• Title/Summary/Keyword: cyclic-voltammetry

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Hierarchically Structured, Functionalized Graphenes for a Highly Reversible Capacitive Charge Storage

  • Yu, Xu;Park, Ho Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.491.1-491.1
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    • 2014
  • Heteroatom phosphorous-doped graphene aerogel (PGA) with high surface area is successfully synthesized via hydrothermal method for high power and energy supercapacitors, including the advantage of three dimensional internetwork and constitutive graphene skeletons. The morphology of PGA was investigated by the scanning electron microscope, transmission electron microscope. The chemical structure and circumstances were confirmed by Raman and X-ray photoelectron spectroscopy, the phosphorus is successfully incorporated with the graphene sheets. As evidenced by electrochemical measurements, cyclic voltammetry and galvanostatic charge discharge, the hierarchically PGA has an unprecedented high capacitance, which contributes to the excellent high-rate performance of this material for supercapacitor application.

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The Electrical Conductivity and Electrochemical Characteristics of Amphiphilic Milecules Multilayer Film confined with Hetero Type (양친매성 다중층막의 전기적 도전성 및 전기적 특성)

  • 최인희;박수길;임기조;이주성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.269-272
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    • 1996
  • The electrochemical behavior of Ru complex and PD complex monolayer, deposited on conductive substrate by the Langmuir-Blodgett(LB) technique as monolayer and multilayer, has been studied by cyclic voltammetry. Monolayer films show stable reversible state. Atomic resolution imaging of LB highly-conductive, environmently stable organic films has been obtained by atomic force microscopy (AFM) showing their closely packed structure,

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Synthesis and Characterization of New Push-Pull Chromophores Containing BF2-Azopyrrole Derivatives

  • Ko, HayeMin
    • Journal of the Korean Chemical Society
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    • v.60 no.1
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    • pp.21-27
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    • 2016
  • Novel push-pull chromophores containing 5’-(4-(bis(9,9-dimethyl-9H-fluoren-2-yl)aniline (bisDMFA) as a donor and phenylazo-methylpyrrolyl-boron difluoride (PhAPy-BF2) as an acceptor were designed and synthesized by the Knoevenagel condensation reaction for organic solar cells. Various electron withdrawing moieties were effectively introduced using 2,4-dimethyl-1H-pyrrole to afford new asymmetric BF2-azopyrrole molecules that were characterized by UV-vis spectroscopy and cyclic voltammetry measurements.

Synthesis of Trimetallic Au@Pb@Pt Core-shell Nanoparticles and their Electrocatalytic Activity toward Formic Acid and Methanol

  • Patra, Srikanta;Yang, Hae-Sik
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1485-1488
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    • 2009
  • A facile, seed-mediated preparation method of trimetallic Au@Pb@Pt core-shell nanoparticles is developed. Au nanoparticles are the template seeds onto which sequentially reduced Pb and Pt are deposited. The trimetallic core-shell structure is confirmed by UV-Vis spectroscopy, TEM and EDS analysis, and cyclic voltammetry. The trimetallic Au@Pb@Pt core-shell nanoparticles show high electrocatalytic activity for formic acid and methanol electrooxidation.

Development of EDLC using aqueous polymeric gel electrolytel (수용성 고분자 젤 전해질을 이용한 전기이중층 커패시터 의 개발)

  • 오길훈;김한주;최원경;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.581-584
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    • 2001
  • For the first time, a totally solid state electric double layer capacitor has been fabricated using an alkaline polymer electrolyte and an activated carbon powder as electrode material. The polymer electrolyte serves both as separator as well as electrode binder. The capacitor has a three-layer structure; electrode-electrolyte-electrode. A cyclic voltammetry and constant current discharge have been used for the determination of the electro chemical performance of capacitors.

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Electrolyte-concentrations Effects on SEI Formation on Graphite Negative Electrode in EC-based Electrolyte Solutions (흑연전극상의 SEI 형성에 미치는 EC계 전해질 농도의 영향)

  • Choi, Dong-Gui;Jeong, Soon-Ki
    • Proceedings of the KAIS Fall Conference
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    • 2007.11a
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    • pp.356-358
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    • 2007
  • 본 논문에서는 농도가 다른 EC계의 전해질 용액 중에서 흑연의 Cyclic voltammetry(CV)를 측정하였다. CV후 전극표면에 생성된 SEI를 투과형 전자현미경으로 분석한 결과, PC계에서 얻어지는 결과와 유사하게 충 방전 반응 및 생성된 SEI의 성질이 전해질의 농도에 크게 의존하고 있음을 확인하였다.

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Behavior of RuO$_2$(100), (110) and (101) Single-Crystal Faces in H$_2$SO$_4$

  • Jeong, Gi-ho;Park, Hong-Lee
    • Bulletin of the Korean Chemical Society
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    • v.3 no.3
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    • pp.89-92
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    • 1982
  • The properties of $RuO_{2}(100)$, (101) and (110) single-crystal faces in sulfuric acid are investigated by cyclic voltammetry. The shapes of the current-voltage profiles for the (100) and (101) planes indicate mainly reversible Faradaic processes while that for the (110) face resembles that resulting from an irreversible Faradaic process.

Reaction Conditions and Mechanism of Electrolytic Reduction of Dibenzoylmethane$^\dag$

  • Kang, Sung-Chul;Chon, Jung-Kyoon
    • Bulletin of the Korean Chemical Society
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    • v.8 no.5
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    • pp.414-418
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    • 1987
  • Electrochemical reduction of dibenzoylmethane was studied on mercury electrode by means of cyclic voltammetry, polarography and potentiostatic measurements in ethanol-water system. In acidic solutions monomeric pinacol was produced by irreversible two-electron process while monomeric and dimeric pinacol were competitively produced by the same process in neutral solution. However, in basic solution the dimeric pinacol was mostly produced through radical by irreversible one-electron transfer process. Mechanisms of the reduction of dibenzoylmethane are deduced from Tafel slope, pH dependance and reaction order with respect to the concentration of dibenzoylmethane in the solution of various pH.

Electrochemical Behavior of Ce ion and Bi ion in LiCl-KCl Molten Salt

  • Kim, Beom-Kyu;Han, Hwa-Jeong;Park, Ji-Hye;Kim, Won-Ki;Park, Byung Gi
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2017.05a
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    • pp.227-228
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    • 2017
  • In this paper, electrolytic behavior of Cerium and Ce-Bi ion system was studied. The electrochemical behavior of Ce was studied in $LiCl-KCl-CeCl_3$ molten salts using electrochemical techniques Cyclic Voltammetry on tungsten electrodes at 773K. During the process of CV electrolysis, intermetallic compound were observed of Ce, Cex-Biy. Further study, in order to determine clarity of diffusion coefficient in this experiment, we will compare result of electrochemistry method and we also need to quantitative research.

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