• 제목/요약/키워드: cycle stability

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도전재 종류와 양에 따른 LiMn$_2$O$_4$정극의 충방전 용량 및 Cycle 안정성 (Charge/discharge capacity and cycle salability of LiMn$_2$O$_4$cathode by sorts and volume of conductive agent)

  • 정인성;박계춘;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
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    • pp.275-278
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    • 1997
  • We investigated effectness of sort and volume of conductive agent to charge/discharge capacity of LiMn$_2$O$_4$. LiMn$_2$O$_4$is prepared by reacting stoichiometric mixture of LiOH . $H_2O$ and MnO$_2$(mole ratio 1 : 2) and heating at 80$0^{\circ}C$ for 24h, 36h, 48h, 60h and 72h. All LiMn$_2$O$_4$cathode active materials show spinel structure. Cathode active materials calcined at 80$0^{\circ}C$ for 36h, charge/discharge characteristics and cycle stability have remarkable advantages. Used that super-s-black and 20wt% as conductive agent in LiMn$_2$O$_4$, it is excellent than property of cathode used Acetylene black or mixture of Super-s-black and acetylene black at charge/discharge capacity and cycle stability. Also, specific efficiency of cathode is excellent as over 98% and that of first cycle is excellent as 92%.

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도재라미네이트 접착용 레진시멘트의 색조 안정성에 관한 연구 (A STUDY ON THE COLOR STABILITY OF RESIN CEMENTS LUTED FOR PORCELAIN LAMINATE VENEER)

  • 김영운;박하옥;방몽숙;양홍서;박상원
    • 대한치과보철학회지
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    • 제45권2호
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    • pp.191-202
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    • 2007
  • Statement of problems: Long-term success of esthetic restorations, depends on various factors, especially on color stability of the restorations. The color stability is affected by resin cements beneath the porcelain laminate veneers. Purpose: The purpose of this study was to comprehend the color stability of resin cements by comparing with 4 different kinds of resin cements (Choice, Variolink II, Nexus 2, Rely-X). Material and methods: Porcelain laminate disk samples were luted with resin cements. After thermocycling of each 1000, 2000 and 3000 cycle, specimens were measured by spectrophotometers and the color differences were. Results: 1. After thermocycling of 1000, 2000 and 3000cycle, color difference, $({\Delta}E^*)$ of all specimens were incresed, but were not statiscally significant differences. 2. In the Choice of A1 shade and the Nexus 2 of A3 shade, color difference$({\Delta}E^*)$ after thermocycling of 3000cycle was $incre^*ased$ significantly than after thermocycling of 1000cycle. However, other groups did not show any statistically significant differences (P<0.05). 3. After thermocycling of 3000cycle, color difference$({\Delta}E^*)$ between A1 shade and A3 shade of Nexus 2 showed statistically significant difference. However no statistically significant differences were observed in other groups (P<0.05). 4. The mean of color difference$({\Delta}E^*)$ is 1.0-2.06 after 3000 thermocycling and the data were ranked in the ascending order of Variolink II, Nexus 2, Choice and Rely-X in A1 shade group and Choice, Rely-X, Variolink II and Nexus 2 in A3 shade group. Conclusion: Above results revealed that, after 3000 thermocycing, the color difference $({\Delta}E^*)$ of experimental resin cements was within clinically acceptable ranges. Color stability of 4 different resin cements was comparatively excellent.

Chemical Stability of Conductive Ceramic Anodes in LiCl-Li2O Molten Salt for Electrolytic Reduction in Pyroprocessing

  • Kim, Sung-Wook;Kang, Hyun Woo;Jeon, Min Ku;Lee, Sang-Kwon;Choi, Eun-Young;Park, Wooshin;Hong, Sun-Seok;Oh, Seung-Chul;Hur, Jin-Mok
    • Nuclear Engineering and Technology
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    • 제48권4호
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    • pp.997-1001
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    • 2016
  • Conductive ceramics are being developed to replace current Pt anodes in the electrolytic reduction of spent oxide fuels in pyroprocessing. While several conductive ceramics have shown promising electrochemical properties in small-scale experiments, their long-term stabilities have not yet been investigated. In this study, the chemical stability of conductive $La_{0.33}Sr_{0.67}MnO_3$ in $LiCl-Li_2O$ molten salt at $650^{\circ}C$ was investigated to examine its feasibility as an anode material. Dissolution of Sr at the anode surface led to structural collapse, thereby indicating that the lifetime of the $La_{0.33}Sr_{0.67}MnO_3$ anode is limited. The dissolution rate of Sr is likely to be influenced by the local environment around Sr in the perovskite framework.

Electrochemical Properties of Coal Tar Pitch based MCMB

  • Suh, Jeong-Kwon;Hong, Ji-Sook;Lee, Jung-Min
    • Carbon letters
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    • 제5권3호
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    • pp.118-126
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    • 2004
  • MCMB (Mesocarbon microbeads) is a kind of anode material for lithium-ion secondary battery. MCMB charge/discharge cycle stability is one of the important criterion at lithium-ion battery operation. In this study, the cycling stability of a lithium-ion secondary battery has been examined. MCMB was made by the direct solvent extraction method. After the MCMB was carbonized and graphitized, the measurement of charge/discharge capacity and efficiency were carried out. In the result, discharge capacity of MCMB in the initial cycle was above 290.0 mAh/g. After the second cycle, efficiency of charge/discharge MCMB was about 98%. These results were similar to the commercial MCMB product.

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INFLUENCE OF INITIAL COMBUSTION IN SI ENGINE ON FOLLOWING COMBUSTION STAGE AND CYCLE-BY-CYCLE VARIATIONS IN COMBUSTION PROCESS

  • Lee, Kyung-Hwan;Kim, Kisung
    • International Journal of Automotive Technology
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    • 제2권1호
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    • pp.25-31
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    • 2001
  • It is necessary to understand the combustion process and cycle-by-cycle variation in combustion to improve the engine stability and consequently to improve the fuel economy and exhaust emissions. The pressure related parameters instead of mass fraction burned were compared for the effect of initial combustion pressures on the following combustion and the analysis of cycle-by-cycle variation in combustion for two pen injected SI engines. The correlation between IMEP and pressures at referenced crank angles showed almost the same trends for equivalence ratios, but the different mixture preparations indicated different tendency. The dependency of IMEP on pressure at the referenced crank angles increases as the mixture becomes leaner for both engines. The mixture distribution in the combustion chamber was varied with the coolant temperature and intake valve deactivation due to the evaporation of fuel and air motion. The correlation between pressure related parameters were also compared for the coolant temperatures and air motion.

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경수로심의 제논진동 해석 (PWR Core Stability Against Xenon-Induced Spatial Power Oscillation)

  • Ho Ju Moon;Ki In Han
    • Nuclear Engineering and Technology
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    • 제14권2호
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    • pp.51-63
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    • 1982
  • 한국에너지연구소에서 개발한 1차원적 제논과도현상해석 코드 DD1D를 사용하여 가압경수로심의 축방향 제논진동에 대한 안정성을 조사하였다. 노심의 출력준위, 감속재온도계수, 노심 입구온도, 도플러출력 계수 그리고 연소도의 변화가 노심의 축방향 안정성에 미치는 효과를 조사하기 위하여 고리1호기의 설계 및 운전자료를 이용하였으며 본 민감도 분석을 통하여 고리 1호기의 노심은 주기 초에는 축방향 제논진동에 대하여 안정하나 연소도가 증가함에 따라 안정도가 차츰 감소하여 주기 말에는 불안정해진다는 것을 알았다. 이같이 연소도가 증가함에 따라 노심의 안정도가 감소하는 이유는 연소도 변화에 따라 축방향의 출력분포, 감속재온도 계수 및 도플러출력계수가 변하기 때문이다. 본 연구를 통하여 출력밀도가 높은 대형 가압 경수로의 경우 전 주기동안 축방향제논진동에 대하여 안정된 노심을 설계하기 힘들다는 결론에 도달하였다.

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터보 방식으로 구동되는 마이크로 파워 시스템의 회전체 동역학적 특성에 관한 연구 (A Study on the Rotordynamic Characteristics of the Micro Turbo Generator)

  • 류근;이용복;이병수;김창호
    • 유체기계공업학회:학술대회논문집
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    • 유체기계공업학회 2004년도 유체기계 연구개발 발표회 논문집
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    • pp.109-115
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    • 2004
  • The micro turbo generator is new portable power source based on the Brayton cycle, which consists of a compressor, a turbine, a generator, and a combustion chamber. In this paper, the thermodynamic analysis was performed to find the required condition for hundreds watts power in the micro turbo generator, and also the rotordynamic stability was predicted using the numerical analysis of air foil bearings which support the micro turbo generator. By experimental works, the rotordynamic stability of the micro turbo generator with foil bearings was verified. While various transient dynamic situation, the micro turbo generator had stable performances. From the result, it was demonstrated that air foil bearings could be adapted to the micro turbo generator as a excellent lubrication element.

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High-Reliability Three-Phase Dual-Buck Grid-Connected Inverter without Shoot-Through Problem

  • Fu, Zhenbin;Feng, Zhihua;Chen, Xi;Zheng, Xinxin
    • Journal of Power Electronics
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    • 제19권2호
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    • pp.454-462
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    • 2019
  • When compared to traditional bridge-type inverters, the dual-buck inverter has a higher reliability due to the fact that its bridge legs do not have a shoot-through problem. In this paper, the working principle of the dual-buck inverter is analyzed. A comparison of the working modes under full-cycle and half-cycle control is discussed. With half-cycle control, the inverter can realize a higher efficiency. However, this results in current zero-crossing distortion. The corresponding control strategy of the dual-buck inverter is proposed in order to realize both high efficiency and low current harmonic distortion. In addition, the system stability is analyzed. Dead-time is unnecessary due to the advantages of the topology. Thus, the current harmonic distortion can be further reduced. An inverter with the proposed control strategy has the advantages of high reliability, high efficiency and low current harmonic distortion. Finally, simulation and experimental results are given to verify the theoretical analysis.

A Study on the Numerical Approach for Industrial Life Cycle: Empirical Evidence from Korea

  • LEE, Kangsun;CHOI, Kyujin;CHO, Daemyeong
    • The Journal of Asian Finance, Economics and Business
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    • 제8권5호
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    • pp.667-678
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    • 2021
  • The industrial life cycle theory was extended to the product life cycle theory and the corporate life cycle theory, but a conceptual life cycle was presented, and quantitative empirical evidence for this was insufficient. It is intended to improve appropriate resource planning and resource allocation by quantitatively predicting the industrial cycle and its position (age) in the cycle. Human resources, tangible assets, and industrial output analysis were conducted based on 28 years of actual data of 39 industries in Korea by applying the Gompertz model, which is a population ecology prediction model. By predicting with the Gompertz model, the coefficient of determination R2 value was 97% or more, confirming the high suitability with the actual cumulative sales value of the industry. A numerical model for calculating the life cycle of each industry, calculating the saturation of input resources for each industry, and diagnosing the financial stability of the industry was presented. These results will contribute to the decision-making of industrial policy officers for budget planning appropriately for each stage of industry development. Future research will apply the numerical model of this study to foreign national industries, complete an inter-industry convergence diagnostic model (e.g. ease of convergence, suitability of convergence, etc.) for renewal of fading industries.

3-로브 베어링으로 지지된 중형 고속 터보차저 로터의 선형 및 비선형 동적 안정성 특성 규명 (Identification of Linear and Nonlinear Dynamic Stability Characteristics of a Medium-size High-speed Turbocharger Rotor Supported by 3-lobe Bearings)

  • 이안성;김병옥
    • 한국소음진동공학회논문집
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    • 제21권6호
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    • pp.562-569
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    • 2011
  • In this study linear and nonlinear dynamic stability characteristics of a medium-size high-speed turbocharger, whose rotor is supported by two 3-lobe journal bearings, are analyzed to evaluate and identify the effects of its bearing design variables. The rotor has the rated speed of 40,500 rpm and maximum continuous speed of 45,000 rpm. At first, utilizing the linear stability analysis method, bearing designs of yielding stable or unstable LogDecs as small as possible are searched by manipulating with machined bearing clearances and preloads. As next, utilizing the nonlinear analysis method, limit cycles of the rotor responses at the rated and maximum continuous speeds are simulated to check their acceptances. Results have shown that for the turbocharger rotor-bearing system considered, the 3-lobe journal bearing design with a smaller machined clearance and a larger preload are preferred for the stable rotor responses. More importantly, since there exists a good correlation between the linear and nonlinear stability analysis results, it is concluded that firstly the linear stability analysis method may be applied to screen quickly the ranges of bearing designs for stable or least unstable solutions and then, lastly the nonlinear stability analysis method may be deployed to check an absolute motion stability in terms of the limit cycle.