• Title/Summary/Keyword: diene

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Effect of acid whey and freeze-dried cranberries on lipid oxidation and fatty acid composition of nitrite-/nitrate-free fermented sausage made from deer meat

  • Karwowska, Malgorzata;Dolatowski, Zbigniew J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.30 no.1
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    • pp.85-93
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    • 2017
  • Objective: This study evaluated the effect of acid whey and freeze-dried cranberries on the physicochemical characteristics, lipid oxidation and fatty acid composition of nitrite-free fermented sausage made from deer meat and pork fat. Antioxidant interactions between acid whey and cranberry compounds were also explored. Methods: Four formulations of fermented venison sausage were prepared: F1 (control), F2 (with 5% liquid acid whey), F3 (with 0.06% of freeze-dried cranberries), and F4 (with 5% liquid acid whey and 0.06% of freeze-dried cranberries). Each sample was analyzed for pH, water activity ($a_w$), heme iron content, 2-thiobarbituric acid reactive substances (TBARS) value and conjugated dienes at the end of the manufacturing process and at 30 and 90 days of refrigerated storage. Fatty acid composition was measured once at the end of the manufacturing process. Results: At the end of ripening, all samples presented statistically different values for a pH range of 4.47 to pH 4.59. The sum of the unsaturated fatty acids was higher, while the conjugated diene and the TBARS values were lower in sausages with freeze-dried cranberries as compared to the control sausage. The highest content of heme iron (21.52 mg/kg) at day 90 was found in the sausage formulation with the addition of freeze-dried cranberries, which suggests that the addition of cranberries stabilized the porphyrin ring of the heme molecule during storage and thereby reduced the release of iron. The use of liquid acid whey in combination with cranberries appears to not be justified in view of the oxidative stability of the obtained products. Conclusion: The results suggest that the application of freeze-dried cranberries can lower the intensity of oxidative changes during the storage of nitrite-free fermented sausage made

Metabolism of Ginsenoside Rg5, a Main Constituent Isolated from Red Ginseng, by Human Intestinal Microflora and Their Antiallergic Effect

  • Shin, Yong-Wook;Bae, Eun-Ah;Han, Myung-Joo;Kim, Dong-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.16 no.11
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    • pp.1791-1798
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    • 2006
  • When ginsenoside Rg5, a main component isolated from red ginseng, was incubated with three human fecal microflora for 24 h, all specimens showed hydrolyzing activity: all specimens produced ginsenoside Rh3 as a main metabolite, but a minor metabolite $3{\beta},12{\beta}$-dihydroxydammar-21(22),24-diene (DD) was observed in two specimens. To evaluate the antiallergic effect of ginsenoside Rg5 and its metabolites, the inhibitory effect of ginsenoside Rg5 and its metabolite ginsenoside Rh3 against RBL-2H3 cell degranulation, mouse passive cutaneous anaphylaxis (PCA) reaction induced by the IgE-antigen complex, and mouse ear skin dermatitis induced by 12-O-tetradecanoilphorbol-13-acetate (TPA) were measured. Ginsenosides Rg5 and Rh3 potently inhibited degranulation of RBL-2H3 cells. These ginsenosides also inhibited mRNA expression of proinflammatory cytokines IL-6 and $TNF-{\alpha}$ in RBL-2H3 cells stimulated by IgE-antigen. Orally and intraperitoneally administered ginsenoside Rg3 and orally administered ginsenoside Rg5 to mice potently inhibited the PCA reaction induced by IgE-antigen complex. However, intraperitoneally administered ginsenoside Rg5 nearly did not inhibit the PCA reaction. These ginsenosides not only suppressed the swelling of mouse ears induced by TPA, but also inhibited mRNA expression of cyclooxygenase-2, $TNF-{\alpha}$, and IL-4 and activation of transcription factor NF-kB. These inhibitions of ginsenoside Rh3 were more potent than those of ginsenoside Rg5. These findings suggest that ginsenoside Rg5 may be metabolized in vivo to ginsenoside Rh3 by human intestinal microflora, and ginsenoside Rh3 may improve antiallergic diseases, such as rhinitis and dermatitis.

Preparation of Sulfur Crosslinkable EVA and Blend With Rubbers (황가황형 EVA의 제조 및 고무와의 블렌드)

  • Jin, Je-Yong;Choi, Sei-Young
    • Elastomers and Composites
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    • v.34 no.3
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    • pp.229-238
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    • 1999
  • In this study, double bond, unsaturated group was introduced to the main chain of EVA by chemically treating EVA, nondiene polymer. Benzene sulfonic acid, ENB and DCPD were used as a third element. Also, from blending CR and SBR, conventional synthetic rubber we prepared vulcanizates and examined their physical properties. The datum lead to the following conclusion that some problems were modified; limited temperature in use and mechanical properties like hardness, tensile strength, tensile stress, and elongation rate of thermoplastic EVA, keeping the following advantages of original EVA; green strength, injection molding by Pressure, adhesion, tackiness, dimensional stability, and ozone resistance, etc. It is expected that continuous research of the modification between nondiene and diene polymer will improve what were shown disadvantages in synthetic polymer; processing, oxidation resistance, and adhesion. In addition, it will be possible to continue process of rubber products by utilizing possible fluidity for fusion of EVA.

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The Effect of Fillers on Rubber Characteristics for Gasket to Lithium Ion Battery (리튬이온 전지용 가스켓 고무의 특성에 미치는 충전제의 영향)

  • Seo, Kwan-Ho;Cho, Kwang-Soo;Yun, In-Sub;Choi, Woo-Hyuk;Hur, Byung-Ki;Kang, Dong-Gug
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.430-433
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    • 2010
  • The gasket materials of for the lithium ion battery requires chemical resistance to electrolyte, electrical insulating, compression set, anti-contamination and low temperature property. To check the special characteristics of fillers which are applied to rubber for gasket, compound of EPDM, NBR and FKM (fluoro elastomer) were made by adjusting weights of carbon black and silica additive. Using these compounds, we had done tests of long-term stability against electrolyte, compression set and low-temperature property with considering operating condition of the lithium ion battery. From this test, we investigated the physical and chemical characteristics of rubber with using of carbon black and silica additive in each.

Comparison of Analytical Methods for Saikosaponins in Bupleurum falcatum L. (자호(紫胡) 사이코사포닌 정량분석방법(定量分析方法) 비교(比較))

  • Kim, Kwan-Su;Lee, Seoung-Tack;Seong, Nak-Sui;Lee, Jung-Il;Chae, Young-Am
    • Korean Journal of Medicinal Crop Science
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    • v.3 no.3
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    • pp.226-232
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    • 1995
  • Extraction methods and instrumental analytical conditions were compared to establish a fast and appropriate analytical method to determine saikosaponins in Bupleurum falcatum. Using HPLC, analysis of diene-saikosaponin treated with 2% acid was faster than that of saikosaponin itself. Among various extraction methods, extraction by standing in methanol at room temperature showed highest efficieny, and extraction with boiling methanol was shorter in analytical time and showed good chromatogram. And we could analyze many samples faster using HPTLC but the analytical accuracy was low. In extraction and analysis of saikosaponins, extraction with boiling methanol and acidic treatment was fast and easy analytical method. And for selecting useful lines in component breeding, we think TLC method was better.

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Morphology and Physical Properties of EPDM Composites Containing Bottom Ash and Talc (EPDM/Bottom Ash 복합재료의 형태학 및 물리적 특성)

  • Kim, Yeongho;Shim, Hyunseok;Lee, Minho;Min, Byong Hun;Kim, Jeong Ho
    • Clean Technology
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    • v.19 no.3
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    • pp.272-278
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    • 2013
  • Ethylene propylene diene terpolymer (EPDM) has been usually used for various applications. Bottom ash generated in thermoelectric power plant is hardly recycled. In this study, EPDM/bottom ash/talc composites were prepared by using roll-mill. Bottom ashes obtained from thermoelectric power plant were modified using surfactant. The processing materials used in this study were antioxidant, processing oil, cross-linking co-agent and softening agent. Morphology and physical properties of EPDM composites are investigated by using SEM, TGA, UTM and Rheometer. As a result, when modified ash and talc are added to EPDM composites, the tensile strength and modulus of EPDM composites were remarkably enhanced.

Water-Proof Technology for Water Hazard in Golf Course in Korea (국내 골프장 연못의 방수기술)

  • Kim Won-Jo;Lee In-Hwan;Lee Jae-Pil;Kim Doo-Hwan
    • Asian Journal of Turfgrass Science
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    • v.18 no.2
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    • pp.77-95
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    • 2004
  • This study was conducted to find out definition, specification and characteristics of water-proof method for pond at golf courses that located in the mountain in Korea. Water-proof method of pond was selected by location, kind of soil, area, depth, cost, construction period and so on. 1. Soil Bentonite Sealing Liner(SBL) is to mix soil with a good quality bentonite. Then the mixed material was dressed on the bottom of pond. $\\$Merit of SBL is to purify the water and planting is possible. It can also reduce construction period and is economical. It's easy to find out the leak points. Demerit of SBL is expensive, if good quality soil is not in constructing site. Shape of pond edge is simple. 2. Ethylen Propylene Diene Monomer Sheef(EPDM-Sheet) makes use of sheet that resists to acid and alkaline. EPDM-Sheet spreads out as a mat on the pond for water-proof. Merit of EPDM-Sheet is to perfectly prove water and make a diverse shape of pond edge. Demerit of EPDM-Sheet is not friendly to environment. It needs drain system, air ventilation and long period of construction. It is also difficult to find out leaking points in this method. 3. Water proof of ESS-13 uses ESS-13 that is resin of vegetable matter and friendly to environment. To prove water of pond, ESS-13 is delicate with water in the pond. After that, Ess-13 in the water is expanded at pore space in the soil and cover with soil. ESS-13 can be to prove a leaking pond in golf course under business. ESS-13 is cheap and it needs short construction period. It does not need to switch the old water-proof system, additionally. It needs to move fishes to other place before utilizing ESS-13.

Influence of Filler Particle Size on Behaviour of EPDM Rubber for Fuel Cell Vehicle Application under High-Pressure Hydrogen Environment (수소전기차용 EPDM 고무의 충전재 입자 크기별 고압 수소 환경에서의 거동 연구)

  • KIM, KEEJUNG;JEON, HYEONG-RYEOL;KANG, YOUNG-IM;KIM, WANJIN;YEOM, JIWOONG;CHOI, SUNG-JOON;CHO, SUNGMIN
    • Journal of Hydrogen and New Energy
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    • v.31 no.5
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    • pp.453-458
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    • 2020
  • In this study, ethylene-propylene-diene monomer (EPDM) rubbers reinforced with various particle size of carbon black were prepared and tested. We followed recently published CSA/ANSI CHMC2 standard "the test methods for evaluating material compatibility in compressed hydrogen applications-polyemr". Measurement of change in hardness, tensile strength and volume were performed after exposure to maximum operating pressure, 87.5 MPa, for 168 hours (1 week). Once EPDM was exposed to high-pressure hydrogen, the samples experience volume increase and degradation of the physical properties. Also, after the dissolved hydrogen was fully eliminated from the specimens, the hardness and the tensile properties were not recovered. The rubber reinforced with smaller sizes of carbon black particles showed less volume expansion and decrease of physical properties. As a result, smaller particle size of carbon black filler led to more resistance to high-pressure hydrogen.

Gas Impermeability Enhancement of EFDM/Crosslinked IIR Blends (Crosslinked IIR의 블렌드비에 따른 EPDM의 내기체투과특성 향상)

  • Kim, Hyun-Jun;Jung, Il-Hyun;Hong, In-Kwon;Park, Jae-Woo
    • Elastomers and Composites
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    • v.33 no.3
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    • pp.193-200
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    • 1998
  • It is well known that EPDM(ethylene propylene diene monomer) rubber has inherently excellent resistance to the weathering, ozone, heat, cold and moisture, whereas crosslinked IIR (isobutylene isoprene divlnyl benzene terpolymer) shows proper resistance to the water and gas permeation. Various characteristics of EPDM blend with crosslinked IIR such as curing characteristics, mechanical properties, dispersion of minor component and gas impermeability were explored. The optimum curing time $(t_{90})$ examined with peroxide was decreased by adding small amount of crosslinked IIR to the EPDM rubber. Mechanical properties of blends such as tensile strength, hardness and elongation at break were enhanced by increasing EPDM content. These results might be explained with the affinity of carbon black to the EPDM rubber. On the other hand, the physical properties were not changed significantly after aging, and the increase of crosslinked IIR fraction caused the decrease of compression set to small rate. EPDM rubber shows different behavior with crosslinked IIR in oxygen permeability. By adding 30wt.% crosslinked IIR to the EPDM rubber, the resistance to the oxygen permeation was improved up to three times than that of pure EPDM rubber. Conclusively, EPDM blend containing 30wt.% crosslinked IIR might be commercially applied to the o-ring and electric parts because of its proper resistance to the weathering, ozone and oxygen permeability.

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Surface Performance of Housing Materials and Profiles in AC Tracking Wheel Tests (AC 트래킹 휠 시험에서 하우징 재료 및 형상의 표면 성능)

  • Kim, Seung-Hyun;Noh, Yo-Han;Cheong, Jong-Hun;Cho, Han-Goo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.2
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    • pp.135-140
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    • 2020
  • An experimental study was conducted using the tracking wheel test (IEC 62217) method for evaluating the performance of insulator materials, in particular ethylene propylene diene monomer (EPDM) and silicone rubber. In addition, we studied the tracking characteristics resulting from applying the same method for the shape of the insulator housing, that is, the performance of regular and alternating sheds. The evaluation parameters were leakage current, surface characteristics, SEM, EDX, hydrophobicity, and temperature distribution; likewise, we applied the commercial frequency dry (and wet) flashover voltage test. We found that the regular shed had a greater leakage current than the alternating shed and that the recovery of the hydrophobicity in terms of rest time was greater than that of the EPDM in terms of leakage current. All of the regular-shed insulators of silicone rubber had tracking traces and choking on the sheath parting line, while the alternating shed showed only choking at the interface but no tracking traces. Therefore, it can be concluded that the commercial frequency wet flashover voltage of the silicone rubber with regular shed before and after the tracking wheel test is higher than that of the alternating shed.