• Bulletin of the Korean Mathematical Society
• /
• v.43 no.4
• /
• pp.671-677
• /
• 2006

Let $A, B{\in}B(H)$ be Hilbert space contractions, and let ${\Delta}_{AB}$ be the elementary operator ${\Delta}_{AB}:X{\rightarrow}AXB-X$. A number of conditions which are equivalent to '${\Delta}_{AB}$ has closed range' are proved.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.5
• /
• pp.1686-1692
• /
• 2012

Densities (${\rho}$), Viscosities (${\eta}$) and ultrasonic speeds (u) of pure acetophenone (AP), propiophenone (PP), $p$-methyl acetophenone ($p$-MeAP), $p$-chloroacetophenone ($p$-ClAP) and those of their binary mixtures with $N$-ethyl aniline ($N$-EA) as a common component, were measured at 303.15 K over the entire composition range. These experimental data were used to calculate the excess volume $V^E$, deviation in ultrasonic speeds ${\Delta}u$, isentropic compressibility $K_s$, intermolecular free length $L_f$, acoustic impedance Z, deviations in isentropic compressibility ${\Delta}K_s$, deviation in viscosity ${\Delta}{\eta}$ and excess Gibbs free energy of activation of viscous flow ($G^{*E}$) at all mole fractions of $N$-ethyl aniline. These parameters, especially excess functions, are found to be quite sensitive towards the intermolecular interactions between component molecules. Theoretical values of viscosity of the binary mixtures were calculated using different empirical relations and theories. The relative merits of these relations and theories were discussed. The experimental results were correlated by using the polynomial proposed by Redlich-Kister equation.

• The Transactions of the Korean Institute of Power Electronics
• /
• v.3 no.4
• /
• pp.273-279
• /
• 1998

In this paper, the proposed charging system consists of step charging mode and time-sharing equalization charging mode. As $\Delta$V=O point is detected, the proposed cut-off method will selectively cut off the only battery to reach the $\Delta$V=O point, preventing serial-connected batteries from undercharging. In the start of each step, the equalization charging mode is performed to reduce the capacity difference among the batteries. Though it is added to simple circuit for selective cut-off, comparing with recently used step-charging method, this system can improve the life cycle of battery and charging efficiency, and be also very effective for preventing the batteries from overcharging and undercharging.

• Journal of Environmental Science International
• /
• v.27 no.3
• /
• pp.167-177
• /
• 2018

The removal characteristics of As and Se ions from aqueous solution by hexadecyl trimethyl ammonium bromide (HTMAB) modified anthracite (HTMAB-AT) were investigated under various conditions of contact time, pH and temperature. When the pH is 6, the zeta potential value of anthracite (AT) is -24 mV and on the other hand, the zeta potential value of the HTMAB-AT is +44 mV. It can be seen that the overall increase of about 60 mV. Increasing the (+) potential value indicates that the surface of the adsorbent had a stronger positive charge, so adsorption for the anion metal was increased. The isotherm data was well described by Langmuir and Temkin isotherm model. The maximum adsorption capacity was found to be 7.81 and 6.89 mg/g for As and Se ions from the Langmuir isotherm model at 298 K, respectively. The kinetic data was tested using pseudo first and pseudo second order models. The results indicated that adsorption fitted well with the pseudo second order kinetic model. The mechanism of the adsorption process showed that adsorption was dependent on intra particle diffusion model according to two step diffusion. The thermodynamic parameters(${\Delta}G^{\circ}$, ${\Delta}H^{\circ}$, and ${\Delta}S^{\circ}$) were also determined using the equilibrium constant value obtained at different temperatures. The thermodynamic parameters indicated that the adsorption process was physisorption, and also an endothermic and spontaneous process.

• Progress in Superconductivity
• /
• v.1 no.2
• /
• pp.110-114
• /
• 2000

We have investigated the Josephson vortex dynamics in $Bi_2Sr_2CaCu_2O{8+\delta}$ intrinsic Josephson junctions subjected to a magnetic field parallel to $CuO_2$ planes. We investigated mesas with $40\times40{\mu}m^2$ in size and containing 6 and 20. intrinsic junctions. The zero field I-V characteristics exhibited a typical hysteretic, multi-branched nature of the intrinsic Josephson effect. At high magnetic fields (H>1.5 T), I-V characteristics showed flux flow steps. The Swihart velocity obtained from this observation was about $4.2\times10^5$ m/s, which was the lowest mode electromagnetic wave velocity of N coupled stack. The experimental I-V curves fitted well into the simple model of Cherenkov radiation including Ohmic and non-linear dissipation terms. This suggests that the dissipation mechanism of Josephson vortex be due to both Cherenkov radiation and quasiparticle tunneling current.

• Journal of the Korean Ceramic Society
• /
• v.38 no.4
• /
• pp.325-330
• /
• 2001

고상반응법으로 이론 밀도의 약 97%의 소결 밀도를 갖는 N $d_{1-x}$S $r_{x}$G $a_{1-x}$M $g_{x}$ $O_{3{\delta}}$(x=0, 0.03, 0.07, 0.1) 고체전해질을 제조하였다. X선 회절 분석 결과, x=0.03일 때의 X선 회절도는 순수한 NdGa $O_3$와 같았으나, x=0.07, 0.1일 때에는 불순물이 나타났다. 교류 복소임피던스는 4$50^{\circ}C$~90$0^{\circ}C$의 온도 범위에서 공기 중에서 측정하였으며, 각 조성에 대하여 상호 비교 분석하기 위하여 복소비저항 스펙트럼으로 변환하여 해석하였다. 전기전도도는 N $d_{0.93}$S $r_{0.07}$G $a_{0.93}$M $g_{0.07}$ $O_{0.97}$(x=0.07) 시편이 90$0^{\circ}C$에서 6$\times$$10^{-3}$ S$cm^{-1}$ /로 가장 우수하였으며, 활성화 에너지는 저온 영역에서는 1 eV, 고온 영역에서는 0.74 eV이었다.다.

• Journal of the Korean Chemical Society
• /
• v.16 no.5
• /
• pp.290-297
• /
• 1972

We have obtained the results of Cannizzaro reaction of furfural, 5-methylfurfural and 5-bromofurfural by using alcoholic potassium hydroxide solution in 95% (V/V) methanol solvent at $0{\sim}40^{\circ}C$. The results are as follows: 1) Their Cannizzaro reaction is fourth-order reaction, and the reaction of furfural proceeds 3 times as rapid as that of 5-methylfurfural and 10 times as slow as that of 5-bromofurfural. 2) Their activation energies of furfural, 5-methylfurfural and 5-bromofurfural in the reaction are 10.46Kcal/mole, 16.27Kcal/mole, and 9.62Kcal/mole respectively, and the calculated activation parameters, and ${\Delta}S^{\neq}$, increase in the order of 5-bromofurfural, furfural and 5-methyl-furfural.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2013.08a
• /
• pp.270.2-270.2
• /
• 2013

직선운동하는 하전입자의 진행방향에 수직한 평면상에 서로 직교하는 전기장과 자기장을 걸어주면, 하전입자에는 전기장에 의한 힘 FE와 자기장과 속도 v에 의한 로렌츠력 $F_B=q(v{\times}B)$가 동시에 작용하게 된다. 이때 Wien 조건 FB=-FE를 만족하는 질량 mA과, 에너지 EA를 가지는 하전입자 A는 휘지 않고 직선운동을 계속하나, 하전입자 A와 다른 에너지 $E_B\;(=E_A+{\delta}E)$나 질량 $m_B\;(=m_A+{\delta}m)$을 가지는 하전입자는 휘게 되며, 그 휘는 정도는 ${\delta}E$나 ${\delta}m$에 비례하게 된다. 이 현상을 이용하여 다양한 종류의 에너지 또는 질량 분석기가 독일, 미국, 일본 등의 분석기기 선진국에서 개발되어 왔고, 전자현미경의 이미지 필터로도 활용되고 있으며, 통상 EXB 필터 또는 발명자의 이름을 딴 Wien 필터로 불리어지고 있다. $E{\times}B$ 필터는 일반적인 하전입자빔 렌즈와 다른 광학특성을 가지며, 지난 발표에서는 $E{\times}B$ 필터의 기본 궤도 방정식 및 다양한 2차 기하 수차 방정식의 유도과정 및 결과를 보여주었다. 본 발표에서는 EXB 필터의 전후에 배치시켜, 초점거리 등의 조정을 수행할 4극자와, $E{\times}B$ 필터에서 발생하는 2차 수차의 보정을 수행할 6극자의 광학특성의 계산 결과를 보여준다. 4극자-6극자-EXB필터-6극자-4극자 조합의 기본 광학궤도 계산 결과는 빔 다이어그램으로 보여준다. 6극자에 의해 수차를 줄여서 향상되는 에너지 분해능 값은 수치적으로 추정한다. 실제 제작이 된 각 부품의 외형 및 사진을 보여주어 에너지 필터의 제작 진행 상황을 보고한다.

• Bulletin of the Korean Chemical Society
• /
• v.4 no.3
• /
• pp.115-119
• /
• 1983

The ionic association constants (K) of 2, N-dimethyl pyridinium iodide (2NDMPI) in 95 volume percentage ethanol-water mixture were determined by a modified UV and conductance method at $20^{\circ}C{\sim}50^{\circ}C$ under 1 to 2000 bars. The K values increase with increasing pressure and decrease with temperature. The total partial molar volume change (${\Delta}V$) has relatively small negative value and the absolute ${\Delta}V$ value decrease with increasing pressure and temperature. The ion size (a) and solvation number (n) of 2NDMPI were about 5 $\AA$ and changed from 1 to 3 with decreasing temperature. Other thermodynamic parameters such as enthalpy (${\Delta}H^{\circ}$) and entropy (${\Delta}S^{\circ}$) for the equilibrium of the 2NDMPI were evaluated. From all the parameters mentioned above, we came to conclusion that the electrostriction effect of 2NDMPI in the ethanol-water mixture is enhanced with increasing pressure and decreasing temperature.

• Journal of the Institute of Electronics Engineers of Korea SP
• /
• v.42 no.4 s.304
• /
• pp.31-38
• /
• 2005

In this paper, we propose the chromatic adaptation models (CAM) for the variations of the luminance levels. A chromatic adaptation model, CAM$\Delta$Y , is proposed according to the change of luminance level under the same illuminants. The proposed model is obtained by the transform the test colors of the high luminance into the corresponding colors of the low luminance. In the proposed model, the optimal coefficients are obtained from the corresponding colors data of the Breneman's experiments. In the experimental results, we confined that the chromaticity errors, $\Delta$u'v', between the predicted colors by the proposed model and the corresponding colors of the Breneman's experiments are 0.004 in u'v' chromaticity coordinates. The prediction performance of the proposed model is excellent because this error is the threshold value that two adjacent color patches can be distinguished. Additionally, we also propose equal-whiteness CCT curves (EWCs) by CAM$\Delta$Y according to the luminance levels of the surround viewing conditions. And the proposed EWCs can be used as the theoretical standard which determines the reference white of the color display devices.