• Title/Summary/Keyword: delta-V

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Synthesis of Zr0.73Y0.27O1.87 Crystals by the Bridgman-Stockbager Method

  • Kim, Won-Sa;Yu, Young-Moon;Lee, Jin-Ho
    • Journal of the Korean earth science society
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    • v.23 no.1
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    • pp.52-58
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    • 2002
  • A colorless and transparent zirconium oxide ($Zr_{0.73}Y_{0.27}O_{1.87}$) crystal has been synthesized by the Bridgman-Stockbager method. The gem-quality material is produced by adding 20${\sim}$25 wt.% $Y_2O_3$ (stabilizer) and 0.04 wt.% $Nd_2O_3$ (decolorising agent) to the $ZrO_2$ powder. It shows a vitreous luster with a slight oily appearance. Under a polarizing microscope, it shows isotropic nature with no appreciable anisotropism. Mohs hardness value and specific gravity is measured to be 8${\sim}$$8{\frac{1}{2}}$ and 5.85, respectively. Under ultraviolet light it shows a faint white glow. The crystal structure of yttria-stabilized zirconia with 0.27 at.% Y has been re-investigated, using single crystal X-ray diffraction, and confirmed to be a cubic symmetry, space group $Fm{\overline{3}}m$ ($O^5_h$) with a=5.1552(5) ${{\AA}}$, V=136.99(5) ${{\AA}}^3$, Z=4. The stabilizer atoms randomly occupy the zirconium sites and there are displacements of oxygen atoms with amplitudes of ${\Delta}/a{\sim}$0.033 and 0.11 along <110> and <111> from the ideal positions of the fluorite structure, respectively.

Dielectric Properties and Electro-Caloric Effects of Low Temperature Sintering Ba(Ti0.9Zr0.1)O3 Ceramics (저온에서 소결된 Ba(Ti0.9Zr0.1)O3 세라믹스의 유전 특성 및 전기 열량 효과)

  • Yoo, Ju-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.1
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    • pp.13-16
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    • 2017
  • In this study, in order to develop composition ceramics for refrigeration device application, $Ba(Ti_{0.9}Zr_{0.1})O_3$ composition was fabricated using conventional solid-state method. Electrocaloric effect of this ceramic was investigated using the characteristics of P-E hysteresis loops at wide temperature range from room temperature to $150^{\circ}C$. Curie temperature of $Ba(Ti_{0.9}Zr_{0.1})O_3$ ceramics showed $80^{\circ}C$. The maximum value of ${\Delta}T=0.12^{\circ}C$ in ambient temperature of $115^{\circ}C$ under 30 kV/cm was appeared. It is concluded that $Ba(Ti_{0.9}Zr_{0.1})O_3$ ceramics can be applied as refrigeration device application.

Influence Analysis of Grid Connected Wind Power Generator by Line Constants (풍력발전 계통연계시 선로정수에 따른 계통 영향 분석)

  • Choy, Young-Do;Kwak, No-Hong;Jeon, Young-Soo;Jeon, Dong-Hoon;Han, Byung-Moon;Yun, Dong-Jin
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.249-250
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    • 2008
  • 본 논문은 고창 전력품질 실증시험장에서 실 계통 연계를 위해 시험 중인 1.5M급 풍력발전 시뮬레이터의 선로정수를 PSCAD/EMTDC를 이용하여 모의하고 선로정수에 따른 풍력발전시스템이 계통에 미치는 영향을 분석하는데 중점을 두었다. 현재 고창에 설치되어있는 전력품질 실증시험장은 22.9kV 급전선에 SSTS(Synchronous Static Transfer Switch)의 한쪽 스위치로 직접 연결되어있으며 다른 한 쪽은 전력계통에서 발생되는 다양한 형태의 이벤트를 발생시키는 SSHG(Sag Swell Harmonics Generator)를 통하여 연결되어있다. 전력품질 향상기기중 하나인 DVR(Dynamic Voltage Restorer)는 SSTS의 부하쪽으로 직렬로 연결되어있으며 delta-wye 변압기를 통해 정류기 부하와 APF(Active Power Filter), 그리고 순저항부하와 유도성부하가 연결되어 있고 또한 SSHG를 통하여 연결된 배전선에는 DSTATCOM(Distribution Static Compensator)가 병렬로 연결되어있다. 본 논문에서는 고창에 있는 풍력발전 시뮬레이터와 동일하게 PSCAD/EMTDC로 구성하였으며 선로정수를 모델링 하기 위해 선로모델을 10Km, 20Km, 30Km, 40Km,로 설정하여 선로정수에 따른 계통영향을 분석하여 풍력발전 시뮬레이터에서 모의가능 한 선로정수 값을 제시한다.

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COMPUTATIONAL FLUID DYNAMICS OF THE LOW-SPEED LONGITUDINAL AERODYNAMIC CHARACTERISTICS FOR BWB TYPE UCAV CONFIGURATION (연속일체형 날개-동체 타입 UCAV 형상의 저속 종방향 공력특성에 대한 전산유동해석)

  • Park, S.H.;Chang, K.;Shim, H.J.;Sheen, D.J.;Park, S.H.
    • Journal of computational fluids engineering
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    • v.21 no.3
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    • pp.48-54
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    • 2016
  • In the present work, numerical simulations were conducted on the scaled model of the BWB type UCAV in the subsonic region using ANSYS FLUENT V15. The prediction method was validated through comparison with experimental results and the effect of the twisted wing was investigated. To consider the transitional flow phenomenon, ${\gamma}$ transition model based on SST model was adopted. The coefficients of lift, drag and pitching moment were compared with experimental results and the pressure distribution and streamlines were investigated. The twisted wing decreases the lift force but increases lift-to-drag ratio through delay of stall and leading edge vortex's movement to the front, also the non-linearity of the pitching moment is decreased.

White Organic Light-Emitting Diodes with Color Stability

  • Seo, Ji-Hoon;Park, Jung-Sun;Koo, Ja-Ryong;Seo, Bo-Min;Lee, Kum-Hee;Yoon, Seung-Soo;Kim, Young-Kwan
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.3
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    • pp.357-361
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    • 2009
  • The authors have demonstrated white oraganic light-emitting diodes (WOLED) using 1,4-bis[2-(4'-diphenylaminobiphenyl-4-yl)vinyl]benzene as fluorescent blue emitter and iridium(III) bis(5-acetyl-2-phenylpyridinato-N,C2') acetylacetonate as phosphorescent red emitter. The optimized WOLED using red host material as bis(2-methyl-8-quinolinato) -4-phenylphenolate exhibited proper color stability in comparison with the control device using 4,4'-N,N'-dicarbazole-biphenyl as red host. The white device showed a maximum luminance of 21100 $cd/m^2$ at 14 V, luminous efficiency of 9.7 cd/A at 20 $mA/cm^2$, and Commission Internationale de I'Eclairage ($CIE_{x,y}$)coordinates of (0.32, 0.34) at 1000 $cd/m^2$. The devices also exhibited the color shift with ${\Delta}CIE_{x,y}$ coordinates of ${\pm}$ (0.01,0.01) from 100 to 20000 $cd/m^2$.

Compare Characteristics of Neck Injuries between Rear Impact Pulse and NCAP Pulse (후방 충돌 펄스와 NCAP 펄스 차이로 인한 목상해 특성 비교)

  • Kim, Jong Kon;Park, Jong Ho
    • Journal of Auto-vehicle Safety Association
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    • v.9 no.3
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    • pp.7-12
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    • 2017
  • The whiplash is the most important issue of low speed rear-impact. So auto makers are committed to developing a seat to improve whiplash injury. Most NCAP tests have been used by same pulse (Mid Velocity 16kph). Only Euro NCAP uses different pulse that consists of Low, Mid, High velocity. But Euro NCAP also uses same pulse in Mid velocity as other NCAP test. That Mid velocity NCAP pulse was made by rear impact that has 90's vehicle structure properties. That pulse was used until now days. However these days, auto maker use more high tensile steel than 90's as customer and society demand more fuel efficiency and light vehicle with good safety structure. So modern vehicles have different pulse patterns of rear impact than NCAP pulse and 90's vehicle crash properties. In this paper, the test was conducted by following condition. Target car was impacted by the rigid barrier with certain velocity. Finally target vehicle gained delta V 16kph which was same velocity as NCAP Mid Velocity pulse. It is critical velocity which occur long period neck injury. It is very different pulse that was gained by real car impact from NCAP pulse. And it has higher peak G with high fluctuation and short duration than NCAP pulse.

타원편광분석법을 이용한 AlP 유전함수 연구

  • Jeong, Yong-U;Hwang, Sun-Yong;Mangesh, S.D.;Gong, Tae-Ho;Kim, Yeong-Dong;Sin, Sang-Hun;Song, Jin-Dong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.42-42
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    • 2011
  • 본 연구에서는 광학소자에 폭넓게 이용되는 AlGaP III-V족 화합물 반도체 중에서 한쪽 끝 이 종화합물인 AlP의 유전함수를 0.75~5.05 eV의 에너지 영역에서 타원편광분석법을 이용하여 분석하였다. AlP는 산소와 급격히 반응하기 때문에, 대기 중에서 물질 고유의 광특성이 유지되기 어려울 뿐만 아니라, 박막 위에 생성되는 산화막 때문에 순수한 AlP의 유전함수 측정이 불가능 하다. 본 연구에서는 물질의 유전함수에 미치는 산화 효과를 최소화하기 위하여 Molecular Beam Epitaxy로 성장한 $1.0{\mu}m$ 두께의 AlP 박막을 초고진공 상태의 chamber 안에서 타원편광분석기를 이용하여 실시간으로 측정하였다. 박막의 투명도에 의해 나타나는 간섭 pattern과 표면거칠기 효과로 인한 유전함수의 왜곡을 보정하기 위하여 변수화 모델이 이용되었으며 다층 변수화모델 계산을 통하여 순수한 AlP의 유전함수를 얻어낼 수 있었다. 본 연구에서 측정된 순수한 AlP의 유전함수는 타원편광분석기를 이용한 최초의 실험결과로서 이차미분을 이용한 전이점 (Critical Point) 분석결과 이론적인 electronic band structure에서 $E_1$, $E_1+_{{\Delta}_1}$, $E_2$에 해당하는 전이점들을 확인할 수 있었다.

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Potentiometric CO2 gas sensor based on the thin film electrolyte of Li+ ion conductor (박막 리튬이온전도체를 이용한 전위차 CO2 가스센서)

  • Noh, Whyo-Sub;Choi, Gwang-Pyo;Song, Ho-Geun;Park, Jin-Seong
    • Journal of Sensor Science and Technology
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    • v.14 no.4
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    • pp.258-264
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    • 2005
  • Li+-ion conducting ($Li_{3}PO_{4}$) thin films with thickness of $0.3{\mu}m$, $0.65{\mu}$, $1.2{\mu}$ were deposited on $Al_{2}O_{3}$ substrate at room temperature by thermal evaporation. They were sintered at $700^{\circ}C$ and $800^{\circ}C$ for 2 hours, respectively. Reference electrode and sensing electrode were printed on Au-electrode by silk printing method. The EMF and the ${\Delta}EMF$/dec were increased with increasing the electrolyte thickness and sintering temperature. The sample sintered at $800^{\circ}C$ was shown a good response and recovery characteristics more than those sintered at $700^{\circ}C$. The Nernst's slop of 75 mV per decade was obtained at operating temperature of $500^{\circ}C$.

A study on CO gas sensing characteristics using SiC Schottky diodes (SiC 쇼트키 장벽 다이오드를 이용한 CO 가스 감지 특성에 관한 연구)

  • 김창교;노일호;조남인;유홍진;기창진
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.5 no.1
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    • pp.83-86
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    • 2004
  • A high temperature tolerant microelectronic-based carbon monioxde(CO) gas sensor has been developed. The gas sensing performance has been studied over a wide temperature range$(100-300^\circ{C)}$. The gas sensitivity of the sensor is high, its initial sensing behavior is very fast, and the sensor is reproducible. Pt-SiC and $Pt-SnO_2-SiC$ diodes are fabricated using standard semiconductor processes and their CO gas-sensing behaviors are analyzed as a function of CO gas concentration and temperature by I-V and $\Delta{I-t}$ methods under steady-state and transient conditions. The sensitivity of the device with $Pt-SnO_2$ catalytic gate is higher than that of the Pt gate. The experimental results indicate that $SnO_2$ layer improves the catalytic reaction of the Pt layer.

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A Study on the degradation mechanism of PAN-LiCLO$_4$ Polymer Electrolyte EC windows (PAN-LIClO$_4$ 계 고분자전해질 EC창의 열화 기구에 관한 연구)

  • 김용혁;김형선;조원일;조병원;윤경석;박인철
    • Journal of Surface Science and Engineering
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    • v.30 no.4
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    • pp.223-230
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    • 1997
  • Tungsten oxide and nickel oxide thin films were deposited onto ITO(Indium Tin Oxide) transparent glass by the E-beam evaporation and were used as a cathode and an anode for the EC(Electrochromic) smart window, respectively. Stoichiometric structures of the deposited films were investigated by the implementation of XPS(X-ray Photoelectron Spectroscopy) analysis and the results were $WO_{2.42}$ and $NiO_{0.44}$. This oxygen deficincy might affect affect the transparency of the thin films. The electrolyte for the EC smart windows was PAN-$LiCIO_4$ conducting polymer. EC(Ethylene Carbonate)and PC(Propylene Carbonate) were added as plasticizer to enhance ion conductivity. When the weight ratio of the EC : PC was 3 : 1, transmission difference and cycle life performance were tested. Polymer EC windows showed 40% $\Delta$T at 1.5V operating volage for 3,200 cycles. Structural degradation was observed by the SIMS(Secondary Ion Mass Spectroscopy) analysis and it was confirmed that structural degradation of polymer caused by the solvent evaporation was the main cause to degrade EC smart windows.

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