• Title/Summary/Keyword: deep disposal

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Evaluation of Americium Solubility in Synthesized Groundwater: Geochemical Modeling and Experimental Study at Over-Saturation Conditions

  • Hee-Kyung Kim;Hye-Ryun Cho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.4
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    • pp.399-410
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    • 2022
  • The solubility and species distribution of radionuclides in groundwater are essential data for the safety assessment of deep underground spent nuclear fuel (SNF) disposal systems. Americium is a major radionuclide responsible for the long-term radiotoxicity of SNF. In this study, the solubility of americium compounds was evaluated in synthetic groundwater (SynDB3), simulating groundwater from the DB3 site of the KAERI Underground Research Tunnel. Geochemical modeling was performed using the ThermoChimie_11a thermochemical database. Concentration of dissolved Am(III) in Syn-DB3 in the pH range of 6.4-10.5 was experimentally measured under over-saturation conditions by liquid scintillation counting over 70 d. The absorption spectra recorded for the same period suggest that Am(III) colloidal particles formed initially followed by rapid precipitation within 2 d. In the pH range of 7.5-10.5, the concentration of dissolved Am(III) converged to approximately 2×10-7 M over 70 d, which is comparable to that of the amorphous AmCO3OH(am) according to the modeling results. As the samples were aged for 70 d, a slow equilibrium process occurred between the solid and solution phases. There was no indication of transformation of the amorphous phase into the crystalline phase during the observation period.

An analytical solution for compaction grouting problem considering exothermic temperature effect of slurry

  • Chao Li;Yingke Liu;Man Yuan;Tengrui Yang
    • Geomechanics and Engineering
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    • v.35 no.6
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    • pp.593-601
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    • 2023
  • In this paper, an analytical solution of large-strain cylindrical cavity expansion in compaction grouting problem under temperature field is given. Considering the stress increment caused by temperature, the analytical solution of cavity expansion under traditional isothermal conditions is improved by substituting the temperature stress increment into the cavity expansion analysis. Subsequently, combined with the first law of thermodynamics, the energy theory is also introduced into the cylindrical cavity expansion analysis, and the energy dissipation solution of cylindrical cavity expansion is derived. Finally, the validity and reliability of solution are proved by comparing the results of expansion pressure with those in published literatures. The results show that the dimensionless expansion pressure increases with the increase of temperature, and the thermal response increases with the increase of dilation angle. The higher the exothermic temperature of grouting slurry, the greater the plastic deformation energy of the surrounding soil, that is, the greater the influence on the surrounding soil deformation and the surrounding environment. The proposed solution not only enrich the theoretical system of cavity expansion, but also can be used as a theoretical tool for energy geotechnical engineering problems, such as CPT, nuclear waste disposal, energy pile and chemical grouting, etc.

Acoustic emission characteristics under the influence of different stages of damage in granite specimens

  • Jong-Won Lee;Tae-Min Oh;Hyunwoo Kim;Min-Jun Kim;Ki-Il Song
    • Geomechanics and Engineering
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    • v.37 no.2
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    • pp.149-166
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    • 2024
  • The acoustic emission (AE) technique is utilized to estimate the rock failure status in underground spaces. Understanding the AE characteristics under loading conditions is essential to ensure the reliability of AE monitoring. The AE characteristics depend on the material properties (p-wave velocity, density, UCS, and Young's modulus) and damage stages (stress ratio) of the target rock mass. In this study, two groups of granite specimens (based on the p-wave velocity regime) were prepared to explore the effect of material properties on AE characteristics. Uniaxial compressive loading tests with an AE measurement system were performed to investigate the effect of the rock properties using AE indices (count index, energy index, and amplitude index). The test results were analyzed according to three damage stages classified by the stress ratio of the specimens. Count index was determined to be the most suitable AE index for evaluating rock mass stability.

Geochemical Characteristics of Deep Granitic Groundwater in Korea (국내 화강암질암내 심부지하수의 지구화학적 특성)

  • 이종운;전효택;전용원
    • Journal of the Korean Society of Groundwater Environment
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    • v.4 no.4
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    • pp.199-211
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    • 1997
  • As a part of study on geological disposal of radioactive waste, hydrogeochemical characteristics of deep granitic groundwater in Korea were investigated through the construction of a large geochemical dataset of natural water, the examination on the behaviour of dissolved constituents, and the consideration of phase stability based on thermodynamic approach. In granitic region, the contents of total dissolved solids increase progressively from surface waters to deep groundwaters, which indicates the presence of more concentrated waters at depth due to water-rock interaction. The chemical composition of groundwater evolves from initial $Ca^{2+}$-(C $l^{-}$+S $O_4$$^{2-}$) or $Ca^{2+}$-HC $O_3$$^{-}$ type to final N $a^{+}$-HC $O_3$$^{-}$ or N $a^{+}$-(C $l^{-}$+S $O_4$$^{2-}$) type, via $Ca^{2+}$-HC $O_3$$^{-}$ type. Three main mechanisms seem to control the chemical composition of groundwater in the granitic region; 1) congruent dissolution of calcite at shallower depth, 2) calcite precipitation and incongruent dissolution of plagioclase at deeper depth, and 3) kaolinite-smectite or/and kaolinite-illite reaction at equilibrium at deeper depth. The behaviour of dissolved major cations (C $a^{2+}$, $K^{+}$, $Mg^{2+}$, M $a^{+}$) and silica is likely to be controlled by these reactions.

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A Study on Natural Ventilation by the Caloric Values of HLW in the Deep Geological Repository (지하처분장내 고준위 방사성 폐기물 발열량에 따른 자연환기력 연구)

  • Roh, Jang-Hoon;Choi, Heui-Joo;Yu, Yeong-Seok;Yoon, Chan-Hoon;Kim, Jin
    • Tunnel and Underground Space
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    • v.21 no.6
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    • pp.518-525
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    • 2011
  • In this study, the natural ventilation pressure resulting from the large altitude difference which is a characteristic of high radioactive waste repository and the caloric value of the heat emitted by wastes was calculated and based on the results, natural ventilation quantities were calculated. A high radioactive waste repository can be considered as being operated through closed cycle thermodynamic processes similar to those of thermal engines. The heat produced by the heating of high radioactive wastes in the underground repository is added to the surrounding air, and the air goes up through the upcast vertical shaft due to the added heat while working on its surroundings. Part of the heat added by the work done by the air can be temporarily changed into mechanical energy to promote the air flow. Therefore, if a sustained and powerful heat source exists in the repository, the heat source will naturally enable continued cyclic flows of air. Based on this assumption, the quantity of natural ventilation made during the disposal of high radioactive wastes in a deep geological layer was mathematically calculated and based on the results, natural ventilation pressure of $74{\sim}183$Pa made by the stack effect was identified along with the resultant natural ventilation quantity of $92.5{\sim}147.7m^3/s$. The result of an analysis by CFD was $82{\sim}143m^3/s$ which was very similar to the results obtained by the mathematical method.

Geological Factor Analysis for Evaluating the Long-term Safety Performance of Natural Barriers in Deep Geological Repository System of High-level Radioactive Waste (지질학적 심지층 처분지 내 천연방벽의 고준위 방사성 폐기물 장기 처분 안전성 평가를 위한 지질학적 인자 분석)

  • Hyeongmok Lee;Jiho Jeong;Jaesung Park;Subi Lee;Suwan So;Jina Jeong
    • Economic and Environmental Geology
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    • v.56 no.5
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    • pp.533-545
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    • 2023
  • In this study, an investigation was conducted on the features, events, and processes (FEP) that could impact the long-term safety of the natural barriers constituting high-level radioactive waste geological repositories. The FEP list was developed utilizing the IFEP list 3.0 provided by the Nuclear Energy Agency (NEA) as foundational data, supplemented by geological investigations and research findings from leading countries in this field. A total of 49 FEPs related to the performance of the natural barrier were identified. For each FEP, detailed definitions, classifications, impacts on long-term safety, significance in domestic conditions, and feasibility of quantification were provided. Moreover, based on the compiled FEP list, three scenarios that could affect the long-term safety of the disposal facility were developed. Geological factors affecting the performance of the natural barrier in each scenario were selected and their relationships were visualized. The constructed FEP list and the visualization of interrelated factors in various scenarios are anticipated to provide essential information for selecting and organizing factors that must be considered in the development of mathematical models for quantitatively evaluating the long-term safety of deep geological repositories. In addition, these findings could be effectively utilized in establishing criteria related to the key performance of natural barriers for the confirmation of repository sites.

Production and Application of Domestic Input Data for Safety Assessment of Disposal (처분안전성평가를 위한 국내고유 입력자료의 확보와 적용)

  • Park, Chung-Kyun;Lee, Jae-Kwang;Baik, Min-Hoon;Lee, Youn-Myoung;Ko, Nak-Youl;Jeong, Jong-Tae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.3
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    • pp.161-170
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    • 2012
  • To provide domestic values of input parameters in a safety assessment of radioactive waste disposal under domestic deep underground environments, various kinds of experiments have been carried out under KURT (KAERI Underground Research Tunnel) conditions. The input parameters were classified, and some of them were selected for this study by the criteria of importance. The domestic experimental data under KURT environments were given top priority in the data review process. Foreign data under similar conditions to KURT were also gathered. The collected data were arranged and the statistical calculations were processed. The properties and distribution of the data were explained and compared to foreign values in view of their validity. The following parameters were analysed: failure time and early time failure rate of a container, solubility of nuclides, porosity and density of the buffer, and distribution coefficients of nuclides in the geomedia, hydraulic conductivity, diffusion depth of nuclides, groundwater flow rate, fracture aperture, length of internal fracture, and width of faulted rock mass in the host rock.

Effects of Excavation Damaged Zone on Thermal Analysis of Multi-layer Geological Repository (다층 심지층처분장 열해석에 미치는 암반손상대의 영향)

  • Cho, Won-Jin;Kim, Jin-Seop;Kim, Geon Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.17 no.1
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    • pp.75-94
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    • 2019
  • As the present single-layer repository concept requires too large an area for the site of the repository, a multi-layer repository concept has been suggested to improve the disposal density. The effects of the excavation damaged zone around the multi-layer repository constructed in the deep host rock on the temperature distribution in the repository were analyzed. For the thermal analysis of the multi-layer repository, the hydrothermal model was used to consider the resaturation process occurring in the buffer, backfill and rock. The existence of an excavation damaged zone has a significant effect on the temperature distribution in the repository, and the maximum peak temperatures of double-layer and triple-layer repositories can rise to $7^{\circ}C$ and $12^{\circ}C$, respectively depending on the size of the excavation damaged zone and the degree of decrease of the thermal conductivity. The dominant factor affecting the peak temperature in the multi-layer repository is the decrease of thermal conductivity in the excavation damaged zone, and the excavation damaged zone formed around the deposition hole has more significant effects on the peak temperature than does the excavation damaged zone formed around the disposal tunnel.

Experimental Study on Frictional Healing Behavior of Rock Joints in the Natural Barriers under Hydro-Mechanical Conditions (천연방벽 내 암반 절리의 수리-역학적 조건에서의 마찰회복 거동에 대한 실험적 연구)

  • Yong-Ki Lee;Seungbeom Choi;Kyung-Woo Park;Jin-Seop Kim;Taehyun Kim
    • Tunnel and Underground Space
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    • v.33 no.1
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    • pp.42-56
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    • 2023
  • In deep geological disposal of high-level radioactive waste (HLW), the natural barrier must physically support the disposal facility and delay the movement of radionuclides for at least hundreds of thousands of years. To evaluate the long-term geological evolution of the natural barriers, it is essential to analyze the long-term behavior of rock joints, including the frictional healing behavior. This study aimed to experimentally analyze the frictional healing behavior of rock joints under hydro-mechanical (H-M) conditions through the slide-hold-slide (SHS) test. The SHS tests were performed under mechanical and H-M conditions for joint specimens of different roughness. In the H-M conditions, the frictional healing rate tended to increase, which was more evident in the specimens with large roughness. In addition, it was confirmed that the effect of the hydro-mechanical conditions was more significant when the effective normal stress acting on the joint surface was small. These results are expected to be used as fundamental data to understand the frictional healing behavior of rock joints in the natural barriers.

Comparison and Analysis of Field Hydraulic Tests to Evaluate Hydraulic Characteristics in Deep Granite Rockmass (심부 화강암반의 수리특성 평가를 위한 현장수리시험 비교 및 해석 연구)

  • Dae-Sung Cheon;Heejun Suk;Seong Kon Lee;Tae-Hee Kim;Ki Seog Kim;Seong-Chun Jun;SeongHo Bae
    • Tunnel and Underground Space
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    • v.34 no.4
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    • pp.393-412
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    • 2024
  • In selecting a disposal site for high-level radioactive waste, the hydrogeological research of the site is very important, and the hydraulic conductivity and the storage coefficient are key parameters. In this study, the hydraulic conductivity obtained by two different types of field hydraulic test equipment and methods was compared and analyzed for the deep granite rockmass in the Wonju area to understand the hydraulic characteristics of the deep granite rockmass. One was to perform the lugeon test, constant pressure injection test, and slug test at a maximum depth of 602.0 m by using the auto pressure/flow injection system, and the calculated hydraulic conductivity ranged from 1.26E-9 to 4.16E-8 m/s. In the overall depth, the maximum and minimum differences of the hydraulic conductivity were found to be about 33 times, and in the same test section, the difference by test method or analysis method was 1.13 to 8.25 times. In the other, the hydraulic conductivity calculated by performing a constant pressure injection test and a pulse test at a maximum depth of 705.1 m using the deep borehole hydraulic testing system was found to be 1.60E-10 to 2.05E-8 m/s, and the maximum and minimum differences were found to be about 130 times. In the constant pressure injection test, the difference depending on the analysis method was found to be 1.02 to 2.8 times. The hydraulic conductivity calculated by the two test equipment and methods generally showed similar ranges as E-9 and E-8 m/s, and no clear trend was observed according to depth. It was found that the granite rockmass in the Wonju area where the field hydraulic test was conducted showed low or very low rockmass permeability, and although there are differences in the range of hydraulic conductivity and the depth of application that can be measured depending on the applied test equipment and test method, it is generally believed that reliable results were presented.