• Journal of the Korean Chemical Society
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• v.37 no.10
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• pp.888-894
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• 1993

The electrochemical behaviors of copper-1-(2-pyridylazo)-2-naphthol(Cu-PAN) complex in acetonitrile (AN) solution have been investigated by the use of cyclic voltammetry, DC-polarography, controlled potential coulometry and UV-Vis spectroscopy. Cu-PAN complex in acetonitrile exhibit three reduction waves at -1.27 V, -1.64 V and -2.08 V vs. Ag/AgNO$_3$(AN). The numbers of electron involved in each reduction step was calculated with controlled potential coulometry, and reduction product was identified with UV-Vis spectrum. As the result, we proposed the reduction mechanism of the Cu-PAN complex in acetonitrile.

• KCI Concrete Journal
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• v.12 no.1
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• pp.23-34
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• 2000

Experiments were carried out to investigate the seismic behaviors, such as lateral strength, ductility and energy-dissipation capacity. of high-strength concrete (HSC) square short column confined in thin steel shell. The primary objective of the study was to investigate the suitability of using HSC square columns confined in thin steel shell in region of moderate-to-high seismic risk. A total of six columns, consisting of two ordinarily reinforced concrete square short columns and four reinforced concrete square short columns confined in thin steel shell was tested. Column specimens, short columns in a moment resisting frame with girder. were tested under a constant axial and reversed cyclic lateral loads. To design the specimens. transverse reinforcing methods, level of axial load applied, and the steel tube width-thickness ratio (D/t) were chosen as main parameters. Test results were also discussed and compared in the light of improvements in general behaviors, ductility, and energy-absorption capacities. Compared to conventionally reinforced concrete columns, the HSC columns confined in thin steel shell had similar load-displacement hysteretic behavior but exhibited greater energy-dissipation characteristics . It is concluded that, in strong earthquake areas, the transverse reinforcing method by using a thin steel shell (D/t=125) is quite effective to make HSC short columns with very strong and ductile.

• Corrosion Science and Technology
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• v.20 no.5
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• pp.315-323
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• 2021

In this study, we examined corrosion behaviors of two types of Pb alloys for a lead acid battery comparatively. One containing 6.6 wt% Sn, 36 mg/kg Bi, and 612.4 mg/kg Ca was prepared by twin-roll continuous casting. The other containing 5.2 wt% Sn, 30.5 mg/kg Ag, and 557 mg/kg Ca was made by twin-belt continuous casting. Potentiodynamic polarization tests were performed to evaluate corrosion resistance. Cyclic voltammetry was done to examine oxidation and reduction reactions occurring on the surface of each alloy in 4.8 M H₂SO₄ solution. Electrochemical test results implied that the Pb alloy prepared with the twin-belt casting method was less stable than that cast with the twin-roll method. Such results might be due to precipitations formed during the casting process. Rolling did not appear to affect the corrosion behavior of the twin-roll samples with Ag < 10 mg/kg, while it reduced the anodic reaction of Ag on the surface of the twin-belt sample with 30.5 mg/kg Ag.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2002.05a
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• pp.134-139
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• 2002

Fracture behaviors of pipes with local wall thinning are very important for the integrity of nuclear power plant. However, effects of local wall thinning on strength and fracture behaviors of piping system were not well studied. Acoustic emission(AE) has been widely used in various fields because of its extreme sensitivity, dynamic detection ability and location of growing defects. In this study, we investigated failure modes of locally wall thinned pipes and AE signals by bending test. From test results, we could be divided four types of failure modes of ovalization, crack initiation after ovalization, local buckling and crack initiation after local buckling. And fracture behaviors such as elastic region, yielding range, plastic deformation range and crack progress could be evaluated by AE counts, accumulative counts and time-frequency analysis during bending test. It is expected to be basic data that can protect a risk according to local wall thinning of pipes, as a real time test of AE.

• Steel and Composite Structures
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• v.27 no.4
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• pp.417-426
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• 2018

This paper presents the seismic behaviors and restoring force model of ring beam joints of steel tube-reinforced concrete column structure under cyclic loading. First, the main failure mode, ultimate bearing capacity, stiffness degradation and energy dissipation capacity are studied. Then, the effects of concrete grade, steel grade, reinforcement ratio and radius-to-width ratios are discussed. Finally, the restoring force model is proposed. Results show that the ring beam joints of steel tube-reinforced concrete column structure performs good seismic performances. With concrete grade increasing, the ultimate bearing capacity and energy dissipation capacity increase, while the stiffness degradation rates increases slightly. When the radius-width ratio is 2, with reinforcement ratio increasing, the ultimate bearing capacity decreases. However, when the radius-to-width ratios are 3, with reinforcement ratio increasing, the ultimate bearing capacity increases. With radius-to-width ratios increasing, the ultimate bearing capacity decreases slightly and the stiffness degradation rate increases, but the energy dissipation capacity increases slightly.

• Journal of the Korean Geotechnical Society
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• v.23 no.10
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• pp.47-56
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• 2007

In this research, the effects of the gravel content on the liquefaction behavior for both of the isotropically and $K_0-anisotropically$ consolidated gravel-sand mixtures are investigated. for this purpose, the cyclic triaxial tests for the specimens with the same relative density (Dr=40%) and variations of gravel content were performed. On the other hand, a series of undrained cyclic triaxial tests were carried out on the isotropically consolidated gravel-sand mixtures with the same void ratio (e=0.7) and from 0% to 30% gravel contents. Void ratios of gravel-sand mixtures with the same relative density (Dr=40%) are found to decrease significantly with the increase of the gravel content from 0% to about 70% and increase thereafter. But the void ratio of the sand matrix among the gravel skeleton increases with the increase of the gravel contents. Test results are as follows : for the isotropically consolidated specimen with 40% of relative density and low gavel contents (GC=0%, 20%, 40%), pore water pressure development and axial strain behavior during undrained cyclic loading show similar behavior to those of the loose sand because of high void ratio, and the specimens with high gravel content (70%) both pore pressure and strata behaviors are similar to those of dense sand. And the isotropically consolidated specimens with the same void ratio (e=0.7) and higher gravel contents show the same behavior of pore water pressure and axial strain as that of the loose sand, but for the lower gravel content this behavior shows similar behavior to that of dense sand. The liquefaction strength of the isotropically consolidated specimens with the same relative density increases with gravel content up to 70%, and the strength decreases with the increase of the gravel content at the same void ratio. Thus, it is confirmed that the liquefaction strength of the gravel-sand mixtures depends both on relative density and void ratio of the whole mixture rather than the relative density of the sand matrix filled among gravels. On the other hand, the behavior of pore water pressure and axial strain for the $K_0-anisotropically$ consolidated gravel-sand mixtures shows almost the same cyclic behavior of the sand with no stress reversal even with some stress reversal of the cyclic loading. Namely, even the stress reversal of about 10% of cyclic stress amplitude, the permanent strain with small cyclic strain increases rapidly with the number of cycles, and the initial liquefaction does not occur always with less than maximum pore water pressure ratio of 1.0. The liquefaction resistance increases with the gravel contents between 0% and 40%, but tends to decrease beyond 40% of gravel content. In conclusion, the cyclic behavior of gravel-sand mixtures depends on factors such as gravel content, void ratio, relative density and consolidation condition.

• Journal of Korean Society of Steel Construction
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• v.28 no.5
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• pp.345-354
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• 2016

In the present study, hybrid moment connections of welding and bar reinforcement for composite beam-column connections were proposed. Concrete-filled octagonal tube and U-section were used for the column and beam, respectively. In the beam-column connection, the top flange and web of the beam U-section were connected to the column plate by welding. However, to reduce stress concentration at the weld joints, the bottom flange of the beam was not welded to the column plate. Instead, to transfer the tension force of the beam flange, reinforcing bars passing through the column plate were used. Four exterior connections with conventional welded and hybrid moment connections were tested under cyclic loading and their cyclic behaviors were investigated. The test results showed that the hybrid moment connections successfully transferred the beam moment to the column. The strength and ductility of the hybrid moment connections were comparable to the conventional welded moment connection with exterior diaphragm; however, the connection performance was significantly affected by the details of the hybrid moment connection.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.1C
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• pp.43-52
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• 2006

Despite several constitutive models have been proposed and applied, it is still difficult to choose a suitable model and to estimate adequate analysis parameters. Furthermore, a cyclic shear behavior under the volume change caused by the seepage is more complex. None of the constitutive model is available at present in the expression of the cyclic behavior of soil under an additional volume change condition by seepage. Therefore, a new geotechnical hybrid simulation system which can control the pore water immigration was developed. The system enables a quantitative evaluation of the residual deformation such as lateral spreading and settlement caused by the liquefaction. The seismic responses in a one-dimensional slightly inclined multilayered soil system are taken into consideration, and the soils are governed by both equation of motion and the continuity equation. Furthermore, the estimation and the selection of the soil parameter for the representation of the strong nonlinearity of the material are not required, because soil behaviors under the earthquake motions are directly introduced instead of a numerical soil constitutive model. This paper presents the concept and specifications of the system. By applying the system to an example problem, the permeability effect on the seismic response during cyclic shear is studied. The importance of the volume change characteristics of sandy soil during and after cyclic shear is shown in conclusion.

• Journal of the Korea institute for structural maintenance and inspection
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• v.28 no.3
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• pp.91-99
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• 2024

Piping systems are crucial facilities used in various industries, particularly in areas related to daily life and safety. Piping systems are fixed to the main structures of buildings and facilities but do not support external loads and serve as non-structural elements performing specific functions. Piping systems are affected by relative displacements owing to phase differences arising from different behaviors between two support points under seismic loads; this can cause damage owing to the displacement-dominant cyclic behavior. Fittings and joints in piping systems are representative elements that are vulnerable to seismic loads. To evaluate the seismic performance and limit states of fittings and joints in piping systems, a high-stroke actuator is required to simulate relative displacements. However, this is challenging because only few facilities can conduct these experiments. Therefore, element-level experiments are required to evaluate the seismic performance and limit states of piping systems connected by fittings and joints. This study proposed a method to evaluate the seismic performance of an elbow specimen that includes fittings and joints that are vulnerable to seismic loads in vertical piping systems. The elbow specimen was created by connecting straight pipes to both ends of a 90° pipe elbow using flexible groove joints. The seismic performance of the elbow specimen was evaluated using a cyclic loading protocol based on deformation angles. To determine the margin of the evaluated seismic performance, the limit states were assessed by applying cyclic loading with a constant amplitude.

• Proceedings of the Earthquake Engineering Society of Korea Conference
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• 2000.10a
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• pp.304-313
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• 2000

This study presents the behavior of traditional wood structures of national heritage under earthquake loadings. A series of experimental program for four wood frames was performed to investigate characteristics of initial stiffness, behavior after ultimate loads, and hysteretic behaviors. The frames consisted of columns with a lintel by special joint and a bare frame was infilled by a mud wall. A pushover est was aimed to estimate the range of ultimate rotation of connection as a pilot test for cyclic load tests. One of frames infilled by a mud wall showed a larger stiffness than those of bare frames due to a strut action in the diagonal direction. However, the post yielding stiffness of the infilled frame was not increased.