmental affect could be more superintendent for concrete carbonation than the age of agricultural hydration structures. Forth, It is difficult to estimate the used year of agricultural hydraulic concrete structures with the carbonation depth measured by indicator method. Finally, the accuracy of this relational function could be decided to be upgraded with continue analysis for more structures.

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Hydrogen Permeation Properties of Ni-based Amorphous Alloys Membrane (Ni-based 비정질 합금막의 수소투과 특성)

  • Seok, Song;Lee, Dock-Young;Kim, Yoon-Bae
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.1
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    • pp.35-40
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    • 2008
  • Ni-based amorphous alloy ribbon was prepared by a single-roller melt-spinning technique. Palladium coating was found to enhance significantly the absorption/desorption behavior of hydrogen in amorphous alloy. The hydrogen permeability of a Pd-coated $(Ni_{60}Nb_{40}){_{100-X}}$TaX(x=5, 10) amorphous alloy was examined in the temperature range of $623{\sim}773K$, comparable with those of $Pd_{60}-Cu_{40}$ alloys. The permeated hydrogen flux was increased with increasing the temperature and the difference of hydrogen pressure between the feed side and permeates side of the membrane. The Ni-based amorphous alloys were characterized by X-ray diffractometry(XRD) and differential scanning calorimetry(DSC). The morphology of surface and roughness was observed by using scanning electron microscopy(SEM) and atomic force microscopy(AFM).

Magnetic Properties of $(\textrm{Fe}_{1-x}\textrm{Co}_{x})_{89}\textrm{Zr}_{11}$ Amorphous Films(II) ($(\textrm{Fe}_{1-x}\textrm{Co}_{x})_{89}\textrm{Zr}_{11}$ 비정질 자성박막의 자기특성(II))

  • Kim, Sang-Won
    • Korean Journal of Materials Research
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    • v.9 no.8
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    • pp.831-836
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    • 1999
  • Magnetic properties of (Fe(sub)1-xCo(sub)x)(sub)89Zr11 amorphous films fabricated by RF sputtering method have been investigated as a function of Co content x. By means of two step field annealing at 190~20$0^{\circ}C$ for 10 minutes in the magnetic field of 130 Oe, the film with x=0.4 among the samples shows the superior soft magnetic properties in spite of showing the high magnetostriction. For example, the obtained properties of coercivity and differential permeability measured in an exciting field of 10 mOe at the frequency of 8.7 MHz are 0.25 Oe and 280, respectively. It is confirmed that such behavior is due to the variation of magnetic anisotropies caused by a optimal compressive stress within the film.

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Organic-inorganic Nano Composite Membranes of Sulfonated Poly(Ether Sulfone-ketone) Copolymer and $SiO_2$ for Fuel Cell Application

  • Lee, Dong-Hoon;Park, Hye-Suk;Seo, Dong-Wan;Kim, Whan-Gi
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.487-488
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    • 2006
  • Novel bisphenol-based wholly aromatic poly(ether sulfone-ketone) copolymer containing pendant sulfonate groups were prepared by direct aromatic nucleophilic substitution polycondensation of 4,4-difluorobenzophenone, 2,2'-disodiumsulfonyl-4,4'-fluorophenylsulfone (40mole% of bisphenol A) and bisphenol A. Polymerization proceeded quantitatively to high molecular weight in N-methyl-2-pyrrolidinone at $180^{\circ}C$. Organic-inorganic composite membranes were obtained by mixing organic polymers with hydrophilic $SiO_2$ (ca. 20nm) obtained by sol-gel process. The polymer and a series of composite membranes were studied by FT-IR, $^1HNMR$, differential scanning calorimetry (DSC) and thermal stability. The proton conductivity as a function of temperature decreased as $SiO_2$ content increased, but methanol permeability decreased. The nano composite membranes were found to posse all requisite properties; Ion exchange capacity (1.2meq./g), glass transition temperatures $(164-183\;^{\circ}C)$, and low affinity towards methanol $(4.63-1.08{\times}10^{-7}\;cm^2/S)$.

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Magnetic Properties of $({Fe_{0.6}}{Co_{0.4}})_{89}$${Zr_{11}$/$({Fe_{1-x}}{Co_x})$$Zr_{11}$(x=0, 0.6, 0.9)Amorphous Multilayers ($({Fe_{0.6}}{Co_{0.4}})_{89}$${Zr_{11}$/$({Fe_{1-x}}{Co_x})$$Zr_{11}$(x=0, 0.6, 0.9)비정질 다층박막의 자기특성)

  • Kim, Sang-Won
    • Korean Journal of Materials Research
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    • v.10 no.10
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    • pp.709-714
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    • 2000
  • SAW 소자에 응용 가능한 자성박막재의 개발을 목적으로 RF 스퍼터링법으로 증착한 (Fe(sub)0.6Co(sub)0.4)(sub)89Zr(sub)11/Fe(sub)1-xCo(sub)x)Zr(sub)11(x=0, 0.6, 0.9)<원문잠조> 비정질 다층박막의 자기특성을 조사하였다. 수직자기장중열처리를 행하였을 때 상온에서 비자성 Fe(sub)89Zr(sub)11 층의 삽입에서만 다층박막화의 효과가 나타났다. 일 예로 (Fe(sub)0.6Co(sub)0.4)(sub)89Zr(sub)11(30${\AA}$)/Fe(sub)89-Zr(sub)11(40${\AA}$)<원문참조> 박막시편에 1kHz, 50 mOe의 여기자기장으로 평가된 최대 미분투자율${\mu}$(sub)d.max는 단층막의 750에서 1650으로 2배 이상 증가, 구동 바이어스자기장 Hw는 20 Oe에서 6Oe로 3배 이하로 감소하는 양호한 특성이 얻어졌다. 그러나 다른 중용 특성인 자왜는 34% 정도 감소하는 것으로 추정되었다.

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Finite Element Analysis of the Effects of Process and Material Parameters on the LVDT Output Characteristics (LVDT의 출력 특성에 미치는 공정 및 재료 변수의 영향에 관한 유한요소해석)

  • Yang, Young-Soo;Bae, Kang-Yul
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.9
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    • pp.11-19
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    • 2021
  • Linear variable differential transformer (LVDT) is a displacement sensor and is commonly used owing to its wide measurement range, excellent linearity, high sensitivity, and precision. To improve the output characteristics of LVDT, a few studies have been conducted to analyze the output using a theoretical method or a finite element method. However, the material properties of the core and the electromagnetic force acting on the core were not considered in the previous studies. In this study, a finite element analysis model was proposed considering the characteristics of the LVDT composed of coils, core, magnetic shell and electric circuit, and the core displacement. Using the proposed model, changes in sensitivity and linear region of LVDT according to changes in process and material parameters were analyzed. The outputs of the LVDT model were compared with those of the theoretical analysis, and then, the proposed analysis model was validated. When the electrical conductivity of the core was high and the relative magnetic permeability was low, the decrease in sensitivity was large. Additionally, an increase in the frequency of the power led to further decrease in sensitivity. The electromagnetic force applied on the core increased as the voltage increased, the frequency decreased, and the core displacement increased.

Decrease in hydrogen crossover through membrane of polymer electrolyte membrane fuel cells at the initial stages of an acceleration stress test

  • Hwang, Byung Chan;Oh, So Hyeong;Lee, Moo Seok;Lee, Dong Hoon;Park, Kwon Pil
    • Korean Journal of Chemical Engineering
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    • v.35 no.11
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    • pp.2290-2295
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    • 2018
  • An acceleration stress test (AST) was performed to evaluate the durability of a polymer membrane in a polymer electrolyte membrane fuel cell (PEMFC) for 500 hours. Previous studies have shown that hydrogen crossover measured by linear sweep voltammetry (LSV) increases when the polymer membrane deteriorates in the AST process. On the other hand, hydrogen crossover of the membrane often decreases in the early stages of the AST test. To investigate the cause of this phenomenon, we analyzed the MEA operated for 50 hours using the AST method (OCV, RH 30% and $90^{\circ}C$). Cyclic voltammetry and transmission electron showed that the electrochemical surface area (ECSA) decreased due to the growth of electrode catalyst particles and that the hydrogen crossover current density measured by LSV could be reduced. Fourier transform infrared spectroscopy and thermogravimetric/differential thermal analysis showed that -S-O-S- crosslinking occurred in the polymer after the 50 hour AST. Gas chromatography showed that the hydrogen permeability was decreased by -S-O-S- crosslinking. The reduction of the hydrogen crossover current density measured by LSV in the early stages of AST could be caused by both reduction of the electrochemical surface area of the electrode catalyst and -S-O-S- crosslinking.

A Study on the Horizontal Drainage Method Using Plastic Drain Board (플라스틱 배수재를 이용한 수평배수공법에 관한 연구)

  • 황정규;김홍택;김석열;강인규;김승욱
    • Geotechnical Engineering
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    • v.14 no.6
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    • pp.93-112
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    • 1998
  • In the present study, 2-D consolidation theory of the dredged clay by means of the horizontal drain method is proposed. The horizontal drain method to install the drains such as plastic drain board within the dredged clay is a soil improvement method to accelerate the consolidation by expelling pore water in the vertical direction along the horizontal drains. Based on the finite strain consolidation theory by Gibson et al., the partial differential equation of 2-D consolidation due to the horizontal drain is derived. The consolidation due to the horizontal drain can be illustrated from combined self-weight consolidation effect and consolidation effect by horizontal drains. For the prediction of consolidation settlement and degree of consolidation numerical analysis is suggested on the basis of Dufort-Frankel finite differential algorithm. Also, the analytical procedures proposed in this study are verified by the model tests, and the predictions of the consolidation settlement and degree of consolidation are compared with the results obtained from the tests for the dredged clay gathering at Siwha site in Ansan, Korea. For the predictions, the relationship void ratio vs effective stress and the relationship permeability vs void ratio of the dredged clay are obtained from the odometer tests. Additionally, the parametric study for consolidation settlement by variations of design parameters related with horizontal drain method is carried out. Based on the results of the parametric study, design .charts for the preliminary design are also proposed.

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Fabrication and Evaluation Properties of Micro-Tubular Solid Oxide Fuel Cells (SOFCs) (마이크로 원통형 SOFC 제작 및 특성평가)

  • Kim, Hwan;Kim, Wan-Je;Lee, Jong-Won;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.749-753
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    • 2012
  • In present work, anode support for micro-tubular SOFC was fabricated with outer diameter of 3 mm and characterized with microstructure, mechanical properties and gas permeability. The microstructure of surface and cross section of a porous anode support were analyzed by using SEM (Scanning Electron Microscope) image. The gas permeability and the mechanical strength of anode support was measured and analysed by using differential pressure at the flow rates of 50, 100, 150 cc/min. and using universal testing machine respectively. The unit cell composed of NiO-YSZ, YSZ, YSZ-LSM/LSM/LSCF was fabricated and operated with reaction temperature and fuel flow rate and showed maximum power density of $1095mW/cm^2$ on the condition of $800^{\circ}C$. The performance of single cell for micro-tubular SOFC increased with the increasing the reaction temperature due to the decrement of ohmic resistance of cell by the increment of the ionic conductivity of electrolyte through the evaluation of electrochemical impedance analysis for single cell with reaction temperature.