• 펄프종이기술
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• 제33권4호
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• pp.42-48
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• 2001

The spent liquor (BSL) obtained from alkaline sulfite-anthraquinone (AS-AQ) cooking of pine bark was applied as a deinking agent. In the ONP deinking system, although BSL removed the small size of ink particles (${\geq}$$12.5{\mu}m$), it did not improve the brightness of pulp. The brightness of pulp slightly improved when treated with BSL at 150~$180^{\circ}C$. However, the brightness of the pulp was lower than that of a commercial deinking agent (oleic acid). It seems that BSL treated with a high temperature still had a high dispersing ability on the ink particles. Intensive oxidations were introduced, and remarkable deinking effects were observed at 13kgf/$cm^2$ oxygen pressure, $160^{\circ}C$ and 2h. When BSL treated at 13kgf/$cm^2$ oxygen pressure, $170^{\circ}C$ and a time period of 30~90 min is added to the pulp, at 0.1% or lower, the deinking effect became higher than that of oleic acid. On the other hand, additional alkali treatments during the oxidation possibility as a deinking agent when oxidized. However, since the oxidized BSL still has a high dispersing ability and lower molecular weight, several modifications need to be done in the near future in order to be applied as a high quality deinking agent.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 춘계학술발표논문집
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• pp.167-173
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• 2006

Deinking is a series of unit operations designed to detach ink from cellulose fibers and separate the dispersed ink from the pulp slurry. Deinking chemicals are process aids that enable expensive mill equipment used in these unit operations to operate more efficiently - often much more efficiently. We propose the blended deinking agent with cellulolutic enzymes and synthetic collector in deinking pulp of conventional alkaline method. The deinking efficiency of old news print in alkaline pH was enhanced with enzyme treatments. The brightness of deinked pulp was increased with less residual ink particles and yield of enzymatic deinked pulp was improved compared to the deinked pulp of conventional alkaline method. Enzymes in biomass were use to Chemical Deinking for reduce environment pollution through surfactant and improve surfactants. examining into compatibility Enzymes and surfactants, these new materials are studied efficiency of deinking efficiency.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 추계학술발표논문집
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• pp.9-14
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• 2006

Deinking is a series of unit operations designed to detach ink from cellulose fibers and separate the dispersed ink from the pulp slurry. Deinking chemicals are process aids that enable expensive mill equipment used in these unit operations to operate more efficiently. This paper presents an overview of ONP deinking efficiency with cellulolytic enzymes and synthetic collector in low alkalinity process. The deinking efficiency of old news print even in low alkalinity condition was enhanced with enzyme contained complex agent. The brightness of deinked pulp was increased with less residual ink particles and yield of deinked pulp was improved compared to the deinked pulp of conventional alkaline method.

• 펄프종이기술
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• 제35권4호
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• pp.34-41
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• 2003

The effect of wettability of deinking agents which formed with various nonionic surfactants against the pulp fibers and ink particles were studied, And the effect of flotation processes on the deinking were also investigated. The wettabilities of the deinking agents against the water and ink particles were measured by Washburn tube and sessile drop techniques, respectively. As the water absorption increased (i.e., hydrophilicity increased), the ink removal increased, which indicates that the ink removal is strongly affected by the detachment process due to the swelling of the pulp. Also, when the contact angle of air/ink/deinking agent increased, the hydrophobicity of the ink particles increased, the efficiency of the ink removal and the brightness increased.

• 펄프종이기술
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• 제35권1호
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• pp.34-40
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• 2003

This study was carried out to select the useful bacteria which secret extracellula enzymes for enzymatic deinking agent of old newspaper. CMCase, FPase and xylanase activities of the bacteria liquid culture were measured at optimal growth conditions. Clear zone test was checked on the solid culture. The results of this study were as follow: Eight strains of 28 bacteria isolated from a paper mill soil ground were shown strong CMCase and xylanase activity with the clear zone test. The optimal pH and temperature for culture growth were 6~8 and 26~$34^{\circ}C$, respectively and optimal culture period were less than 60 hours. Based on CMCase, FPase and xylanase activity, strain No. 18, 21, 22 and 28 which were relatively higher than the other strains, were selected for further enzymatic deinking research.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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• pp.451-454
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• 2006

This paper presents an overview of ONP deinking efficiency with cellulolytic enzymes and synthetic collector in alkaline pH. Deinking is a series of unit operations designed to detach ink from cellulose fibers and separate the dispersed ink from the pulp slurry. Deinking chemicals are process aids that enable expensive mill equipment used in these unit operations to operate more efficiently - often much more efficiently. We propose the blended deinking agent with cellulolutic enzymes and synthetic collector in deinking pulp of conventional alkaline method. The deinking efficiency of old news print in alkaline pH was enhanced with enzyme treatments. The brightness of deinked pulp was increased with less residual ink particles and yield of enzymatic deinked pulp was improved compared to the deinked pulp of conventional alkaline method.

• 한국산학기술학회논문지
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• 제17권6호
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• pp.729-736
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• 2016

지구 환경 보존이라는 관점에서 폐지류의 재활용 및 자원화 노력이 절대적으로 필요하다. 폐지 재활용은 잉크 제거의 효과에 따라 기술력이 좌우된다. 기존 고체 탈묵제의 잉크 제거 효울을 개선하기 위해 액상 탈묵제를 지방산 종류에 따라 검화 반응시키고 EO/PO를 추가 혼합하여 제조하였다. 제조된 탈묵제를 폐지 재활용 공정에 투입하고 각각 펄핑 공정 (시료 조성 ONP : OMG = 5 : 5, 농도 15%, 온도 $45^{\circ}C$, 펄핑 시간 20분) 과 flotation 공정 (농도 1%, 온도 $45^{\circ}C$, air flow 7 L/min, 반응시간 8분) 처리 전, 후의 ERIC과 brightness를 측정하여 잉크의 제거 효율을 평가하였다. 또한 hyperwashing 전, 후의 ERIC과 brightness도 측정하여 잉크의 재흡착 여부도 평가하였다. 포화 지방산 Lauric acid 보다 불포화 지방산 Oleic acid를 $80^{\circ}C$에서 KOH로 검화 반응시키고 EO/PO를 추가 혼합하여 액상 탈묵제를 대량 제조하였다. 대량 생산한 액상 탈묵제는 제지 회사의 탈묵 공정 현장에 직접 투입하였을 때, 거품의 사이즈가 커지고 reject의 색깔이 짙어지면서 잉크의 포집력이 좋아진 것을 확인할 수 있었다. flotation 전, 후 백색도는 4 point 정도 증가하던 것이 약 5 point로 1 point 정도가 더 증가였다. reject의 ERIC 값은 개발 제품을 사용했을 때 약 7%정도 낮아진 것을 확인할 수 있었다. 본 연구에서 개발한 액상 탈묵제의 탈묵 성능이 우수함을 알 수 있었다.

• 펄프종이기술
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• 제36권3호
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• pp.9-14
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• 2004

The useful fungi which secret extracellular enzymes was selected for deinking agent of old newsprint. Five fungal strains were isolated from a paper mill soil ground. The CMCase, FPase and xylanase activities of fungi on the liquid culture were investigated at optimal growth conditions. The results of this study were as follow: The optimal pH and temperature for culture growth were 4～8 and 27～$35^{\circ}C$, respectively. For screening of extracellular enzymes at optimal culture conditions the optimal culture period were less than 6-7 days. Fusarium pallidoroseum and Aspergiilus niger which shows relatively higher CMCase, FPase and xylanase activities than the other species were selected for further enzymatic deinking research.

• 펄프종이기술
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• 제47권6호
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• pp.164-169
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• 2015

Nowadays blending ratio of OMG (old magazine) in recovered paper used for manufacturing newspaper have been increased. When large amount of OMG is consumed in newsprint mill, brightness can be improved by inorganic pigments of coating layer. On the other hand decrease in yield of deinking process will be encountered because the pigments can be removed as reject of froth flotation process. Therefore selection of the optimal deinking agent is an important. Non-ionic surfactant have been used widely in newsprint mill. Non-ionic surfactant has amphoteric characteristics. Hydrophilic group is ethylene and propylene oxide that can induce hydrogen bonding with water molecules. In this regard, cloud point is an important parameter in order to control efficiency of deinking process because hydration of the hydrophobic group can be varied according to temperature of a system. In this study, deinking properties of ONP at high blending ratio of OMG was analyzed according to cloud points of non-ionic surfactants. $L^*$, $a^*$, $b^*$, brightness and effective residual ink concentration did not affected by the change of cloud points. Especially, flotation reject decreased significantly according to increase in cloud point of the non-ionic surfactant. Consequently, when a nonionic surfactant having a cloud point higher than the temperature of the system is used, properties of the deinked pulp can be maintained and yield of deinking process can be improved.

• 펄프종이기술
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• 제37권1호
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• pp.38-46
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• 2005

This study was focused on the optimum culture condition in CMCase, FPase and xylanase activities of two fungal strains that secret extracellular enzymes for using enzymatic deinking agent to old newsprint. The results of this study were as follows. When Fusarium pallidoroseum was grown on the medium, containing of rice bran+xylan $2.0\%,\;peptone\;0.6\%,\;KH_2PO_4\;0.075\%\;and\;MnSO_4\;0.06\%\;with\;pH\;9.0,\;at\;29^{\circ}C$ for 6 days, the quantitative degree of extracellular enzyme production was the highest. Optimum culture condition for Aspergillus niger was pH 5.0, $27^{\circ}C$ incubating temperature and 7 days incubation period on liquid medium, containing of CMC+xylan $2.5\%,\;yeast\;extract\;0.4\%,\;K_3PO_4\;0.05\%\;and\;CaCl_2+FeSO_4\;0.08\%$. Aspergillus niger was fairly higher FPase and xylanase activities than Trichoderma reesei ATCC 28217.