• Title/Summary/Keyword: decay properties

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Theoretical Study of Auger Recombination of Excitons in Monolayer Transition-metal Dichalcogenides

  • Lee, Hyun Cheol
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1735-1743
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    • 2018
  • Excitons are the most prominent features of the optical properties of monolayer transition-metal dichalcogenides(TMDC). In view of optoelectronics it is very important to understand the decay mechanisms of the excitons of these materials. Auger recombination of excitons are regarded as one of the dominant decay processes. In this paper the Auger constant of recombination is computed based on the approach proposed by Kavoulakis and Baym. We obtain both temperature dependent (from type A, A' processes) and temperature independent (from type B, B' processes) contributions, and a numerical estimate of theoretical result yields the value of constant in the order of $10^{-2}cm^2s^{-1}$, being consistent with existing experimental data. This implies that Auger decay processes severely limit the photoluminescence yield of TMDC-based optoelectronic devices.

Physiological properties of grape cluster portions between cultivars and the effect of postharvest cooling on the marketability (포도 품종간 송이 부위별 생리적 특성과 수확 후 냉각과 유통성 관계)

  • Min, Jeong-Ho;Lim, Byung-Seon;Choi, Yeon-Soo;Lee, Kyung-Min;Kim, Dal-Woo;Hwang, Yong-Soo
    • Korean Journal of Agricultural Science
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    • v.39 no.1
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    • pp.1-8
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    • 2012
  • Rapid loss of grape berry quality after harvest occurs due to poor postharvest management. Understanding physiological properties between cultivars is required to develop practical technologies to control fast quality deterioration of tables grapes. Physiological characteristics of whole cluster, rachis and berries were examined to find their effects on postharvest behaviour of table grapes. 'Tamnara' showed high respiration rate and browning of rachis compared to 'Campbell Early'. Weight loss of rachis of 'Cheongsoo' was highest of three cultivars. Berry decay in 'Cheongsoo' begins at the connection portion between peduncle and berry, and berry decay of 'Cheongsoo' was the most severe among three cultivars. Precooling at $0^{\circ}C$ showed better results than cooling at $10^{\circ}C$ regardless of cultivars but cooling effect decreased when simulated marketing period increased up to 10 days. Plastic film wrapping was effective on reducing decay in general but not at higher marketing temperature. For successful commercialization of newly developed grapes, the inhibition technology of rachis browning in 'Tamnara' is required and decay control in 'Cheongsoo' through establishment of cold chain system is recommended.

Acoustic Properties of Three-room Coupled System by Connected Two Apertures (개구부로 연결된 3중 커플룸의 음향특성)

  • Na, Hae Joong;Lim, Byoung-Duk
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.26 no.3
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    • pp.340-349
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    • 2016
  • A coupled room system consists of adjacent rooms and apertures where the sound energy is exchanged between the two rooms. Acoustically, a coupled room system shows a non-exponential decay profile. Most of the related researches have been to analyze the acoustic properties of two-room coupled system so far whereas three-room coupled system were seldom studied. In this regard, this paper aims to analyse the distribution of sound pressure level, sound decay curve of three-room coupled system and sound energy flow between them by using the acoustic diffusion model and to further verify them through experiments. Firstly, the sound pressure level distribution and mean sound pressure level in the steady-state condition are analyzed at various frequencies and source locations. Good agreements are observed in both experiments and analysis results. Secondly, two double slope effect quantifiers of sound attenuation, LDT/EDT and LDT/T10 are compared at various frequencies and for different source locations. The result indicates that LDT/T10, less affected by the early reflection patterns than LDT/EDT, is more suitable to the analysis and experiments of a multi-slope sound decay curve. Lastly, the sound energy flow in each room is analyzed based on the acoustic diffusion model. After the early decay stage, the sound energy is observed to flow from the room with a long reverberation time to the room with a short one.

Deterioration and Preservation Technique of Wooden Cultural Properties (Part 2) -Biodeterioration of Square Post to Support Wooden Printing Blocks Shelves, Janggeongpanjeon- (목조문화재 열화 및 보존기술에 관한 연구(제2보) -장경각 구조부재중 실내 판가 기둥의 생물적 열화 특성-)

  • Kim, Yeong-Suk;Han, Sang-Mi
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.1
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    • pp.64-72
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    • 2007
  • The biodeterioration behaviors of square post to support the wooden printing blocks Shelves in the Janggeongpanjeon were investigated according to the positions and parts of square post, and environmental conditions. It was found that a high differences of deterioration in the progressing levels of wood decay, according to the positions and parts of square post, and environmental conditions. The decay levels were very high and still progressing in the contacted areas with stone foundation which are about up to 50 cm above it. In the decay type, white rot fungi was mainly affected in the inside of building which mainly made of softwood. The decay in the square posts to support the wooden printing block shelves inside of building was worse in the rear side, compared to front side. The insects was not found in most of square posts excluding the post which was neighboring at the infected round column by insect.

Comparison of Blue Luminescence Between Spark-processed Photoluminescian Silicon and Ambient Air Aged Anodically Etched Porous Silicon

  • Chang, Sung-Sik;Yoon, Sang-Ok
    • The Korean Journal of Ceramics
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    • v.2 no.3
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    • pp.137-141
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    • 1996
  • Ambient air aged anodically etched porous silicon (PS) and spark-processed silicon (sp-Si) show interesting similarities and dissimilarities in some of their luminescence-related properties. Among these similarties are: (1) the photoluminescence (PL) peak maximum in the blue/violet (410 nm);(2) the blue/violet PL peak positions are essentially unchanged with temperature ; (3) PL decay times in the nanosecond region which are independent of the detection wavelength, which is much faster in decay times compared to that of observed decay time in $SiO_2$.Among the dissimilarities are: (1) the PL intensity of blue/violet luminescence, namely, the PL intensity of sp-Si is at least 2 orders of magnitude larger than that of an ambient air aged PS; (2) the blue/violet PL intensity of sp-Si is more stable than that of ambient air aged PS under UV illuminations; (3) FTIR spectra of sp-Si favor those modes, which involve silicon -oxygen bonds in $SiO_2$ stoichiometry, whereas ambient air aged PS can be considered as a nonstoichiometric oxide judging from the observed vibrational spectra.

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The Influence of Moisture Contents on Decay and Carbonization in Flue-Cured Tobacco during Aging storage. (잎담배의 수분함량이 부패 및 탄화엽 발생에 미치는 영향)

  • 민영근;이경구;안동명;이완남
    • Journal of the Korean Society of Tobacco Science
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    • v.13 no.1
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    • pp.61-68
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    • 1991
  • The moisture contents of threshed leaf tobacco during aging storage were very important factor for the improvement or deterioration of leaf quality. Decay and carbonization of leaf tobacco were mainly controlled by moisture contents during storage. The influence of moisture contents on the decay and carbonization of threshed leaf tobacco (Flue-Cured, Var. NC 82. AB3O-1 grade) were examined during 1 year. The moisture contents of leaf tobacco were treated to 3 kg as 12% (controle), 16%, 20% and 24% after redrying, respectively, These tobacco were put into center of carton box containing about 200kg with 12%'s tobacco, and then packed and stored from June, 1988 under natural weather condition in warehouse at Ock-Cheon threshing plant. Samples were taken from dissected carton box at 0, 1, 2, 4, 7 and 12 months after moisture treatment and Racking time, and some chemical properties were investigated at every sampling time. In results of inducement to decay and carbonization of leaf tobaccos during 1 year's storage by moisture treatment. decayed leaf was appeared but carbonized leaf did not. Calorification and decayed leaf occurred at high moisture contents above 20%, and these phenomena were appeared between 30 and 150 days after moisture treatment and packing. High moisture content leaves (above 20%) caused nearby other leaves to be sunk with high moisture content. Nicotine and calcium contents were increased to 20%~30% and 10%~22%, respectively, but total sugar contents was decreased to 40%~60% by moisture treatment(20% ~24% ).

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Surface Analysis of Plasma-treated PDMS by XPS and Surface Voltage Decay

  • Youn, Bok-Hee;Park, Chung-Ryul;Kim, Nam-Ryul;Seo, Yu-Jin;Huh, Chang-Su;Lee, Ki-Taek
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.4
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    • pp.10-15
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    • 2002
  • Surface states of polydimethylsiloxane (PDMS) treated by plasma were investigated by the analysis by x-ray photoelectron spectroscopy (XPS) and surface voltage decay. Plasma treatment causes the silica-like(SiO$\_$x/, x=3∼4) oxidative layer, which is confirmed with XPS, and lowers surface resistivity from 1.78$\times$1014 Ω/square to 1.09$\times$10$\^$13/ Ω/square with increasing the plasma treatment time. By measuring the decay time constant of surface voltage, the calculated surface resistivity was compared with the value directly measured by a voltage-current method, so good agreement between two methods was obtained. It was observed that the plasma treatment led to decrease of the thermal activation energy of the surface conduction from 31.0 kJ/mol of untreated specimen to 21.8 kJ/mol. It is found that our results allow the examination of effects of plasma on electrical properties of PDMS.

On the study of two luminescence band structfue from ambient air aged porous silicon (대기중에서 aged된 다공성 실리콘의 2가지 발광 band에 관한 연구)

  • Sung-Sik Chang;Akira Sakai
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.4
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    • pp.564-570
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    • 1996
  • We have observed the red and blue luminescence from porous silicon (PS) without any rapid thermal oxidation. Aged porous silicon specimens prepared in dilute HF concentration, especially for the short duration of etching, display the increase of the blue band. The measured luminescence decay time at room temperature exhibits a decay time of about 100 ps and shows appreciably faster decay time than that of 20 K. No photoluminescence (PL) peak maximum shift is observed for the blue PL band at 77 K. However, the red PL band shows the blue shift and displays yellow luminescence at 77 K. The origin of red luminescence has some properties related to Si crystallites, whereas blue luminescence seems to be associated other than Si crystallites.

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Effects of Water Treating on Surface Properties of Epoxy Insulation Materials (Epoxy 절연재료이 표면특성에 미치는 수분처리의 영향)

  • Lim, Kyung-Bum;Lee, Duck-Chool
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.10
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    • pp.553-558
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    • 2000
  • This paper deals with change of contact angle, surface potential decay, surface resistivity and XPS of water-treated epoxy insulator. From the experimental results on the contact angle was reduced from $74^{\circ}$to $24^{\circ}$ due to the formation of polar hydroxyl groups on surface which was associated with intermolecular reaction between epoxy chains of three-dimensional network structure and water molecules. From the experimental results in the surface potential decay of water treated-samples, it was found that the accumulation of charge is decreased and the surface potential decay time is shortened by the interaction of polar hydroxyl groups induced on the treated surface as the increment of treatment time. The positive charging on the treated surface compared with negative charging is relatively lowered by the induction of polar hydroxyl groups. The surface resistivity was changed from $10^{15}[{\Omega}/cm^2$] to $10^{12}[{\Omega}/cm^2$] caused by water treatment. From XPS, it was found that the changes affected by the surface degradation of epoxy were caused by the generation of carboxyl groups through the chain decomposition and recombination with oxygen molecules in the air.

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Cathodoluminescence Properties of Novel $Mg_2SnO_4$:Mn Phosphor under Low-Voltage Electron Excitation

  • Kim, Kyung-Nam;Jung, Ha-Kyun;Park, Hee-Dong;Kim, Do-Jin
    • Journal of Information Display
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    • v.2 no.3
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    • pp.13-17
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    • 2001
  • The manganese-doped magnesium tin oxide with spinel structure was selected as a green phosphor for FED application and was synthesized by the solid state reaction. Its luminescence properties were investigated under low-voltage electron excitation. The $Mg_2SnO_4$:Mn phosphor showed green emission with the spectrum centered at 500 nm due to energy transfer from $^4T_1$ to $^6A_1$ of $Mn^{2+}$ ion. Optimum Mn concentration was 0.6 mole % and the decay time was shorter than 10 ms.

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