• 제목/요약/키워드: cylindrical pores

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Changing the Surface-Liquid Crystal Interaction through the Adsorption of Silica Nanoparticles

  • Finotello, Daniele;Jin, Tao
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.847-848
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    • 2004
  • We studied a low density 8CB liquid crystal-hydrophobic aerosil dispersions imbedded in submicron-size cylindrical pores. The nanosize spherical aerosil particles are adsorbed at the pore wall and hinder the planar anchoring. The adsorption is temperature dependent, and an axial to radial molecular configuration transition occurs within the cylindrical pores.

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Fabrication of Lotus Nickel Through Thermal Decomposition Method of Compounds under Ar Gas Atmosphere

  • Kim, Sang-Youl;Hur, Bo-Young;Nakajima, Hideo
    • Korean Journal of Materials Research
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    • v.19 no.5
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    • pp.270-275
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    • 2009
  • Lotus-type porous nickel with cylindrical pores was fabricated by unidirectional solidification under an Ar gas atmosphere using the thermal decomposition method of the compounds such as sodium hydroxide, calcium hydroxide, calcium carbonate, and titanium hydride. The decomposed gas does form the pores in liquid nickel, and then, the pores become the cylindrical pores during unidirectional solidification. The decomposed particles from the compounds do play a rule on nucleation sites of the pores. The behavior of pore growth was controlled by atmosphere pressure, which can be explained by Boyle's law. The porosity and pore size decreased with increasing Ar gas pressure when the pores contain hydrogen gas decomposed from calcium and sodium hydroxide and titanium hydride, ; however it they did not change when the pores contain containing carbon dioxide decomposed from calcium carbonate. These results indicate that nickel does not have the solubility of carbon dioxide. Lotus-type porous metals can be easily fabricated by the thermal decomposition method, which is superior to the conventional fabrication method used to pressurized gas atmospheres.

SAXS and AFM Study on Porous Silicon Prepared by Anodic Etching in HF-based Solution (SAXS와 AFM에 의한 HF-용액내 양극 에칭에 의해 제조된 기공성 실리콘의 구조연구)

  • Kim, Eu-gene;Kim, Hwa-Joong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.11
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    • pp.1218-1223
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    • 2004
  • Porous silicon materials have been shown to have bright prospects for applications in light emitting, solar cell, as well as light- and chemical-sensing devices. In this report, structures of porous silicon prepared by anodic etching in HF-based solution with various etching times were studied in detail by Atomic Force Microscopy and Small Angle X -ray Scattering technique using the high energy beam line at Pohang Light Source in Korea. The results showed the coexistence of the various pores with nanometer and submicrometer scales. For nanameter size pores, the mixed ones with two different shapes were identified: the larger ones in cylindrical shape and the smaller ones in spherical shape. Volume fractions of the cylindrical and the spherical pores were about equal and remained unchanged at all etching times investigated. On the whole uniform values of the specific surface area and of the size parameters of the pores were observed except for the larger specific surface area for the sample with the short etching time. The results implies that etching process causes the inner surfaces to become smoother while new pores are being generated. In all SAXS data at large Q vectors, Porod slope of -4 was observed, which supports the fact that the pores have smooth surfaces.

Fabrication of Cylindrical Macroporous Silicon and Diaphragms (원통형 메크로기공을 갖는 다공질 실리콘과 다이어프램의 제작)

  • 민남기;이치우;하동식;정우식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.8
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    • pp.620-627
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    • 1998
  • For chemical microsensors such as humidity and gas sensors, it is essential to obtain a single pore with a large inner surface and straight structure. In this paper, cylindrical macroporous silicon layers have been formed of p-silicon substrate by anodization in HF-ethanol-water solution with an applied current. The pores grew normal to the (100) surface and were uniformly distributed. The pore diameter was approximately $1.5~2{\mu}m$ with a depth of $20~30{\mu}m$ and the pores were not interconnected, which are in sharp contrast to the porous silicon reported previouly for similarly doped p-Si. Porous silicon diaphragms 18 to $200{\mu}m$ thick were formed by anistropic etching in TMAH solution and then anodization. The fabrication of macroporous silicon and free-standing diaphragms is expected to offer applications for microsensors, micromachining, and separators.

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Acoustic Characteristics of Sand Sediment Slab with Water- and Air-filled Pore

  • Roh Heui-Seol;Lee Kang Il;Yoon Suk Wang
    • Proceedings of the Acoustical Society of Korea Conference
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    • autumn
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    • pp.223-226
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    • 2001
  • Acoustic pressure transmission coefficient and phase velocity are measured as the functions of water porosity and air porosity in sand sediment slabs with water- and air-filled pores. Pores in the sand sediment slab we modeled as the structure of circular cylindrical tube shape filled with water and air. The first kind(fast) wave and second kind (slow) wave, identified by Biot, in the solid and fluid mixed medium are affected by the presence of water and air pores. Acoustic characteristics of such porous medium in water are also theoretically investigated in terms of the modified Biot-Attenborough (MBA) model, which uses the separate treatment of viscosity effect and thermal effect in non-rigid porous medium with water- and air-filed pores. The information on the fast waves introduces new concepts of the generalized tortuosity factor and dynamic shape factor.

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Nonlinear forced vibration of axially moving functionally graded cylindrical shells under hygro-thermal loads

  • Jin-Peng Song;Gui-Lin She;Yu-Jie He
    • Geomechanics and Engineering
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    • v.36 no.2
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    • pp.99-109
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    • 2024
  • Studying the dynamic behavior of axially moving cylindrical shells in hygro-thermal environments has important theoretical and engineering value for aircraft design. Therefore, in this paper, considering hygro-thermal effect, the nonlinear forced vibration of an axially moving cylindrical shell made of functionally graded materials (FGM) is studied. It is assumed that the material properties vary continuously along the thickness and contain pores. The Donnell thin shell theory is used to derive the motion equations of FGM cylindrical shells with hygro-thermal loads. Under the four sides clamped (CCCC) boundary conditions, the Gallekin method and multi-scale method are used for nonlinear analysis. The effects of power law index, porosity coefficient, temperature rise, moisture concentration, axial velocity, prestress, damping and external excitation amplitude on nonlinear forced vibration are explored through parametric research. It can be found that, the changes in temperature and humidity have a significant effect. Increasing in temperature and humidity will cause the resonance position to shift to the left and increase the resonance amplitude.

Effect of Pore Geometry on Gas Adsorption: Grand Canonical Monte Carlo Simulation Studies

  • Lee, Eon-Ji;Chang, Rak-Woo;Han, Ji-Hyung;Chung, Taek-Dong
    • Bulletin of the Korean Chemical Society
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    • v.33 no.3
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    • pp.901-905
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    • 2012
  • In this study, we investigated the pure geometrical effect of porous materials in gas adsorption using the grand canonical Monte Carlo simulations of primitive gas-pore models with various pore geometries such as planar, cylindrical, and random pore geometries. Although the model does not possess atomistic level details of porous materials, our simulation results provided many insightful information in the effect of pore geometry on the adsorption behavior of gas molecules. First, the surface curvature of porous materials plays a significant role in the amount of adsorbed gas molecules: the concave surface such as in cylindrical pores induces more attraction between gas molecules and pore, which results in the enhanced gas adsorption. On the contrary, the convex surface of random pores gives the opposite effect. Second, this geometrical effect shows a nonmonotonic dependence on the gas-pore interaction strength and length. Third, as the external gas pressure is increased, the change in the gas adsorption due to pore geometry is reduced. Finally, the pore geometry also affects the collision dynamics of gas molecules. Since our model is based on primitive description of fluid molecules, our conclusion can be applied to any fluidic systems including reactant-electrode systems.

Preparation of Biodegradable Porous Calcium Phosphate Ceramics for Bone Fillers (뼈 충진재용 생분해성 다공질 Calcium Phosphate 세라믹스의 제조)

  • Lee, Joong-Hwan;Kim, Suk-Young
    • Proceedings of the KOSOMBE Conference
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    • v.1996 no.05
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    • pp.130-132
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    • 1996
  • It is well known when porous calcium phosphate ceramics are used as a bone graft substitute, new tissues or blood vessels are grown into the porous implant due to their excellent biocompatibility. In this study, the ${\beta}$-crystalline form of calcium metaphosphate, $Ca(PO_{3})_{2}$ is prepared by the controlled thermolysis of monocalcium phosphate, $Ca(H_{2}PO_{4})_{2}$. The diameter of cylindrical pores formed during cooling was controlled by a holding time at the melting point of a monocalcium phosphate and by the change of a recrystallization temperature, to obtained the most appropriate size (about $200{\mu}m$) of pores. It was observed that the increasing holding time at the melting point of monocalcium phosphate results in the decreases of pore sizes.

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Finite Element Simulation of a Pore Closing Process during Upsetting in Open Die Forging (자유단조에서 업세팅 공정 중 기공 압착 과정의 유한요소 시뮬레이션)

  • Lee, M.C.;Cho, J.H.;Choi, I.S.;Jang, S.M.;Joun, M.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.79-83
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    • 2008
  • We carry out three-dimensional simulation of pore closing processes during upsetting in open die forging. Several pores on a plane section of a cylindrical material are traced at the same time and the results of hydrostatic pressure and effective strain are discussed to reveal the parameters affecting pore closing phenomena. Five different sizes of pores are also investigated by simulation to reveal the pore size effect in pore closing during upsetting. AFDEX 3D is employed for this study.

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Acoustic Characteristics of Sand Sediment with Circular Cylindrical Pores in Water (수중 원통형 다공성 모래퇴적물의 음향특성)

  • 윤석왕;이용주;노희설
    • The Journal of the Acoustical Society of Korea
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    • v.21 no.2
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    • pp.110-119
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    • 2002
  • Acoustic characteristics of water sediment were experimentally studied in laboratory. Water saturated sand sediment less than the grain size of 0.5 mm diameter is uniformly distributed in an acryl box (100 mm×100mm×42mm) with material thickness 1 mm. Pores in the acryl box are modeled as the structure of cylindrical pore tubes (diameter 3 mm and length 42 mm) filled with water. Cylindrical pore tubes have porosities 0%, 5%, 11%, 18% and 26 % controlled by the tube numbers. Transmitted acoustic waves through sand sediment specimen are analyzed as the functions of porosity and frequency from 0.3 MHz to 4 MHz. Transmitted acoustic waves are mixed with the first-kind wave from whole specimen and the second-kind wane from cylindrical pore tubes. For the center frequency 1 MHz, the first kind wave is dominant but for the center frequency 2.25 MHz, the second kind wave is dominant. In the case of the first-kind wave, as the porosity increases, the transmission coefficient decreases and the sound speed decreases to the sound speed of water. As the frequency increases, the transmission coefficient decreases but the sound speed is almost constant. In the case of the second-kind wave, as the porosity increases, the transmission coefficient increases but the sound speed is almost constant. The transmission coefficient and the sound speed are almost constant as a function of frequency.