• Title/Summary/Keyword: delamination resistance

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Study of Pr0.3Sr0.7CoxMn(1-x)O3 as the Cathode Materials for Intermediate Temperature SOFC (중.저온형 고체 산화물 연료전지의 공기극 물질로 사용되는 Pr0.3Sr0.7CoxMn(1-x)O3 (x=0, 0.3, 0.5, 0.7, 1)에 관한 연구)

  • Park, Kwang-Jin;Kim, Jung-Hyun;Bae, Joong-Myeon
    • Journal of the Korean Ceramic Society
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    • v.44 no.4 s.299
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    • pp.214-218
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    • 2007
  • The decrease of polarization resistance in cathode is the key point for operating at intermediate temperature SOFC (solid oxide fuel cell). In this study, the influence of Co substitution in B-site at complex perovskite on the electronic conductivity of PSCM ($Pr_{0.3}Sr_{0.7}Co_xMn_{(1-x)}$) was investigated. The PSCM series exhibits excellent MIEC (mixed ionic electronic conductor) properties. The ASR (area specific resistance) of PSCM3773 was $0.174{\Omega}{\cdot}cm^2\;at\;700^{\circ}C$. The activation energy of PSCM3773 was also lower than other compositions of PSCM. The TEC(thermal expansion coefficient) was decreased by addition of Mn. The ASR values were increased gradually during the thermal cycling test of PSCM37773 due to the delamination between electrolyte and cathode materials. The delamination was caused by the difference of TEC.

Failure Mechanism of Bendable Embedded Electronic Module Under Various Environment Conditions (Bendable 임베디드 전자모듈의 손상 메커니즘)

  • Jo, Yun-Seong;Kim, A Young;Hong, Won Sik
    • Journal of Welding and Joining
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    • v.31 no.5
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    • pp.59-63
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    • 2013
  • A bendable electronic module has been developed for a mobile application by using a low-cost roll-to-roll manufacturing process. In flexible embedded electronic module, a thin silicon chip was embedded in a polymer-based encapsulating adhesive between flexible copper clad polyimide layers. To confirm reliability and durability of prototype bendable module, the following tests were conducted: Moisture sensitivity level, thermal shock test, high temperature & high humidity storage test, and pressure cooker tester. Those experiments to induce failure of the module due to temperature variations and moisture are the experiment to verify the reliability. Failure criterion was 20% increase in bump resistance from the initial value. The mechanism of the increase of the bump resistance was analyzed by using non-destructive X-ray analysis and scanning acoustic microscopy. During the pressure cooker test (PCT), delamination occurred at the various interfaces of the bendable embedded modules. To investigate the failure mechanism, moisture diffusion analysis was conducted to the pressure cooker's test. The hygroscopic characteristics of the encapsulating polymeric materials were experimentally determined. Analysis results have shown moisture saturation process of flexible module under high temperature/high humidity and high atmosphere conditions. Based on these results, stress factor and failure mechanism/mode of bendable embedded electronic module were obtained.

Lifetime Estimation of an ACF in Navigation (Navigation Connection용 ACF(Anisotropic Conductive Film)의 수명 예측)

  • Yu, Yeong-Chang;Shin, Seung-Jung;Kwack, Kae-Dal
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1277-1282
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    • 2008
  • Recently LCD panels have becom very important components for portable electronics. In the high density interconnection material, ACF's are used to connect the outer lead of the tape automated bonding to the transparent indium tin oxide electrodes of the LCD panel. ACF consists of an adhesive polymer matrix and randomly dispersed conductive balls. In this study, we analyzed Failure Mode / Mechanism of ACF which is identified Conductive ball Corrsion, Delamination, Crack and Polymer Expansion / Swelling. In ALT(Accelerated Life Test), we select primary stress factors as temperature and humidity. As time passes by, an increase of connection resistance was observed. In conclusion, we have found that high temperature / humidity affects the adhesion.

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Effect of Fluoride Conversion Coating on the Corrosion Resistance and Adhesion of E-painted AZ31 Magnesium Alloy

  • Fazal, Basit Raza;Moon, Sungmo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.124.2-124.2
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    • 2016
  • Corrosion resistance and adhesion of electro-paint (E-paint) with fluoride conversion coating (FCC) on AZ31 Mg alloy were studied. Corrosion resistance and adhesion were studied as a function of FCC-treatment time and concentration of FCC-bath. Aqueous hydrogen fluoride (HF) solutions, with concentrations ranging from 0.5 M to 5 M, were used to form FCC on chemically polished AZ31 Mg alloy samples for six different times; 10, 30, 60, 90, 120, and 180s. The results from salt spray test (SST) showed that corrosion resistance of E-paint appeared to decrease with increasing FCC treatment times in low concentration FCC baths. The number of blisters formed on the FCC-treated samples increased with increasing FCC treatment time of more than 1 min in low concentration (0.5 M to 1 M) solutions. On the other hand, samples treated in the 5 M HF solution for 120s showed no delamination or blistering even after 1200h of SST.

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A Study on the Impact-Induced Damage in CFRP Angle-ply Laminates (CFRP 사교적층판의 충격손상에 관한 연구)

  • 배태성;입야영;양동률
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.2
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    • pp.237-247
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    • 1993
  • Carbon fiber reinforced plastics(CFRP) have gained increased application in aerospace structures because of their specific strength and stiffness, but are sensitive to impact-induced damage. An experimental investigation was carried out to evaluate the impact resistance of CFRP according to the ply angle. The specimens of angle ply laminate composites were employed with [0.deg. $_{6}$/ .deg.$_{10}$/0.deg.$_{6}$], in which 6 kinds of ply angle such as .deg.=15.deg., 30.deg., 45.deg., 60.deg., 75.deg. and 90.deg. were selected. The impact tests were conducted using the air gun type impact testing machine by steel balls of diameter of 5 mm and 10 mm, and impact-induced damages were evaluated under same impact speed of V=60m/s. The impact damaged zones were observed through a scanning acoustic microscope (SAM). The obtained results were summarized as follows: (1) Delaminations on the interfacial boundaries showed th directional characteristics to the fiber directions. The delamination area on the impact side (interface A) was considerably smaller compared to that of the opposite side (interface B). (2) Cracks corresponding to other delaminations than those mentioned in SAM photographs were also seen on the impact damaged zone. (3) The delamination patterns were affected by the ply-angle, the dimensions of the specimen, and the boundary conditions. (4) The impact damaged zone showed zone showed the delamination on the interfacial boundaries, transverse shear cracks of the surface layer, and bending cracks of the bottom layer.r.r.r.

Wear Characteristics of the Extruded Bars of Hypereutectic Al-Si Alloy Powders produced by Rapid Solidification Process (급속응고법으로 제조한 과공정 Al-Si합금분말 압출재의 마멸특성)

  • Ahn, Young-Nam;Cho, Gue-Serb;Ra, Hyung-Yong
    • Journal of Korea Foundry Society
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    • v.14 no.5
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    • pp.447-454
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    • 1994
  • Wear resistance and wear mechanism of hypereutectic Al-($15{\sim}40$)wt%Si alloys were investigated. Primary Si particles under $20{\mu}m$ size were formed in hypereutectic Al-Si alloy powders due to rapid solidification. But the Si particles of extruded bars were finely distributed in smaller size than that of atomized powders. The wear mechanism of hypereutectic Al-Si alloys was divided into three types of wear phenomena, which were abrasive wear, delamination wear and severe adhesive wear according to sliding speed and load. At low sliding speed and load, wear mechanism was abrasive wear, so Al-15wt%Si alloy showed the best wear resistance. At high sliding speed and load, wear mechanism was adhesive wear, and Al-40wt%Si alloy showed the best wear resistance.

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Effect of Carbon on Wear Resistance in Self-lubricating Fe-Cr-C-Mn-Cu Alloys

  • Kim, Ki Nam;Shin, Gyeong Su;Park, Myung Chul;Lee, Sung Yong;Yun, Jae Yong;Kim, Seon Jin
    • Korean Journal of Metals and Materials
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    • v.50 no.9
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    • pp.637-643
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    • 2012
  • Recently, because of safety and environmental concerns, there has been a tendency to introduce solid self-lubricating composites for bearing materials. In this paper, we developed Fe-Cr-C-Mn-Cu cast composite alloys as a self-lubricating composite and investigated the effect of carbon on the formation of protective tribofilms during sliding. The wear resistance of these materials was mainly affected by carbon concentrations due to the fact that in particular wear passed from delamination to tribo-oxidation, reducing the wear rate. The improved wear resistance likely resulted from protective tribofilms that formed on the surface during sliding.

Electrical applications of braided composite materials (브레이드 섬유강화 복합재료의 전기적 특성)

  • 한동희;조한구;한세원;박기호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.882-885
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    • 2001
  • This paper aims to investigate the characteristics of braided thermoplastic composite and pressure relief for polymer arrester. In general, braided composite has potential for improved impact and delamination resistance. Manufacturing processes of the braided composite could also be automated and could potentially lead to lower costs. Therefore, in consideration of characteristics of pressure relief for polymer arrester, the fabric pattern of braided composite was decided. And polymer arrester module was manufactured with braid.

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Processing and Mode 1 Fracture Toughness of Carbon Fiber Composites Reinforced With Carbon Nanotubes (탄소나노튜브로 보강된 탄소섬유복합재의 제조 공정과 모드 1 파괴인성)

  • Kim, Han-Sang
    • Composites Research
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    • v.24 no.5
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    • pp.39-43
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    • 2011
  • For the last twenty years, nanocomposites composed of polymer matrices reinforced with carbon nanotubes (CNTs) have been an active research area. Also, the polymeric nanocomposites reinforced with CNTs are being investigated to be used matrices of carbon fiber composites. Carbon tiber composites have achieved advanced properties in the direction of carbon fibers due to enhanced carbon fiber properties. However, the matrix dominated properties need to be improved further to fully utilize the advanced carbon fiber properties. In particular, delamination is a typical and critical reason for fracture of carbon fiber composites. Mode I fracture toughness test which is also often called double cantilever beam (DCB) test shows the resistance to delamination of carbon fiber composites and this test is performed on carbon fiber composite samples incorporated with carbon nanotubes functionalized with various functional groups. The specimens with mat-like CNT layers showed the increased fracture toughness by 10.6%.

Penetration Characteristics of CFRP Laminated shells according to Stacking Sequence and Curvature (CFRP 적층쉘의 적층구성 및 곡률 변화에 따른 관통 특성)

  • Cho Young Jea;Kim Young Nam;Yang In Young
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.2
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    • pp.164-171
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    • 2005
  • This study aims to examine an effect of stacking sequence and curvature on the penetration characteristic of a composite laminated shell. For the purpose, we manufactured specimens with different stacking sequences and curvatures, and conducted a penetration test using an air-gun. To examine an influence according to stacking sequence, as flat plate and curvature specimen had more plies, their critical penetration energy was higher, Critical penetration energies of specimen A and C with less interfaces somewhat higher than those of B and D with more interfaces. The reason that with less interfaces, critical penetration energy was higher is pre-impact bending stiffness of composite laminated shell with less interfaces was lower than that of laminated shell with more interfaces, but bending stiffness after impact was higher. And it is because interface, the weakest part of the composite laminated shell, was influenced by transverse impact. As curvature increases, critical penetration energy increases linearly. It is because as curvature increases, resistance to in-plane deformation as well as bending deformation increases, which need higher critical penetration energy. Patterns of cracks caused by penetration of composite laminated shells include interlaminar crack, intralaminar crack, and laminar fracture. A 0$^{\circ}$ply laminar had a matrix crack, a 90$^{\circ}$ply laminar had intralaminar crack and laminar fracture, and interface between 0$^{\circ}$and 90$^{\circ}$laminar had a interlaminar crack. We examined crack length and delamination area through a penetration test. For the specimen A and C with 2 interface, the longest circumferential direction crack length and largest delamination area were observed on the first interface from the impact point. For the specimen B and D with 4 interface, the longest crack length and largest delamination area were observed on the third interface from the impact point.