• 자원환경지질
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• 제6권4호
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• pp.195-200
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• 1973

Temperature environments of the formation of fluorite deposits in the Wolaksan area and the Cheonil Mine, Chungcheongbuk-Do are presented and interpreted in brief. These deposits occur more or less near the contact zone between the Paleozoic limestone formations and the Cretaceous biotite granites as a number of hydrothermal veins or replacement deposits. The homogenization temperatures of fluorite crystals from the Wolaksan area fall within the narrow range of $149{\sim}167^{\circ}C$, of which lower limit is quite high, while those of the Cheonil Mine show wide range of $126{\sim}177^{\circ}C$, which indicates much lower mean temperature of formation. If the possible correction for pressure, which may not exceed $+30^{\circ}C$ as the depth of the deposits was 1.5km, were applied, the possible highest value of the true formation temperatures of fluorites in both area might be reached to around $200^{\circ}C$ that means these deposits were formed as a series of early products of the epithermal stage of hydrothermal processes.

• 한국광물학회지
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• 제6권2호
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• pp.80-93
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• 1993

Jido kaolin deposits developed in the rhyolitic tuff of Cretaceous are located in the western part of Sinan-gun, Jeonranam-do. Jido kaolin deposits is predominantly composed of pyrophyllite, kaolinite and illite. On the basis of mineral assemblage Jido kaolin deposits can be divided into three alteraion zone from the center of alteration to the margin; kaolinite, kaolinite-pyrophyillite and pyrophyillite zones. Discriminant analysis show that $Al_2O_3$, $K_2O$, $Na_2O$, CaO of major elements are discriminant elements classifying kaolinite, kaolinite-pyrophyllite and pyrophyllite zones, while in case of trace elements Cr, Ni, Sc, Zn, and Zr are discriminant elements. Kaolin deposits has been formed by the hydrothermal alterations of the volcano rocks such as rhyolitic tuff and lapilli tuff, in late cretaceous. On the basis of the results of X-ray diffraction analysis, the deposits can be classified into three types of minerals assemblages; kaolinite, kaolinite-pyrophyllite and pyrophyllite zones. All the assemblages contain quartz and muscovite, but the kaolinite zone contains kaolinite, illite and chlorite, the kaolinite-pyrophyllite zone contains kaolinite, pyrophyllite and the pyrophyllite zone contains illite and pyrite.

• 한국연소학회지
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• 제7권4호
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• pp.1-9
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• 2002

The morphology of deposits on $15-{\mu}m$ thin SiC filaments has been investigated with SEM and compared with UV-excited laser induced broadband fluorescences in co-flowing, propane laminar diffusion flames in a reduced oxidizer environment. The homogeneous morphology of droplet-like deposits inner flame zone and the agglomeration of condensed-phase deposits and the transition to soots from grown up droplet-like precursors with approaching the flame surface can be observed in a barely sooting flame. The average size of the mature soots deposited in the luminous flame edge is scarcely dependent on their axial position in a confined flame under reduced oxidizer condition. A double structure of PAH fluorescence is observed in near-extinction flames with further decreasing of oxidizer. A comparison of the PAH fluorescence with the morphologies of deposits indicates that appearance of the "dark" hollow zone is caused by a decreased number density of developed liquid-phase large molecules and the outer weak fluorescence zone is caused by the diffusion of gas-phase small molecules.

• 자원환경지질
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• 제17권4호
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• pp.245-258
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• 1984

Geoje copper ore deposits are fissure filled copper veins which developed in late Cretaceous pyroclastics, andesite and shale. Mineral paragenesis reveals a division of the hydrothermal mineralization into three stages: Stage I, deposition of pyrite, magnetite, specularite, quartz and chlorite; Stage II, deposition of chalcopyrite, sphalerite, galena, tetrahedrite, aikinite, cosalite, electrum, quartz and chlorite; Stage III, deposition of barren calcite. Filling temperatures of fluid inclusions in quartz of stage I range from 171 to $282^{\circ}C$ whereas fluid inclusions in quartz and sphalerite of stage II range from 213 to $262^{\circ}C$ and from 186 to $301^{\circ}C$ respectively. Salinities of fluid inclusions in quartz of stage I range from 5.2 to 11.2 weight percent equivalent to NaCl. Salinities of fluid inclusions in quartz and sphalerite of stage II range from 6.6 to 10.9 and from 7.1 to 14.4 weight percent equivalent NaCl. Salinities of ore fluid during major mineralization stage in this deposits reveal nearly the same ranges as those of many copper deposits in Koseong copper mining district which located about 30km apart from Geoje mine. But filling temperatures of fluid inclusions formed during major copper mineralization stage in this deposits show slightly lower than those of copper deposits in Koseong copper mining district.

• 한국재료학회지
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• 제22권1호
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• pp.8-15
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• 2012

Silicon-based thin film was prepared at room temperature by an electrochemical deposition method and a feasibility study was conducted for its use as an anode material in a rechargeable lithium battery. The growth of the electrodeposits was mainly concentrated on the surface defects of the Cu substrate while that growth was trivial on the defect-free surface region. Intentional formation of random defects on the substrate by chemical etching led to uniform formation of deposits throughout the surface. The morphology of the electrodeposits reflected first the roughened surface of the substrate, but it became flattened as the deposition time increased, due primarily to the concentration of reduction current on the convex region of the deposits. The electrodeposits proved to be amorphous and to contain chlorine and carbon, together with silicon, indicating that the electrolyte is captured in the deposits during the fabrication process. The silicon in the deposits readily reacted with lithium, but thick deposits resulted in significant reaction overvoltage. The charge efficiency of oxidation (lithiation) to reduction (delithiation) was higher in the relatively thick deposit. This abnormal behavior needs to clarified in view of the thickness dependence of the internal residual stress and the relaxation tendency of the reaction-induced stress due to the porous structure of the deposits and the deposit components other than silicon.

• 자원환경지질
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• 제26권2호
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• pp.135-143
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• 1993

Chemical compositions of sphalerites from 25 gold and/or silver deposits in central Korea were obtained with an electron probe microanalyzer. The FeS contents of sphalerites depend generally upon the assemblage of associated iron sulphides (pyrite and/or pyrrhotite) especially. The sphalerites coexisting with pyrrhotite show a narrow range of FeS variation, but the sphalerites associated with pyrite and/or pyrrhotite have the variable and wide range of FeS contents. The sphalerites from Au-dominant deposits, which vary considerably in each deposit, are generally characterized by high CdS content and low MnS content. On the contrary, the sphalerites from Ag-dominant and Au-Ag deposits tend to be characterized by relatively high MnS and very low CdS content. Based upon the mineralogy, fluid inclusions and stable isotope data, the Au-dominant deposits were formed under higher temperature and deeper depth than the Ag-dominant and Au-Ag deposits. The results suggest the possibility that the diverse sources and evolution of ore fluid at the time of ore deposition are responsible for the deposition of Cd and Mn components in sphalerites.

• 한국광물학회지
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• 제3권1호
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• pp.44-57
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• 1990

Mineralogy of clay(Napseok) deposits in Yangsan area has been studied by the methods of field investigation and laboratory works including the polarizing microscopy, X-ray diffraction, infrared spectroscopy, thermal analysis, chemical analysis by electron micro-probe and atomic absorption spectrophotometer, and electron microscopy(SEM and TEM). The Napseok ores in both the Cheonbulsan and Yongcheon deposits consist mainly of sericite, pyrophyllite and quartz, with more or less tourmaline. The high temperature minerals such as corundum and dumortierite are found in the Cheonbulsan deposit, but not in the Yongcheon deposits. Dickite, nacrite, and halloysite are found in the Yongcheon deposit, but not in the Cheonbulsan deposit. The Napseok ores of the Yukwang deposit consist of sericite posits in the Yangsan area. Occurrence, chemistry and structural features of important minerals are described. Mineralogical data of sericite such as intensity raios and chemistry also support that the Napseok deposits of both the Chenobulsan and Yongcheon mines were formed at the higher temperature than those of the Yukwang mine. Presence of sericite-dickite-pyrophyllite ores in the Yongcheon deposit also suggests the lower temperautre than in the Cheonbulsan deposit.

• 한국지형학회지
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• 제26권4호
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• pp.141-145
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• 2019

This study investigated Quaternary sand deposits in the process of surveying Quaternary deposits distributed in Yonghan-ri, Heunghae-eup, Pohang city. Field geological surveys were conducted and OSL dating samples were taken. The altitude of the Quaternary sand deposits layer is about 15m, and there are two upper and lower sand dune layers, and a peat layer is developed between them. The sampling point are just above the peat layer, and the altitude level is about 13.4m (YHO-1) and about 13.7m (YHO-2). OSL dating was performed for YHO-1 and YHO-2 and the results were 69 ± 6 ka and 62 ± 5 ka, respectively. The date analyzed are interpreted as MIS 4. On the other hand, the formation time of the peat layer at an altitude of about 13.2 to 13.7m can be compared with the results of the OSL dating of the above sandy deposits. The peat layer can be inferred to have formed during MIS 5a or earlier.

• 헤리티지:역사와 과학
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• 제44권1호
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• pp.4-29
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• 2011

복족류 패각화석층이 반복적으로 발달되어 있는 하동군 대송리 지역의 하산동층을 대상으로, 이 지역 퇴적층의 퇴적상 및 퇴적환경을 해석하고, 수반되어 있는 패각화석층의 화석화과정 발달특성을 토대로 이 지역 하산동층 퇴적 당시의 고환경을 해석하였으며, 이 결과를 바탕으로 연구지역 퇴적층의 암층서적 의미와 지질유산으로의 가치를 고찰하였다. 연구지역에 발달된 하산동층의 퇴적층은 붉은색층을 협재하지 않고 층의 횡적인 연장성이 양호한 회색질 우세의 퇴적층으로서 대규모 범람에 의해 충적평원 내에 얕은 호수가 형성되고 이후 소멸해 가는 과정을 통해 형성된 호수 주변의 사질평원 내지 이질평원에서 천호저에 이르는 환경의 퇴적층으로 해석된다. Brotiopsis wakinoensis 단일 종만이 집중되어 나타나는 특성을 보이는 연구지역의 패각 화석층은 Brotiopsis 속의 배타적 서식특성에 기인한 것으로 여겨지며, 패각화석층의 산출특성을 기준으로 3가지 유형으로 분류된다. 이 중 유형 1과 2는 이들이 서식하던 천호저 환경에서 사후에 층상범람 및 호수의 범람에 의해 이질평원 내지 사질평원으로 재동되어 화석화된 것이며, 유형 3은 충적평원상에 발달한 얕은 호수가 비교적 안정화된 시기에 호저에 집단으로 서식하던 복족류들이 죽은 후 서식하던 장소에 대부분 퇴적되어 형성된 것으로 해석된다. 하산동층의 충적평원층 내에 이와 같은 특성의 호수퇴적층이 수십 m 두께의 규모로 발달된 기록은 경상누층군 내에서 일어난 하산동층(하성평원)-진주층(호수)-칠곡층(충적평원) 간의 퇴적환경 변화의 축소판이라 볼 수 있으며, 이러한 특성의 퇴적층이 유사한 층준에 걸쳐 여러 지역에 발달되어 있음은 암층서에 의한 하산동층의 층서대비에 추가적인 설정이 필요함을 제시해 준다. 이와 함께 연구지역 하산동층의 복족류 패각화석층은 우리나라 백악기 초기의 고환경을 이해하는 데에 귀중한 자연사기록으로서, 향후 국내 백악기 연체동물 화석층의 지질유산으로서의 가치분석에 유용한 바탕자료가 될 수 있다.

• 자원환경지질
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• 제8권1호
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• pp.25-56
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• 1975

Most fluorite deposits of South Korea are distributed in three metallogenic zones namly as: Hwacheon, Hwangangni and Geumsan metallogenic zones. Fluorite deposits of each zone show The characteristic features owing to the geological setting, the structural patterns and their forming processes. deposits of the Hwacheon metallogenic zone are wholly fissure filling hydrothermal veins emThe bedded in shear fractures of the granite gneiss or schists of Precambrian age or in the cooling fractures of the granite and acidic hypabyssal rocks which are assumed to be a differentiated sister rock of the granite. Localization of most fluorite veins of the region is structurally controlled by NW and EW fracture systems and genetically related to the granite intrusion which ascertained as motivating rock of the fluorite mineralization. Fluorites are in most cases accompanied by quartz, chalcedony mainly and rarely agate, calcite, barite and sulphide base metals in some localities. The deposits of the Hwangangni metallogenic zone were formed at the last stage of hydrothermal polymineralization of W, Mo, Cu, Pb, Zn. The majority of the fluorite ore bodies were originated from replacement in limestone beds of Great Limestone Series or in calcareous interbeds of metasediments, whereas some cavity-filling ore bodies were embedded in phyllites and schists of the Ockcheon system and along the fissures in the replaced beds which were originated by volume decrease. The localization of fluorite deposits in this region is genetically related to the Moongyong granite which has been dated as middle Cretaceous, and controlled structurally by the $N20^{\circ}{\sim}50^{\circ}W$ extension fracture system or axial planes of folds, and by faults of NE direction that acted as paths of ore solution. The deposits of the Geumsan metallogenic zone are seemed to be formed through the similar process as that of Hwangangni metallogenic zone, but characteristic distinctions are in that they are more prevailing fracture filling veins and large number of the deposits are localized in roof-pendants or xenolithes of limestone in granites and porphyries. Igneous rocks that presumably motivated the mineraltzation are middle Cretaceous Geumsan granite and porphyries. Metallogenic epoch of the fluorite mineralization of South Korea are puesumably limited in early-middle Cretaceous. Studies of the fluid inclusions in fluorites of the region reveal that the homogenization temperature of the fluorite deposits are as follows: Hwacheon metallogenic zone : $95^{\circ}C{\sim}165^{\circ}C$; Hwangangni metallogenic zone : $97^{\circ}C{\sim}235^{\circ}C$; Geumsan metallogenic zone : $93^{\circ}C{\sim}236^{\circ}C$. Judging from the above results, the deposits of the Hwancheon region were formed at the epithermal stage, and those in the Hwangangni and Geumsan regions, were deposited at epithermal stage preceded by mesothermal mineralization of small scale in which some sulphide minerals were deposited. The analytical data of minor elements in the fluorites reveal that ore solutions of Hwangangni metallogenic zone seemed to be emanated in more acidic stage of magma differentiation than Hwacheon metallogenic zone did.