• 환경위생공학
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• 제5권2호
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• pp.95-102
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• 1990

Since the production of synthetic detergents in 1966, the demand of detergents increased rapidly during the past in Korea. Its production which was solely for donlestic consumption leaped from 402 tons in 1966 to 259387 tons in 1989. Practically all of these products were the anionic detergents primarily sodium salts of Alkyl Benzene Sulfonate(ABS). ABS persists for long periods in stream because of its resistance to triodegradation. Therefore synthetic detergents have been considered major contributors to water pollution. The detergents give a raise to be noted is foaming at sewage treatment plant and the drinking water contaminated by detergents have often been accompanying taste and odor. So the biodegradable Linear Alkyl benzene Sulfonate(LAS) has been adapted as the substituents for the Alkyl Benzene Sulfonate (ABS) since the 1980. However, the Inassive bubbles stemmed from use of synthetic detergents in the sewage treatment plant and the branch of tile Han River had been reported. Therefore, this investigation less undertaken so as to know the pollution of detergents in domestic sewage and the receiving river, and determine the biodegradation of synthetic detergents since ABS has been replaced by LAS in 1980. The study results on the pollution and biodegradation of synthetic detergents were as follows . 1. The major streams in Seoul were contaminated by synthetic detergents. The concentration of detergents were 2.48 mg/l of Anyangchon. 2. The biodegradation were determined by spontaneous settling and aeration. Since the LAS was substitute for ABS in 1980, detergents was more easy to biodegradable. The reduction ratio of Tanchon, Chungranchon, and Anyangchon were 15% , 11% and 16% by the settling and 76%, 77% and 82% by aerations for 5 days.

• 한국염색가공학회지
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• 제26권3호
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• pp.209-217
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• 2014

Detergency and soil redeposition of wool fabric in drycleaning solvents, i.e. petroleum solvent, perchloroethylene (PCE), decamethylcyclopentasiloxane($D_5$), with commercial detergents were studied. The detergency of wool soiled cloth in drycleaning solvents without detergents were the order of PCE > petroleum solvent > $D_5$. When commercial detergents were added to the system, the detergency were greatly improved. When 1.0% water was added to solvents/commercial detergents system, the detergency of petroleum solvent and PCE improved whereas that of $D_5$ decreased. The soil redeposition prevention effects of solvents were the same order of detergency, i.e. PCE > petroleum solvent > $D_5$. When commercial detergents were added to the system, the soil redeposition changed depending on solvents and detergents. The soil redeposition in $D_5$ became higher with a commercial detergent, therefore it is important to develop appropriate detergents for $D_5$. Three silicone surfactants were tested for detergency and soil redeposition in $D_5$ to find candidate surfactants for drycleaning detergent formulations. Silicone surfactant PEG/PPG-19/19 Dimethicone was found to be the best surfactant for $D_5$ drycleaning detergents.

• 한국의류학회지
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• 제1권2호
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• pp.95-99
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• 1977

Washing efficiency of detergents were investigated by measuring of surface reflectance after cotton fabrics soiled in bath which consist of carbon black, palmitic acid, liquid paraffin and carbon tetrachloride were treated in Laundry-tester. Detergents used were soaps and synthetic detergents being on the marketing. Results of this study indicate that soaps were superior to synthetic detergents. Washing continued three times repeatedly in the same bath and washing in the bath which is kept for 24 hours after one washing, both of the washing efficiencies are found no appreciable change.

• 한국의류산업학회지
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• 제9권6호
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• pp.671-678
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• 2007

Formulations of compact and supercompact heavy-duty detergents, which are being used widely around the world, differ from those of conventional heavy-duty detergents. Significant differences in composition exist between the compact detergents and the conventional detergents. The compact detergents have a higher content of surfactants, oxygen bleach and enzymes than the conventional detergents. We have studied to find the most effective washing conditions of artificially soiled cloths with a commercial, supercompact, heavy-duty detergent and a drum type washing machine which is becoming the preferred type in Korea. Moreover, we have studied the washing performance with an impeller type washing machine, which has heretofore been the most popular type in East Asia. With the drum-type washing machine, washing performances improved as the washing temperatures went up and the washing times were lengthened. Though the rate of soil removal with a double recommended dosage was higher than with the recommended amount at $20^{\circ}C$, the effects of the higher dosage decreased as the washing temperatures increased. Finally, the washing performances with the two different dosages were the same at $60^{\circ}C$. The washing performances at $40^{\circ}C$ with the recommended dosage for 90 minutes were the same as with the double recommended dosage for 45 minutes. The soil removal efficiencies with the impeller-type washing machine were much lower than those of the drum-type washing machine. The reasons for this were the higher bath ratio that led to the lower concentration of wash liquor, the shorter washing time, and the lower washing temperature.

• Environmental Analysis Health and Toxicology
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• 제5권1_2호
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• pp.37-44
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• 1990

Synthetic detergents and surfactants are in widespread usage as household and industrial detergents. Potential human toxic hazard arises following percutaneous absorption or oral ingestion of solution residues from kitchen and feeding utensils, fruits, and vegetables and contaminated water supplies. A toxicological investigations was performed with the synthetic detergents and surfactants [linear alkyl benzene sulfonate (LAS), ${\alpha}$-olefin sulfonate (AOS), sodium lauryl sulfonate (SLS), sodium lauryl ester sulfonate (SLES)］, In acute toxicity, agents were administered subcutaneously into ICR mice. In acute study, after lowering of spontaneous motility, respiratory failure, death appeared, vomitting was often associated with salivation and or retching. No sex difference was observed in LD$\sub$50/ of mice. In subacute toxicity, agents were administered orally into SD rats. Body weight increase was suppressed and there was no adverse effect on food and water consumption. The weight of organs were not changed by agents as compared with control group. No specific change was observed in biochemical and hematologicalor data.

• 대한가정학회지
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• 제37권4호
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• pp.29-40
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• 1999

Effects of the commercial laundry detergents, fabric softeners, and bleaches on bactericidal activities were studied. Bactericidal activities under various conditions during washing, rinsing, and bleaching were evaluated in terms of minimum inhibitory concentration(MIC) by a broth dilution method. The experiments were carried out using Staphylococcus aureus and Escherichia coli which were usually employed in antibacterial activity tests. The results are summarized as follows : 1. All samples of Powder detergents(10 samples), soaps(7 samples) and fabric softeners(4 samples) were inactive against the Staphylococcus aureus and Escherichia coli. 2. One sample in the liquid detergents(6 samples) showed a very low MIC for Staphylococcus aureus and Escherichia coli., and three samples showed a selective effect for two bacterial strains. 3. Bleaching agent(containing peroxide) did not have bactericidal effect for Staphylococcus aureus and Escherichia coli. but the other(containing chlorine) had the effect for every bacterial strain in standard concentration. 4. All samples showed bactericidal effect above 60$^{\circ}C$.

• Environmental Analysis Health and Toxicology
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• 제7권1_2호
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• pp.67-87
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• 1992

Each detergent-solution in the concentration of 0.4% was prepared with four kinds of raw materials of detergents and two kinds of commercial surfactants for kitchen. LAS (Linear Alkyl Benzene Sulfonate), AOS ($\alpha$-O1effine Sulfonate), SLS (Sodium Lauryl Sulfonate) and SLE (Sodium Lauryl Ester Sulfonate) were used as the raw materials. Vegetables and fruits such as cucumber, crown daisy, lettuce, strawberry and tomatos were diped in each solution and washed 5 times in static or flow state. For the other experiments, tablewares such as porcelain, stainless bowls, glass and plastic cups were diped in each solution and washed also 5 times with cold and hot water in static or flow state. The residues of the detergents on the every steps of wash-conditions were measured. The results of this study were summarized as followings: 1. The residures of the detergents on the tested vegetables and fruits after 5 times washing were detected with the range from 0.450 to 7.120 ppm in static state and from 0.343 to 6.375 ppm in flow state. 2. The residures of the detergents on the tested tablewares after 5 times washing with cold water were observed with the range from 0.057 to 0.815 ppm in static state and from 0.066 to 0.905 ppm in flow state. 4. The residures of the detergents on the tested tablewares after 5 times washing with hot water were determined with the range from 0.061 to 0.424 ppm in static state and from 0.066 to 0.368 ppm in flow state. 4. Independent on detergent types, water temperatures and washing methods, the detergents were remained stablely on the porcelain; 0.057~0.815 ppm, on the stainless bowl; 0.061~0.905 ppm, on the glass cup; 0.0l4~0.592 ppm and on the plastic cup; 0.201~0.592 ppm.

• Membrane and Water Treatment
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• 제4권1호
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• pp.27-51
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• 2013

During cleaning steps, ultrafiltration membranes are mechanically and chemically stressed. This may result in membrane degradations and failures. In this paper, polysulfone membranes were used to evaluate membrane deteriorations by commercial detergents in static conditions. Ageing of the membrane was simulated by immersing samples in solutions containing commercial detergents with various concentrations, temperatures and times defined by experimental designs. Indeed, an innovative approach in the chemical membranes ageing researches, based on methodological tools, was used in order to achieve significant ageing experiments without using an accelerated ageing protocol. The macroscopic changes were monitored by permeability measurements and mechanical strength tests coupled with a microscopic characterization by ATR-FTIR and HRSEM. The present work details results obtained for three commercial detergents: an alkaline, an acidic and an enzymatic detergent. It was found that the detergents used in the industrial advised conditions (concentration, temperature and time of contact) were not detrimental for membrane properties (permeability and elongation at break) and so for the quality of the produced water. Over the industrial cumulated time of contact, different ageing effects can be observed and compared with the ones induced by NaOCl.

• 한국의류학회지
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• 제3권1호
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• pp.49-56
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• 1979

To investigate detergency of various woven fabrics in relation to the detergents and washing temperature. cotton, polyester/cotton (p/c), nylon, acetate, and polyester were soiled in aqueous artificial ($carbon-CCl_4$) soil. Each fabric was washed with soap, alkaline and neutral synthetic detergents at $30^{\circ}C$, $40^{\circ}C$ and $60^{\circ}C$ respectively. The results obtained may be summerized as follows; 1. In soap, ascension of temperature had the most important effect upon washing efficiency and the higher the temperature was, the higher the washing efficiency was showed in all fabrics. And in case of alkaline synthetic detergent, nylon and p/c fabrics were much more difficult to clean at higher temperature and also acetate and polyester had the best efficiency at $40^{\circ}C$. Detergency of neutral detergent was good but the effect of temperature in neutral detergent was less than in soap. 2. Washing efficiency of cotton was less than that of others. 3. The higher the temperature was, the higher the washing efficiency of cotton in all detergents, and the best was in soap. In p/c, detergency of neutral detergent was good but effect of ascension of temperature was lower than in soap. In nylon, washing efficiencies of alkaline synthetic detergent and neutral detergent were excellent at 30°C but detergency of soap at $60^{\circ}C$ was best. In case of acetate, detergency of all detergents was about the same at $30^{\circ}C$ but that of soap at $60^{\circ}C$ was best. In polyester at $30^{\circ}C$, efficiency of neutral detergent was excellent but that of soap was more excellent at higher temperature and the best detergency of alkaline synthetic detergent showed at $40^{\circ}C$. In general. the higher the temperature is, the higher the washing efficiency of soap is. But when synthetic fibers of nylon and polyester are washed with synthetic detergents, washing at lower temperature is advisable.

• 한국환경보건학회지
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• 제23권4호
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• pp.115-120
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• 1997

The purpose of thesis was to investigate the removal efficiency of surfactants and commercial detergents by Oenanthe javanica that is one of aquatic plants in Korea. The experiment is concerned with measuring the concentrations of surfactants and commercial detergents in different media: 1) in pure water, 2) in water containing Oenanthe javanica, 3) in water containing Oenanthe javanica and commercial nutrients. The surfactants used in this research include linear alkylbenzene sulfonates (LAS), $\alpha$-sulfo fatty acid methyl esters(MES), and alkylbenzene sulfonates(ABS). Two commercial detergents designated as A and B were in the forms of power and liquid. The results showed that LAS and MES were more effectively removed by Oenanthe javanica probably because these have a chain of linear carbon than on ABS with a branched carbon structure. In the case of commercial detergents, when the except was performed on the basis of surfactants proportion, the removal trends were similar to LAS and MES. The 5-day cultivating test with initial concentration of 0.5-1.0 ppm surfactants showed that less than 10% was removed if no nutrients an Oenanthe javanica were added. When Oenanthe javanica was added into the sample solution containing surfactants, the removal efficiency was increased 100% for the solution containing 0.5-1.0 ppm 60-70% for 5-10 ppm. In addition, chlorisis on Oenanthe javanica was observed due to surfactants and commercial detergents for all three cases. To test the dependence of population density on nutrients, the initial population density was made 300 g/0.4 m$^2$. Throughout the 5-day experiment, the on Oenanthe javanica grew 20-25% with 0.5-1.0 ppm without the synthetic nutrients but by 5% with a high concentrations of 5-10 ppm. The population density was appeared to be independent of synthetic nutrients. The leaves were to be grown with synthetic nutrients, while roots were grown without synthetic nutrients. Based on this research, the fundamental data concerning cultivation and an adequate adjustment of the water condition can provide for the utilization of Oenanthe javanica in real water treatment system.