• Bulletin of the Korean Chemical Society
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• v.8 no.6
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• pp.466-470
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• 1987

Di-2-pyridyl thionocarbonate, prepared from thiophosgene and 2-hydroxypyridine in the presence of triethylamine in dichloromethane, was found to be very effective for dehydration, dehydrosulfurization, and thiocarbonyl transfer reactions. Di-2-pyridyl thionocarbonate was successfully for the esterification of carboxylic acids, dehydration of aldoximes into nitriles, preparation of isothiocyanates from amines, and preparation of cyclic thionocarbonates from 1,2- and 1,3-diols.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.284-284
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• 2012

In this study, $V_2O_5/TiO_2$ catalyst was measured reactivity of ethanol when vanadia ratio was increasing. First, $V_2O_5/TiO_2$ catalyst was prepared to the increasing vanadia ($VO_x$) ratio as 0.2, 1, 10 wt%. And we were used X-ray diffraction (XRD), then not appear markedly peak to pure vanadia about XRD analysis. So we were decided vanadia that was evenly dispersed on $TiO_2$. Result about temperature-programmed reduction (TPR) analysis was obtained 3 reactions that was dehydrogenationfrom obtained to acetaldehyde, dehydration from obtained to ethylene, condensation from obtained to diethyl ether. If vanadia ratio was increasing in $V_2O_5/TiO_2$, reactions temperature of ethanol was known lower. And condensation into diethyl ether is quenched away with increasing vanadia loading. In addition, competition between reductive dehydration and oxidative dehydrogenation occurs, while the selectivity toward dehydrogenation is favored with increasing vanadia loading.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.11a
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• pp.154-155
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• 2013

The aim of this work is to have a better knowledge of reactions that take place in a cement paste, blast furnace slag mixed cement paste and fly ash mixed cement paste and know about the change in chemical components exposed to elevated temperature. The results show that the dehydration reactions appeared differently in the each admixture mixed cement paste and can be used as tracers for determining the temperature history of concrete after a fire exposure.

• Bulletin of the Korean Chemical Society
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• v.26 no.4
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• pp.609-613
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• 2005

The fragmentation patterns and ion-molecule reactions of two alkyn alcohols, 2-propyn-1-ol (HC≡$CCH_2$OH) and 2-methyl-3-butyn-2-ol (HC≡CC($CH_3)_2$OH), were investigated using Fourier transform mass spectrometry (FTMS). The most abundant fragment ions formed from the molecular ions were [M-H]$^+$ for 2-propyn-1-ol and [M-$CH_3]^+$ for 2-methyl-3-butyn-2-ol. The dehydrated ion, [M-$H_2O]^+$ was formed only from 2-propyn-1-ol in which $\alpha$ -hydrogen atoms were available for $\alpha,\;\alpha$ -elimination reaction. The protonated molecules were dissociated into [M+H-$H_2O]^+$ and [M+H-$C_2H_2]^+$ through dehydration and deacetylenylation processes. The formations of [M+H-$H_2O]^+$ and [M+H-$C_2H_2]^+$ from 2-methyl-3-butyn-2-ol were more favorable than those from 2-propyn-1-ol due to stabilization by two methyl groups at $\alpha$ -carbon. Ion-neutral complexes formed at long ion trapping time gave dehydrated and/or deacetylenylated ion products by further dissociation.

• Current Research on Agriculture and Life Sciences
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• v.7
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• pp.175-184
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• 1989

Kinetics of ascorbic acid and browning that may use on the optimization of food dehydration were evaluated. Banana was chosen for this as the representative test material. We have described the destruction of ascorbic acid and browning as first and zero order reactions. The temperature dependence between two reactions were conducted with Arrhenius equation. Finally we have operated SPSS computer programs reapeatedly that we found very dose value of the parameter between result of ascorbic acid and browning. The attained Kinetic models were well prepared for the value of result experiments and the models may use on optimization for dehydration progress. Destruction rate of ascorbic acid and browning rate were low at initiation of progress, increased to show maximum at the low moisture on mid-progress and then decreased gradually. Freeze drying showed the most constant quality of product in this case.

• Bulletin of the Korean Chemical Society
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• v.25 no.10
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• pp.1538-1544
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• 2004

Fragmentations and proton transfer reactions of mono-, di-, and triethanolamines were studied using FTMS. It was found that the most abundant fragment ion was $[M-CH_2OH]^+$. The $[M-CH_2OH-H_2O]^+$ was observed in the mass spectra of diethanolamine and triethanolamine. By increasing the ion trapping time in the ICR cell, the $[M+H]^+$ and $[M+H-H_2O]^+$ ions were notably increased for all the samples while the $[M+H-2H_2O]^+$ was observed in the mass spectra of diethanolamine and triethanolamine. The proton transfer reactions between the fragment ions and neutral molecules occurred predominantly by increasing the ion trapping time. The rate constants for the proton transfer reactions were calculated from experimental results. The proton transfer reaction of $CHO^+$ was the fastest one, which is consistent with the heats of reaction. The rate constants for proton transfer reactions of triethanolamine were much slower than those of ethanolamine and diethanolamine because of the steric hindered structure of triethanolamine. The plausible structures of observed ions and heats of reaction for proton transfer were calculated with AM1 semiempirical method.

• Bulletin of the Korean Chemical Society
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• v.22 no.12
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• pp.1309-1315
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• 2001

Zirconium sulfate supported on zirconia catalysts were prepared by impregnation of powdered $Zr(OH)_4$ with zirconium sulfate aqueous solution followed by calcining in air at high temperature. The characterization of prepared catalysts was performed using Fourier transform infrared (FTIR), X-ray diffraction (XRD), differential scanning calorimetry (DSC), and by the measurement of surface area. The addition of zirconium sulfate to zirconia increased the phase transition temperature of $ZrO_2$ from amorphous to tetragonal due to the interaction between zirconium sulfate and zirconia, and the specific surface area and acidity of catalysts increased in proportion to the zirconium sulfate content up to 10 wt% of $Zr(SO_4)_2$. Infrared spectra of ammonia adsorbed on $Zr(SO_4)2}ZrO_2$ showed the presence of Bronsted and Lewis acid sites on the surface. $10-Zr(SO_4)_2}ZrO_2$ calcined at $600^{\circ}C$ exhibited maximum catalytic activities for 2-propanol dehydration and cumene dealkylation. The catalytic activities for both reactions were correlated with the acidity of catalysts measured by ammonia chemisorption method.

• Bulletin of the Korean Chemical Society
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• v.11 no.5
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• pp.403-406
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• 1990

Two types of new silica catalysts modified with benzenesulfonic acid derivatives were prepared by esterification or phenylation followed by sulfonation. Both catalysts thus prepared were tested as acid catalysts for 2-propanol dehydration and cumene dealkylation reactions. B catalyst () were more active than A catalyst (). Highter catalytic activity for B catalyst may be accounted for by higher resistance to water, higher acid strength, more acidity, and better thermal stability as compared with A catalyst.

• Membrane Journal
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• v.33 no.6
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• pp.305-314
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• 2023

Various methods for removing by-products from chemical reactions are being studied to improve yield of catalytic reaction. Since the water is predominantly generated as a by-product in industrially significant reactions, it is necessary to develop the technology that can reliably remove water over a wide range of temperatures. Although several strategies using absorbents and additional dehydration reactions, have been proposed, they have limitations due to the issues such as additional energy and time consuming steps and sustainability of conversion. Membrane technology, which offers advantages such as easy operation, installation, and low maintenance costs, proves to be a promising approach for enhancing the efficiency of catalysts in various catalytic reactions. Therefore, this review discusses the removal of by-products using membranes and the associated benefits in this context.

• Bulletin of the Korean Chemical Society
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• v.25 no.5
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• pp.657-664
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• 2004

Titanium sulfate supported on $TiO_2$was prepared by impregnation of powdered $TiO_2$with an aqueous solution of titanium sulfate followed by calcining in air at high temperature. For Ti$(SO_4)_2/TiO_2$ samples calcined at 300 $^{\circ}C$, no diffraction lines of titanium sulfate are observed at $Ti(SO_4)_2$loading up to 30 wt%, indicating good dispersion of $Ti(SO_4)_2$ on the surface of $TiO_2$. The acidity of the catalysts increased in proportion to the titanium sulfate content up to 20 wt% of $Ti(SO_4)_2$. 20 wt% $Ti(SO_4)_2/TiO_2$ calcined at 300 $^{\circ}C$ exhibited maximum catalytic activities for 2-propanol dehydration and cumene dealkylation. The catalytic activities for these reactions, were correlated with the acidity of catalysts measured by ammonia chemisorption method.