• 한국초전도ㆍ저온공학회논문지
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• 제15권3호
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• pp.1-4
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• 2013

We investigated the effect of Nb substitution for Ru on the structural and magnetic properties of $(Ru_{1-x}Nb_x)\;Sr_2(Sm_{1.4}Ce_{0.6})Cu_2O_z$ Samples. X-ray diffraction measurements indicated that nearly single-phase samples are formed in the range from x = 0 to 1.0. The superconducting transition temperature determined from the inflection in the field-cooled magnetic susceptibility decreased only slightly from $T_c$ = 25 K for x = 0 to $T_c$ = 22 K for x = 1.0, in consistent with the change in room temperature thermopower of the samples. However, the Nb substitution for Ru above x = 0.25 significantly suppressed the weak ferromagnetic component of the field-cooled magnetic susceptibility. It was also found that the Nb substitution for Ru results in an enhanced diamagnetic susceptibility with Nb content above x = 0.5 in both zero field-cooled and field-cooled magnetization measurements, in contrast to the behavior of the samples with $x{\leq}0.5$ in which the diamagnetic susceptibility decreases as the Nb content increases.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1989년도 추계학술대회 논문집 학회본부
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• pp.87-90
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• 1989

The force acting on high Tc superconductors at 77K is measured and analyzed numerically. Both values are compared, and the difference between them is discussed. The forces, acting on a superconducting disk (thickness:1[mm], diameter:12[mm]) in an axially-symmetric magnetic field produced by a solenoid or a permanent magnet ring, are measured at 77K. The disk is an YBCO high Tc superconductor. The discrete surface current method(DSCM) is formalized for an axially-symmetric magnetic field. The forces of the superconducting disk in the magnetic field are analyzed using the DSCM, assuming that the disk is a perfect diamagnetic body. When the bottom side of the disk is separated 8[mm] from the top side of the solenoid, and the magnetic field applied on the center of the bottom side of the disk is 96[G], the measured value and the calculated value of the force are 96 and 496[mgf], respectively. The difference between them is caused by a non-perfect diamagnetism of the high Tc superconductor at 77K. It is proposed that a real force acting on high Tc superconductors at 77K can be estimated on the basis of a measured magnetic susceptibility of the high Tc superconductor at 77K and a calculated force of a perfect diamagnetic body.

• 대한화학회지
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• 제33권5호
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• pp.538-544
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• 1989

1-(phenoxymethyl)benzotriazole(1)과 1-(thiophenoxymethyl)benzotriazole(2) 유도체중의 X 치환기가 전자를 끄는 세기(${\rho}<0$)와 methylene group의 인접 Y원자에 의한 local diamagnetic effect(Y=O(1)>S(2)), 그리고 용매의 극성파라미터($E_T$=Kcal/mol:acetone;42.2>chloroform;39.0)가 클수록 methylene group의 수소원자($H_m$)와 용매사이에 B-형의 수소결합성이 증가되었으며 (1)의 methylene group 에 대한 substituent chemical shift($CH_2-SCS$)에 미치는 자유 에너지 직선관계(LFER)의 조성은 아세톤 용액 중에서 장(F)(또는 유발(I))-효과 보다 공명(R)-효과가 더 크게 나타나는 용매 의존적인 경향이었다.

• 한국산학기술학회논문지
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• 제4권1호
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• pp.27-30
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• 2003

자수정은 우리나라에서 산출되어 수출시장이 큰 준보석이다. 원석을 가공하여 최종 장신구제품을 제작하는데 실제 원석에서는 연수정, 자수정, 백수정이 함께 산출되어 이들의 품위를 정량적으로 평가하여 원석가격을 산출하는 것과 아직 확보되지 않은 자수정의 정량적 감정 기술이 필요하다. 이제까지는 아쉽게도 육안 판별과 경험에 의존하였으나 투과전자 현미경과 진동시편자력계측정을 통하여 3가지 원석의 특성을 명확히 구별하는 것이 가능하였다. 또한 FTIR(Fourier transformation infra-red) 측정을 통하여 고가 자수정의 정량품질 확인도 가능하였다. 이러한 방법은 원석의 품위를 확인하는데 효과적이고 최초 원석 상태에서의 고가 자수정의 함량을 평가할 수 있는 우수한 지표가 될 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제15권6호
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• pp.465-468
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• 1994

The charge transfer compounds $(TTF)_4FeCl_3{\cdot}CH_3OH,\;(TTF)_4SbCl_4\;and\;(TTF)_5(SbBr_4)_2{\cdot}CH_3COCH_3$ were prepared from reactions of the TTF (tetrathiafulvalene) and metal halides. The compounds were characterized by spectroscopic (UV,IR, EPR and XPS) methods, magnetic susceptibility and electrical conductivity measurements. The d.c electrical conductivities of the pressed pellets are in the order of $10^{-1}-10^{-3} Scm^{-1}$, which lies in the range of semiconductor region at room temperature. It means that the partially ionized TTF has stacked in low-dimensional chain in each compound. Spectroscopic properties also indicate that TTF molecules are partially ionized and charge transfer has occurred from (TTF)n to Fe(III) center in $(TTF)_4FeCl_3{\cdot}CH_3OH$ whereas to the $-SbX_4^-$ entity in $(TTF)_4SbCl_4\;and\;(TTF)_5(SbBr_4)_2{\cdot}CH_3COCH_3$. The EPR g values are consistent with TTF radical formation and EPR linewidths suggest the delocalization of unpaired electrons along TTF stacks. A signal arised from metal (Fe and Sb) ions were not detected in EPR spectra, indicating that metal ion is in the diamagnetic state in each compound. The diamagnetic state was also examined by the magnetic susceptibility measurement. The magnetic properties reveal the significant interaction between the $TTF^+$ radical cations in the stacks. The oxidation state of metal ions was also investigated by XPS spectra.

• 한국초전도저온공학회:학술대회논문집
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• 한국초전도저온공학회 1999년도 제1회 학술대회논문집(KIASC 1st conference 99)
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• pp.77-80
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• 1999

In this paper. We experimentally investigated the magnetic properties of YBCO bulk superconductor using AC magnetization method. The sample is 2.8cm wide in a diameter and 1.4cm long. We applied Ac magnetic field parallel to the direction of length of YBCO bulk. It is observed that YBCO bulk has the diamagnetic properties. AC loss calculation of YBCO bulk superconductor was performed by evaluating the total area of magnetization traces. As depends on the frequency and amplitude of the applied magnetic field.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제55권4호
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• pp.213-216
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• 2006

The magnetic levitation effect a high Tc superconductor beneath the toroidal permanent magnet was examined by means of a improved magnetic seesaw method. Magnetic effects associated with penetration and pinning in superconductor. One of these was focussing of magnetic field by superconductor and the other was magnetic levitation. The existence of equilibrium was shown to be related to hysteresis observed in the force separation for a toroidal permanent magnet and superconductor. Obtained results indicate that magnetic levitation effect in the present case was mainly due to diamagnetic effect.

• Bulletin of the Korean Chemical Society
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• 제29권11호
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• pp.2252-2258
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• 2008

• 천문학회보
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• 제34권1호
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• pp.80.2-80.2
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• 2009

• 한국초전도ㆍ저온공학회논문지
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• 제14권4호
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• pp.1-4
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• 2012

The applicability of the two types of magnetic separation system, high gradient magnetic separation (HGMS) and Magneto Archimedes method were studied considering the magnetic susceptibility of targeted substances. It was noted that the combination of the two methods can control the almost all the substances, paramagnetic and diamagnetic in addition to ferromagnetic substances. The principle of the methods was given and the conceput of the magnet force control technology is discussed. The practical applications of the technique were introduced together with the new application of HGMS.