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The Critical Pigment Volume Concentration Concept for Paper Coatings: I. Model Coating Systems Using Plastic Pigments and Latex Binders for Paper Coating Applications

  • Lee, Do-Ik
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.5
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    • pp.1-17
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    • 2002
  • The immobilization and consolidation of the model coatings based on the plastic pigment and latex binder of known particle sizes were theoretically Studied in terms of the dense random packing of binary spheres and varying extent of latex film shrinkage. The porosity of the model coatings was calculated based on three proposed latex shrinkage models: Maximum, Minimum, and Linearly Decreasing Latex Shrinkage. The increasing extent of latex shrinkage was calculated up to the critical pigment volume concentration(CPVC) as a function of plastic pigment volume fractions, and the maximum latex shrinkage was estimated from the CPVC. Also, the number of pores and the average equivalent spherical pore diameters were calculated based on those proposed models. The opacity and gloss of the model coatings on polyester films were measured and their porosity was also determined by a simple coat weight-thickness method. As expected, various coating structure-property-composition relationships, such as opacity, gloss, porosity, etc., were shown to exhibit sharp transitions near the CPVC. The CPVC values determined by the opacity, gloss, and porosity vs. PVC relationships, respectively, agreed very well with each other. Especially, the CPVC's determined by the opacity and porosity vs. PVC curves were identical. The comparison between the theoretically calculated and experimental porosity values showed that the intermediate value between the maximum and minimum latex shrinkage would best fit the experimental porosity data. The effect of plastic pigment particle size on the optical properties and porosity of model coatings was also studied and it was observed that the coating opacity and porosity increased with increasing plastic pigment particle size, but the gloss decreased. The ink gloss of the uncalendered model coatings applied onto commercial sheet offset coated papers was shown to be affected by both the coating gloss and porosity: the higher the coating gloss, the higher the ink gloss, but the higher the coating porosity, the lower the ink gloss. Their printability was also studied in terms of the number of passes-to-fail and the rate of ink setting as a function of both plastic pigment volume fractions and plastic pigment particle sizes. A minimum crack-free temperature(MCR) of latex-bound coatings was proposed to better predict the behaviors of latexes as coating binders. The wet state of model coating dispersions, the surfaces of consolidated model coatings, and their internal structure were examined by both electron and atomic force microscopy, and their micrographs were found to be consistent with our immobilization and consolidation models.

Effects of Thermal and Electrical Conductivity of Al(OH)3 Functionalized Graphene/Epoxy Composites by Simple Sol-Gel Method (졸-젤 법을 이용한 Al(OH)3 처리된 그래핀/에폭시 복합체의 열 및 전기전도 특성 분석)

  • Kim, Ji-Won;Im, Hyun-Gu;Han, Jung-Geun;Kim, Joo-Heon
    • Polymer(Korea)
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    • v.36 no.1
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    • pp.22-28
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    • 2012
  • Functionalized graphene/epoxy composites were prepared to miprove thermal conductivities of epoxy composites and to maintain electrical insulating property. Graphene oxide (GO) was prepared using Hummers method, and then GO was reacted with aluminum isopropoxide to functionalize $Al(OH)_3$ layer onto GO surface by a simple sol-gel method (Al-GO). GO and Al-GO were characterized by X-ray photoelectron spectroscopy, field emission scanning electron microscopy and transmission electron microscopy. The analyses confirm that GO was coated with a large and dense coverage of $Al(OH)_3$. GO and Al-GO (1 and 3 wt%) were embedded in bisphenol A (DGEBA) to investigate the effects of electrical insulating property. Electrical resistivity showed that Al-GO had better insulating property than GO. Further, the thermal conductivity of GO and Al-GO/epoxy composites was higher than that of neat epoxy resins. In particular, the thermal conductivity of Al-GO/bisphenol F (DGEBF) improved by 23.3% and Al-GO/DGEBA enhanced by 21.8% compared with pure epoxy resins.

Fractal Analysis of Tidal Channel using High Resolution Satellite Image (고해상도 위성 영상을 이용한 조류로의 프랙털 분석)

  • Eom, Jin-Ah;Lee, Yoon-Kyung;Ryu, Joo-Hyung;Won, Joong-Sun
    • Korean Journal of Remote Sensing
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    • v.23 no.6
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    • pp.567-573
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    • 2007
  • Tidal channel development is influenced by sediment type, grain size, composition and tidal current. Tidal channels are usually characterized by channel formation, density and shape. Quantitative analysis of tidal channels using remotely sensed data have rarely been studied. The objective of this study is to quantify tidal channels in terms of fractal dimension and compare different inter-tidal channel patterns and compare with DEM (Digital Elevation Model). For the fractal analysis, we used box counting method which had been successfully applied to streams, coastlines and others linear features. For a study, the southern part of Ganghwado tidal flats was selected which know for high dynamics of tidal currents and vast tidal flats. This area has different widths and lengths of tidal channels. IKONOS was used for extracting tidal channels, and the box counting method was applied to obtain fractal dimensions (D) for each tidal channel. Yeochari area where channels showed less dense development and low DEM had low fractal dimenwion near $1.00{\sim}1.20$. Area (near Donggumdo and Yeongjongdo) of dendritic channel pattern and high DEM resulted in high fractal dimension near $1.20{\sim}1.35$. The difference of fractal dimensions according to channel development in tidal flats is relatively large enough to use as an index for tidal channel classification. Therefore we could conclude that fractal dimension, channel development and DEM in tidal channel has high correlation. Using fractal dimension, channel development and DEM, it would be possible to quantify the tidal channel development in association with surface characteristics.

Building Height Extraction using Triangular Vector Structure from a Single High Resolution Satellite Image (삼각벡터구조를 이용한 고해상도 위성 단영상에서의 건물 높이 추출)

  • Kim, Hye-Jin;Han, Dong-Yeob;Kim, Yong-Il
    • Korean Journal of Remote Sensing
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    • v.22 no.6
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    • pp.621-626
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    • 2006
  • Today's commercial high resolution satellite imagery such as IKONOS and QuickBird, offers the potential to extract useful spatial information for geographical database construction and GIS applications. Extraction of 3D building information from high resolution satellite imagery is one of the most active research topics. There have been many previous works to extract 3D information based on stereo analysis, including sensor modelling. Practically, it is not easy to obtain stereo high resolution satellite images. On single image performance, most studies applied the roof-bottom points or shadow length extracted manually to sensor models with DEM. It is not suitable to apply these algorithms for dense buildings. We aim to extract 3D building information from a single satellite image in a simple and practical way. To measure as many buildings as possible, in this paper, we suggested a new way to extract building height by triangular vector structure that consists of a building bottom point, its corresponding roof point and a shadow end point. The proposed method could increase the number of measurable building, and decrease the digitizing error and the computation efficiency.

Structures of OH Emulsion Prepared with Saccharide Surfactants (당류계 계면활성제로 제조된 O/W 에멀젼의 구조)

  • 홍세흠;한창규;조춘구
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.26 no.1
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    • pp.261-274
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    • 2000
  • The o/w emulsions were prepared with saccharide surfactants which were sucrose monostearate(S160), sucrose distearate(S110), and POE(20) methyl glucose stearate(SSE20). And for emulsion the oils used were n-hydocarbon, squalane(SQ), liquid paraffin(LP), octylpalmitate(OP), octylstearate(OS), alkyl benzoate(AB), isostearyl benzoate(ISB). The structures of o/w emulsion droplet were investigated by laser light scattering and the fractal dimensions were calculated from light intensity curves. Increasing of concentration, chain length, and nonpolarity of oils, fractal dimensions of emulsion droplets were found greater. In general fiactal dimensions were varied from 1.7 to 2.8 and its structures were fractal But the fractal dimensions of octadecane( $C_{18}$), 50, and LP emulsified with S110 and S160 were varied from 3.0 to 3.2 and its structures were more dense. The overall fractal dimensions of S110 and S160 were varied from 2.1 to 2.6, that of SSE20 were varied from 1.5 to 2.1. So it was found that the structures of SSE20 system were less compact than that of S110 and S 160 system, because the hindrance effect of polyoxyehtylene group of SSE20 was stronger than that of sucrose of S160. The strucures of emulsion droplets changed according to the nature of emulsifiers and to compositions of oil substances which they contained, and the structures were found similar when the hydophilic moiety of emulsifiers was same.

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A REVIEW ON THE ODSCC OF STEAM GENERATOR TUBES IN KOREAN NPPS

  • Chung, Hansub;Kim, Hong-Deok;Oh, Seungjin;Boo, Myung Hwan;Na, Kyung-Hwan;Yun, Eunsup;Kang, Yong-Seok;Kim, Wang-Bae;Lee, Jae Gon;Kim, Dong-Jin;Kim, Hong Pyo
    • Nuclear Engineering and Technology
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    • v.45 no.4
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    • pp.513-522
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    • 2013
  • The ODSCC detected in the TSP position of Ulchin 3&4 SGs are typical ODSCC of Alloy 600MA tubes. The causative chemical environment is formed by concentration of impurities inside the occluded region formed by the tube surface, egg crate strips, and sludge deposit there. Most cracks are detected at or near the line contacts between the tube surface and the egg crate strips. The region of dense crack population, as defined as between $4^{th}$ and $9^{th}$ TSPs, and near the center of hot leg hemisphere plane, coincided well with the region of preferential sludge deposition as defined by thermal hydraulics calculation using SGAP computer code. The cracks developed homogeneously in a wide range of SGs, so that the number of cracks detected each outage increased very rapidly since the first detection in the $8^{th}$ refueling outage. The root cause assessment focused on investigation of the difference in microstructure and manufacturing residual stress in order to reveal the cause of different susceptibilities to ODSCC among identical six units. The manufacturing residual stress as measured by XRD on OD surface and by split tube method indicated that the high residual stress of Alloy 600MA tube played a critical role in developing ODSCC. The level of residual stress showed substantial variations among the six units depending on details of straightening and OD grinding processes. Youngwang 3&4 tubes are less susceptible to ODSCC than U3 and U4 tubes because semi-continuous coarse chromium carbides are formed along the grain boundary of Y3&4 tubes, while there are finer less continuous chromium carbides in U3 and U4. The different carbide morphology is caused by the difference in cooling rate after mill anneal. There is a possibility that high chromium content in the Y3&4 tubes, still within the allowable range of Alloy 600, has made some contribution to the improved resistance to ODSCC. It is anticipated that ODSCC in Y5&6 SGs will be retarded more considerably than U3 SGs since the manufacturing residual stress in Y5&6 tubes is substantially lower than in U3 tubes, while the microstructure is similar with each other.

Fabrication and optical characteristics of 50 ㎓ narrow band pass filter for fiber optical communication using dual ion beam sputtering technique (이중 이온빔 스퍼터링 방식을 사용한 채널 간격 50 ㎓ 광통신용 협대역 투과 필터의 제작 및 특성)

  • 김회경;김명진
    • Korean Journal of Optics and Photonics
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    • v.14 no.3
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    • pp.331-337
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    • 2003
  • This paper represents 50 ㎓ narrow band pass filters for fiber optical communication fabricated by dual ion beam sputtering method. We have analyzed the characteristics of the TA$_2$ $O_{5}$ and $SiO_2$ single layers in order to optimize the process conditions for the 50 ㎓ narrow band pass filters, and controlled the film thickness uniformity to less than 0.1 nm deviation by dual peak spike filter pre-deposition. We designed and fabricated 50 ㎓ narrow band pass filters that consist of 216 layers including 4 cavities based on quarter wave optical thickness. Class substrates with high thermal expansion coefficients were used to reduce the film stress. Anti-reflection coating at the rear side of the substrate was also needed to reduce the optical thickness errors of the Optical Monitoring System caused by multiple beam interference between the front side and the rear side of substrate. The optical characteristics of this 50 ㎓ narrow band pass filters are insertion loss of 0.40 ㏈, pass band ripple of 0.20 ㏈, and pass bandwidth at -0.5 ㏈ of 0.20 nm. and isolation bandwidth at -25 ㏈ of 0.6 nm, which satisfy specifications of dense WDM system in fiber optical communications.tions.

Effect of sweet potato source control by planting density and defoliation on dry weight matter (재식밀도와 경엽절제에 의한 Source 조절이 고구마의 건물생산에 미치는 영향)

  • 남상영;정승근;강한철;김태수
    • Korean Journal of Plant Resources
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    • v.12 no.4
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    • pp.269-275
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    • 1999
  • For the purpose of sweet potato varietal improvement, yulmi, shinyulmi, gunmi, hongmi, and seonmi, whose source and sink are different, were cultivated at different planting densities, and then defoliation at initial stage of tuberous root weight increase on the relation of source and sink was observed as follows. The response of stem and leaf and tuberous root weight by planting density and defoliation rate of sweet potato varieties was different. Stem and leaf weight per m$^2$ increased along with dense planting by the following order; shinyulmi> seonmi> hongmi> gunmi> yulmi. Tuberous root number per m$^2$ was the most at 75$\times$20cm planting density, showing seonmi the most number. The number of stem and leaf and tuberous root increased along with the lowered rate of defoliation. In case of 75$\times$10cm and 75$\times$20cm planting density, tuberous root weight increased by increase of stem and leaf weight up to 50% defoliation and the difference of stem and leaf and tuberous root number was low as defoliation rate increases. The tuberous root and total dry weight matter was the most at 75$\times$20cm planting density. The increase and decrease of source synchronized with those of sink at 75$\times$10cm and 75$\times$20cm, however the relationship occurred less at 75$\times$30cm.

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Changes in the Community Structure of Benthic Polychaetes after the Shellfish Farm Cessation in Tongyeong Bay of Korea (통영연안의 패류양식장 중단 이후 다모류 군집구조의 변화)

  • Park, Sohyun;Kim, Sunyoung;Sim, Bo-Ram;Park, Se-jin;Kim, Hyung Chul;Yoon, Sang-Pil
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.5
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    • pp.605-617
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    • 2021
  • The recovery of the sedimentary environment around a fallowing shellfish farm during its rest period after 20 years of long-running operation, was explored in Tongyeong Bay of Korea. Seasonal survey on macrobenthos community was conducted from July 2016 to September 2018 at five stations, which included the fallowing shellfish farm after 20-year operation (FF), a newly installed shellfish farm (NF), a shellfish farm for comparison around the closed shellfish farm (CF), and control stations with no farming activities (Con1, Con2). The total number of species and the density of macrobenthos were higher at the shellfish farm stations than the non-shellfish farm station, and their seasonal changes were significant. The dominant species at the shellfish farm stations was Capitella capitata while Paraprionospio patiens was dominant at the non-shellfish farm stations. The two dominant species were potential organic contamination indicators usually inhabiting the areas with dense organic matter. This suggests that the overall survey area was highly polluted with organic matters. Multivariate analysis showed that the macrobenthic community of CF changed to a level similar to that of Con1 immediately after the investigation, but not to a state above the Con1 level. Furthermore, the changes in NF were not significant when compared to those in CF.

Ecological Characteristic of Abies koreana Stand Structure of Mt. Jirisan and Mt. Hallasan (지리산과 한라산의 구상나무 임분 구조의 생태적 특성)

  • Song, Ju Hyeon;Han, Sang Hak;Lee, Sang Hun;Yun, Chung Weon
    • Journal of Korean Society of Forest Science
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    • v.110 no.4
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    • pp.590-600
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    • 2021
  • This study compared the stand structure of Abies koreana forests between Mt. Jirisan and Mt. Hallasan by analyzing DBH distribution, stem vitality, crown structure, importance value, species diversity, and DCA. The data were acquired through the national long-term ecological research project conducted by the Ministry of Environment. In the comparison of DBH class distribution, the stem density of A. koreana with DBH < 20 cm was higher in Mt. Hallasan than that in Mt. Jirisan; however, the stem density of A. koreana with DBH > 20 cm was higher in Mt. Jirisan than that in Mt. Hallasan. For A. koreana stem vitality, the ratio of alive standing was higher in Mt. Jirisan (72.0%) than in Mt. Hallasan (60.7%), whereas the ratio of alive leaning was higher in Mt. Hallasan (10.2%) than in Mt. Jirisan (1.1%). A. koreana stand in Mt. Jirisan was a mature stand with four evenly developed and distinct layers, whereas the tree layer in Mt. Hallasan was less than 10 m and the stand had three layers without a subtree layer. Mt. Hallasan's importance value of A. koreana was 39.4% higher than Mt. Jirisan's importance value of 26.6%. The species diversity of the A. koreana community of Mt. Jirisan was 2.52 times higher than that of Mt. Hallasan, which was 1.58. DCA results revealed that the average distance between Mt. Jirisan and Mt. Hallasan was relatively distinguished, and the degree of scattering of species composition of Mt. Jirisan was relatively dense compared with that of Mt. Hallasan.