• 한국자기공명학회논문지
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• 제17권1호
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• pp.47-53
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• 2013

Four new cyclic peroxide compounds (1~4) were isolated from the marine sponge Plakortis simplex. Their structures including relative stereochemistry were determined by MS and NMR analysis. All compounds, a side carbon chain with 10 carbons, were very unstable. After transformation into methyl ester analogues, the structure determination was conducted. Compounds 1a and 2a are stereoisomers, assigned as $3S^*$, $4S^*$, $6R^*$ and $3R^*$, $4S^*$, $6R^*$, respectively. Similarly, compounds 3a and 4a, replaced the methoxy group with an aliphatic methyl, are also stereoisomers. Compounds 1a and 2a exhibited the strong antifungal effect against the fungus Candida albicans.

• 한국강구조학회 논문집
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• 제9권1호통권30호
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• pp.95-105
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• 1997

Structures subjected to strong seismic excitation may undergo inelastic deformation cycles. The resulting cumulative fatigue damage process reduces the ability of structures and components to withstand seismic loads. Yet, the present earthquake resistance design methods focus mainly on the maximum displacement ductility, ignoring the effect of the cyclic responses. The damage parameters closely related to the cumulative damage need to be properly reflected on the aseismic design methods. In this study, two cumulative damage assessment methods derived from the plastic fatigue theory are investigated. The one is based on the hysteretic ductility amplitude, and the other is based on the dissipated hysteretic energy. Both methods can consider the maximum ductility and the cyclic behavior of structural response. The validity of two damage methods has been examined for single degree of freedom structures with various natural frequencies against two different earthquake excitations.

• Nuclear Engineering and Technology
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• 제30권5호
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• pp.387-395
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• 1998

In general, the laminated rubber bearing (LRB), a composite structure laminated with the elastic rubber and steel plates, has a complex hysteretic nonlinear characteristics in relationships between the restoring force and shear deflection. The representative nonlinear characteristics of LRB include the change of hysteresis loop with cyclic shear deflections and the hardening effects at large shear deflection regions. Changes of the hysteresis loop of LRB with cyclic shear deflections affect the horizontal stiffness and the damping characteristics. The hardening behavior of LRB in large shear deflection region results in an increased horizontal stiffness and therefore, has a great impacton the seismic responses. In this paper, the seismic response analysis is carried out using the modified hysteretic bi-linear model of LRB, which takes into account the hysteresis loop change and the hardening behavior with cyclic shear deflection. The results on seismic responses are compared with those obtained using the widely used hysteretic hi-linear model. The new model is found to reveal the greater amount of peak acceleration response.

• 한국응용과학기술학회지
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• 제27권4호
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• pp.531-538
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• 2010

The electrochemistry characterization of metal is important in many industrial applications. In this study, we investigated the C-V diagrams related to the electrochemistry characterization of nickel. We determined electrochemical measurement by using cyclic voltammetry with a three electrode system. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650mV and measured to the initial point. The scan rate were 100, 150, 200 and 200mV/s. As a result, the C-V characterization of nickel using ethanolamine and ethylethanolamine inhibitor appeared irreversible process caused by the oxidation current from the cyclic voltammogram. After adding ethanolamine compound additive, adsorption film constituted, and the passive phenomena happened. According to the results by cyclic voltammetry method, it was revealed that the effect of the electrochemistry characterization of nickel depends on ethanolamine structure interaction to adsorption complex.

• Steel and Composite Structures
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• 제7권5호
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• pp.391-404
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• 2007

This paper presents push-out tests of stud shear connectors to examine their fatigue behavior for developing a new composite bridge deck system. The fifteen push-out specimens of D16 mm stud welded on 9 mm steel plate were fabricated according to Eurocode-4, and a series of fatigue endurance test and residual strength test were performed. Additionally, the stiffness and strength variations by cyclic loading were compared. The push-out test, when the stiffness reduction ratio of the specimens was 0.95 under cyclic load, resulted in the failure of the studs. The stiffness variation of the push-out specimens additionally showed that the application of cyclic loads reduced the residual strength. The fatigue strength of the shear connectors were compared with the design values specified in the Eurocode-4, ASSHTO LRFD and JSSC codes. The comparison result showed that the fatigue endurance of the specimens satisfies the design values of these codes.

• Earthquakes and Structures
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• 제14권6호
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• pp.551-565
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• 2018

Experimental testing is considered the most realistic approach to obtain a detailed representation of the nonlinear behaviour of masonry-infilled reinforced concrete (RC) structures. Among other applications, these tests can be used to calibrate the properties of numerical models such as simplified macro-models (e.g., strut-type models) representing the masonry infill behaviour. Since the significant cost of experimental tests limits their widespread use, alternative approaches need to be established to obtain adequate data to validate the referred simplified models. The proposed paper introduces a detailed finite element modelling strategy that can be used as an alternative to experimental tests to represent the behaviour of masonry-infilled RC frames under earthquake loading. Several examples of RC infilled frames with different infill configurations and properties subjected to cyclic loading are analysed using the proposed modelling approach. The comparison between numerical and experimental results shows that the numerical models capture the overall nonlinear behaviour of the physical specimens with adequate accuracy, predicting their monotonic stiffness, strength and several failure mechanisms.

• Structural Engineering and Mechanics
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• 제55권5호
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• pp.913-929
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• 2015

The ratcheting and strain cyclic behaviour of joined conical-cylindrical shells under uniaxial strain controlled, uniaxial and multiaxial stress controlled cyclic loading are investigated in the paper. The elasto-plastic deformation of the structure is simulated using Chaboche non-linear kinematic hardening model in finite element package ANSYS 13.0. The stress-strain response near the joint of conical and cylindrical shell portions is discussed in detail. The effects of strain amplitude, mean stress, stress amplitude and temperature on ratcheting are investigated. Under strain symmetric cycling, the stress amplitude increases with the increase in imposed strain amplitude. Under imposed uniaxial/multiaxial stress cycling, ratcheting strain increases with the increasing mean/amplitude values of stress and temperature. The abrupt change in geometry at the joint results in local plastic deformation inducing large strain variations in the vicinity of the joint. The forcing frequency corresponding to peak axial ratcheting strain amplitude is significantly smaller than the frequency of first linear elastic axial vibration mode. The strains predicted from quasi static analysis are significantly smaller as compared to the peak strains from dynamic analysis.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.225-228
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• 2004

In order to estimate the chloride ion penetration, the model, which considers diffusion and sorption, is proposed on the basis of Finite Element Method (FEM). The FEM program provides the estimation of chloride concentration according to cyclic humidity and sorption. After the humidity diffusion analysis is carried out, the chloride ion diffusion and sorption analysis are conducted on the basis of the preestimated humidity data in each element. Each element has different analysis variables at different ages and locations. At early ages and constant outer humidity, the difference between inner and outer relative humidity causes the chloride ion penetration by sorption. As the humidity diffusion reduces the difference with age, the effect of sorption on the chloride ion penetration decreases. By the way, the cyclic humidity increases the effect of sorption on the chloride ion penetration at early ages, and the quantity of chloride ion around steel at later ages. Therefore, the in-situ analysis of chloride ion penetration for marine concrete structures must be performed considering the cyclic humidity condition and the long term sorption.

• Bulletin of the Korean Chemical Society
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• 제31권4호
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• pp.874-880
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• 2010

A series of 13- and 14-membered cyclic enkephalin analogs based on the moderately $\mu$ selective prototype compound Tyr-C[D-$A_2bu$-Gly-Phe-Leu] 8a were synthesized to investigate the structure-activity relationship. The modifications of sequence were mainly focused on two positions 3 and 5, critical for the selective recognition for $\mu$ and $\delta$ opioid receptors. The substitution of hydrophobic $Leu^5$ with hydrophilic $Asp^5$ derivatives led to Tyr-C[D-$A_2bu$-Gly-Phe-Asp(N-Me)] 7 and Tyr-C[D-Glu-Phe-gPhe-rAsp(O-Me)] 5, the peptides with a large affinity losses at both $\mu$ and $\delta$ receptors. The substitution of $Phe^3$ with $Gly^3$ led to Tyr-C[D-Glu-Gly-gPhe-rLeu] 3 and Tyr-C[D-Glu-Gly-gPhe-D-rLeu] 4, the peptides with large affinity losses at $\mu$ receptors, indicating the critical role of phenyl ring of $Phe^3$ for $\mu$ receptor affinities. One atom reduction of the ring size from 14-membered analogs Tyr-C[D-Glu-Phe-gPhe-(L and D)-rLeu] 6a, 6b to 13-membered analogs Tyr-C[D-Asp-Phe-gPhe-(L and D)-rLeu] 1, 2 reduced the affinity at both $\mu$ and $\delta$ receptors, but increased the potency in the nociceptive assay, indicating the ring constrain is attributed to high nociceptive potency of the analogs. For the influence of D- or L-chirality of $Leu^5$ on the receptor selectivity, regardless of chirality and ring size, all cyclic diastereomers displayed marked $\mu$ selectivity with low potencies at the $\delta$ receptor. The retro-inverso analogs display similar or more active at $\mu$ receptor, but less active at $\delta$ receptor than the parent analogs.

• Computers and Concrete
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• 제7권3호
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• pp.203-220
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• 2010

In the present study, exterior beam-column sub-assemblage from a regular reinforced concrete (RC) building has been considered. Two different types of beam-column sub-assemblages from existing RC building have been considered, i.e., gravity load designed ('GLD'), and seismically designed but without any ductile detailing ('NonDuctile'). Hence, both the cases represent the under-designed structure at different time frame span before the introduction of ductile detailing. For designing 'NonDuctile' structure, Eurocode and Indian Standard were considered. Non-linear finite element (FE) program has been employed for analysing the sub-assemblages under cyclic loading. FE models were developed using quadratic concrete brick elements with embedded truss elements to represent reinforcements. It has been found that the results obtained from the numerical analysis are well corroborated with that of experimental results. Using the validated numerical models, it was proposed to correlate the energy dissipation from numerical analysis to that from experimental analysis. Numerical models would be helpful in practice to evaluate the seismic performance of the critical sub-assemblages prior to design decisions. Further, using the numerical studies, performance of the sub-assemblages with variation of axial load ratios (ratio is defined by applied axial load divided by axial strength) has been studied since many researchers have brought out inconsistent observations on role of axial load in changing strength and energy dissipation under cyclic load.