• Title/Summary/Keyword: degree of dispersion

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Evaluation of dispersion degree of nanoparticles in TiO2/epoxy resin nanocomposites

  • Nam, Ki-Woo;Moon, Chang-Kwon
    • Journal of Ocean Engineering and Technology
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    • v.28 no.4
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    • pp.338-344
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    • 2014
  • The purpose of this study was to evaluate the dispersion degree of particles using a nanoindentation test for titanium oxide nanoparticles/epoxy resin nanocomposites. Thus, the effects of the particle size and weight fraction, dispersion agent, and position of the sample on the modulus and degree of particle dispersion in the nanocomposites were investigated. As a result, the dispersion degree of large particles was found to be better than that of smaller particles in composites. It could be found that the aggregation or agglomeration of small particles with large surface energy occurred more easily in nanocomposites because of the large specific surface area. The moduli of the upper side of the film-shaped sample obtained from a nanoindentation test were low scattering, while the values for the bottom side were high scattering. Thus, the dispersion situation of the nanoparticles on the upper side of film-shaped samples could be considered to be better than that for the bottom side. This could be concluded due to the non-uniform nanoparticle dispersion in the same sample. The modulus obtained from nanoindentation test increased slightly with the content of nanoparticles and increased with the indented depth for the same sample. The latter is presumably due to the increase in the accumulated particles facing the indenter with the indented depth. The nanoindentation test was found to be a useful method to evaluate the dispersion status of nanoparticles in nanocomposites.

THE EXISTENCE OF PERIODIC SOLUTION OF A TWO-PATCHES PREDATOR-PREY DISPERSION DELAY MODELS WITH FUNCTIONAL RESPONSE

  • Zhang, Zhengqiu;Wang, Zhicheng
    • Journal of the Korean Mathematical Society
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    • v.40 no.5
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    • pp.869-881
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    • 2003
  • In this paper, a nonautonomous predator-prey dispersion delay models with functional response is studied. By using the continuation theorem of coincidence degree theory, the existence of a positive periodic solution for above models is established.

Prediction Method of Dispersion Condition for Reinforced Epoxy in Nano SiC Particles Using Capacitance Measurement (Capacitance 측정법을 이용한 나노 SiC 에폭시 복합재료의 내부 강화재 분산 예측방법)

  • Kwon, Dong-Jun;Wang, Zuo-Jia;Kim, Je-Jun;Jang, Key-Wook;Park, Joung-Man
    • Composites Research
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    • v.26 no.6
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    • pp.337-342
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    • 2013
  • The good dispersion of nano-materials in epoxy matrix was important parameter for the reinforcement effect, and the evaluation of dispersion degree was to prove it. This work was studied to predict the dispersion condition of nano-SiC powders in SiC/epoxy composites using capacitance measurement. Capacitance was defined to be the electric capacity in proportional to electron charge of the measuring section. In case of nano-SiC powders, the electron charge of SiC/epoxy composites was higher than that of neat epoxy resin. Capacitance was evaluated for each section of SiC/epoxy composites. The prediction of dispersion condition was verified by using capacitance measurement. Dispersion condition of nano-SiC powders in epoxy matrix was evaluated with two different dispersion methods, i.e., sonication and stirring methods. The dispersion degree was also verified with the tensile strength correlating to capacitance.

The Feasible Linkage between Pay Dispersion and Job Performance in the Case of U.S. Retail Sales Workers

  • KANG, Eungoo;HWANG, Hee-Joong
    • Journal of Distribution Science
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    • v.20 no.4
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    • pp.111-119
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    • 2022
  • Purpose: This study seeks to address the omission through examining the manner in which demographic similarity affects the responses of employees in the retail sector towards horizontal pay dispersion. Through doing so the study will be effective in bolstering the recent efforts of more careful exploration of conditions. Research design, data, and methodology: Scant past studies are available to guide for practitioners in retail sector which compensation strategy might lead adequate job performance for retail sales workers. To suggest possible solution, the present authors used variables of pay dispersion and obtained 317 US retail sale workers in distribution channels to measure the association between pay dispersion and employee job performance. Results: The statistical findings indicated both first and second hypothesis could be acceptable with favorable Beta and T values, resulting high degree of pay dispersion leads a low level of job performance, while a low degree of pay dispersion can motivate retail sales workers to improve their performance. Conclusions: The findings of this study raises an argument that processes of social comparison work in a more vigorous manner. This is thus a representation of the propensity of a retail sales worker to voluntarily resign from an organization when dispersion rates are higher.

Quantitative Analysis of Initial Dispersion Condition Effects on Randomness of Magnus Rotor Bomblet (Magnus Rotor 자탄의 초기 방출조건이 분산도에 미치는 영향에 대한 정량적 분석)

  • Bai, Ikhyun
    • Journal of the Korea Society for Simulation
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    • v.28 no.3
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    • pp.83-89
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    • 2019
  • This research describes quantitative effects of initial dispersion conditions upon the dispersion randomness of Magnus rotor bomblets. Ratios of the missile spin rate to the missile velocity, a, flight path angles, ${\gamma}$ and altitudes, h, were changed to investigate their effects on dispersion randomness. Dispersion was analyzed through calculation of 6 degree of freedom motion equation with aerodynamic coefficients from wind tunnel experiments. In order to analyze the randomness, regression analysis is adopted to calculate the coefficient of determination. The optimized ratio of the missile spin rate to the missile velocity and flight path angle were obtained and the dispersion altitudes had more effect on the dispersion diameter and had less effect on dispersion than other parameters.

One-Pot Synthesis of Clay-dispersed Poly(styrene-co-acrylonitrile) Copolymer Nanocomposite using Poly($\varepsilon$-caprolactone) as a Compatibilizer

  • Ko, Moon-Bae
    • Macromolecular Research
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    • v.8 no.4
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    • pp.186-191
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    • 2000
  • Clay-dispersed nanocomposites have been prepared by simple melt-mixing of three components, i.e. poly (styrene co-acrylonitrile) copolymer (SAN), poly ($\xi$-caprolactone ) (PCL), and an organophilic clay(Cloisite(R) 30A). In the present study, poly($\xi$-caprolactone) was added in the mixtures in order to facilitate the intercalation of SAN into the gallery of silicate layers, and the molecular weight effects of PCL on the dispersion of silicate layers were compared by changing the amount of added PCL. The degree of dispersion of 10-$\AA$-thick silicate layers of clay in the nanocomposites was investigated by using an X-ray diffractometer and a transmission electron microscope. It was found that PCL added in the mixture facilitate the intercalation of SAN copolymers into the galleries of silicate layers modified with an organic intercalant, resulting in the better dispersion of clay. It was, also, observed that the processing temperature influences the degree of clay dispersion.

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Quantitative Dispersion Evaluation of Carbon Nanotubes Reinforced Polymer Nano-composites (탄소나노튜브 첨가 고분자 나노복합재료의 정량적 분산도 평가)

  • Lee, Sang-Bok;Jeong, Bo-Hwa;Yi, Jin-Woo;Lee, Won-Oh;Um, Moon-Kwang
    • Polymer(Korea)
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    • v.35 no.1
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    • pp.60-65
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    • 2011
  • In order to maximize the performance of polymer nano-composites, it is essential to understand an effect of a dispersion state on material properties as well as to achieve highly dispersed composites. In this work, a simple quantitative approach to evaluate the degree of dispersion was suggested for carbon nanotube (CNT) embedded polymer nano-composites. Through UV-visible spectroscopy analysis, the transmittance of nano-composites was measured at various dispersion states and it was found that the transmittance reduced as the dispersion state of CNT improved. Based on the results, an effective concentration factor for quantitative evaluation of dispersion state was introduced into the Beer-Lambert transmittance law. The proposed method and parameter to evaluate the degree of dispersion were verified by analyzing the transmittances at different dispersion states of CNT, concentrations of CNT and sample thicknesses.

The dispersion of the flexural waves in a compound hollow cylinder under imperfect contact between layers

  • Ipek, Cengiz
    • Structural Engineering and Mechanics
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    • v.55 no.2
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    • pp.335-348
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    • 2015
  • The influence of the interface imperfect bonding on the flexural wave dispersion in the bilayered hollow circular cylinder is studied with utilizing three-dimensional linear theory of elastodynamics. The shear-spring type model is used for describing the imperfect bonding on the interface between the layers and the degree of the imperfectness is estimated through the dimensionless shear-spring parameters which enter the mentioned model. The method for finding the analytical expressions for the sought values and dispersion equation are discussed and detailed. Numerical results on the lowest first and second modes are presented and analyzed. These results are obtained for various values of the shear-spring parameters. According to these results, in particular, it is established that as a results of the imperfection of the bonding between the layers the new branches of the dispersion related the first fundamental mode arise and the character of the dispersion curve related to the second mode becomes more complicated.

The Quantitative Characterization of the Dispersion State of Single-Walled Carbon Nanotubes (단일벽 탄소나노튜브의 분산도 정량적 평가)

  • Yoon, Do-Kyung;Choi, Jae-Boong;Kim, Young-Jin;Baik, Seung-Hyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.4
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    • pp.483-489
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    • 2007
  • We have investigated quantitative measurement techniques of the degree of dispersion of single-walled carbon nanotubes (SWNTs). SWNTs were suspended in aqueous media using a sodium dodecyl sulfate (SDS) surfactant. SWNTs with different dispersion states were prepared by controlling the intensity and time of sonication and centrifugation. The laser spectroscopic techniques were employed to characterize the dispersion state; i.e., raman fluorescence and absorption spectroscopic techniques. Raman spectroscopy has been used to probe the dispersion and aggregation state of SWNTs in solution. Individually suspended SWNTs show increased fluorescence peaks and decreased roping peaks at a raman shift 267 $cm^{-1}$ compared with the samples containing bundles of SWNTs. The ultraviolet-visible-near infrared (UV-vis-NIR) absorption spectrum of decanted supernatant samples show sharp van Hove singularity peaks