• Title/Summary/Keyword: cycle stability

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Charge/discharge capacity and cycle salability of LiMn$_2$O$_4$cathode by sorts and volume of conductive agent (도전재 종류와 양에 따른 LiMn$_2$O$_4$정극의 충방전 용량 및 Cycle 안정성)

  • 정인성;박계춘;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.275-278
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    • 1997
  • We investigated effectness of sort and volume of conductive agent to charge/discharge capacity of LiMn$_2$O$_4$. LiMn$_2$O$_4$is prepared by reacting stoichiometric mixture of LiOH . $H_2O$ and MnO$_2$(mole ratio 1 : 2) and heating at 80$0^{\circ}C$ for 24h, 36h, 48h, 60h and 72h. All LiMn$_2$O$_4$cathode active materials show spinel structure. Cathode active materials calcined at 80$0^{\circ}C$ for 36h, charge/discharge characteristics and cycle stability have remarkable advantages. Used that super-s-black and 20wt% as conductive agent in LiMn$_2$O$_4$, it is excellent than property of cathode used Acetylene black or mixture of Super-s-black and acetylene black at charge/discharge capacity and cycle stability. Also, specific efficiency of cathode is excellent as over 98% and that of first cycle is excellent as 92%.

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A STUDY ON THE COLOR STABILITY OF RESIN CEMENTS LUTED FOR PORCELAIN LAMINATE VENEER (도재라미네이트 접착용 레진시멘트의 색조 안정성에 관한 연구)

  • Kim, Young-Woon;Park, Ha-Ok;Vang, Mong-Sook;Yang, Hong-So;Park, Sang-Won
    • The Journal of Korean Academy of Prosthodontics
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    • v.45 no.2
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    • pp.191-202
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    • 2007
  • Statement of problems: Long-term success of esthetic restorations, depends on various factors, especially on color stability of the restorations. The color stability is affected by resin cements beneath the porcelain laminate veneers. Purpose: The purpose of this study was to comprehend the color stability of resin cements by comparing with 4 different kinds of resin cements (Choice, Variolink II, Nexus 2, Rely-X). Material and methods: Porcelain laminate disk samples were luted with resin cements. After thermocycling of each 1000, 2000 and 3000 cycle, specimens were measured by spectrophotometers and the color differences were. Results: 1. After thermocycling of 1000, 2000 and 3000cycle, color difference, $({\Delta}E^*)$ of all specimens were incresed, but were not statiscally significant differences. 2. In the Choice of A1 shade and the Nexus 2 of A3 shade, color difference$({\Delta}E^*)$ after thermocycling of 3000cycle was $incre^*ased$ significantly than after thermocycling of 1000cycle. However, other groups did not show any statistically significant differences (P<0.05). 3. After thermocycling of 3000cycle, color difference$({\Delta}E^*)$ between A1 shade and A3 shade of Nexus 2 showed statistically significant difference. However no statistically significant differences were observed in other groups (P<0.05). 4. The mean of color difference$({\Delta}E^*)$ is 1.0-2.06 after 3000 thermocycling and the data were ranked in the ascending order of Variolink II, Nexus 2, Choice and Rely-X in A1 shade group and Choice, Rely-X, Variolink II and Nexus 2 in A3 shade group. Conclusion: Above results revealed that, after 3000 thermocycing, the color difference $({\Delta}E^*)$ of experimental resin cements was within clinically acceptable ranges. Color stability of 4 different resin cements was comparatively excellent.

Chemical Stability of Conductive Ceramic Anodes in LiCl-Li2O Molten Salt for Electrolytic Reduction in Pyroprocessing

  • Kim, Sung-Wook;Kang, Hyun Woo;Jeon, Min Ku;Lee, Sang-Kwon;Choi, Eun-Young;Park, Wooshin;Hong, Sun-Seok;Oh, Seung-Chul;Hur, Jin-Mok
    • Nuclear Engineering and Technology
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    • v.48 no.4
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    • pp.997-1001
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    • 2016
  • Conductive ceramics are being developed to replace current Pt anodes in the electrolytic reduction of spent oxide fuels in pyroprocessing. While several conductive ceramics have shown promising electrochemical properties in small-scale experiments, their long-term stabilities have not yet been investigated. In this study, the chemical stability of conductive $La_{0.33}Sr_{0.67}MnO_3$ in $LiCl-Li_2O$ molten salt at $650^{\circ}C$ was investigated to examine its feasibility as an anode material. Dissolution of Sr at the anode surface led to structural collapse, thereby indicating that the lifetime of the $La_{0.33}Sr_{0.67}MnO_3$ anode is limited. The dissolution rate of Sr is likely to be influenced by the local environment around Sr in the perovskite framework.

Electrochemical Properties of Coal Tar Pitch based MCMB

  • Suh, Jeong-Kwon;Hong, Ji-Sook;Lee, Jung-Min
    • Carbon letters
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    • v.5 no.3
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    • pp.118-126
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    • 2004
  • MCMB (Mesocarbon microbeads) is a kind of anode material for lithium-ion secondary battery. MCMB charge/discharge cycle stability is one of the important criterion at lithium-ion battery operation. In this study, the cycling stability of a lithium-ion secondary battery has been examined. MCMB was made by the direct solvent extraction method. After the MCMB was carbonized and graphitized, the measurement of charge/discharge capacity and efficiency were carried out. In the result, discharge capacity of MCMB in the initial cycle was above 290.0 mAh/g. After the second cycle, efficiency of charge/discharge MCMB was about 98%. These results were similar to the commercial MCMB product.

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INFLUENCE OF INITIAL COMBUSTION IN SI ENGINE ON FOLLOWING COMBUSTION STAGE AND CYCLE-BY-CYCLE VARIATIONS IN COMBUSTION PROCESS

  • Lee, Kyung-Hwan;Kim, Kisung
    • International Journal of Automotive Technology
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    • v.2 no.1
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    • pp.25-31
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    • 2001
  • It is necessary to understand the combustion process and cycle-by-cycle variation in combustion to improve the engine stability and consequently to improve the fuel economy and exhaust emissions. The pressure related parameters instead of mass fraction burned were compared for the effect of initial combustion pressures on the following combustion and the analysis of cycle-by-cycle variation in combustion for two pen injected SI engines. The correlation between IMEP and pressures at referenced crank angles showed almost the same trends for equivalence ratios, but the different mixture preparations indicated different tendency. The dependency of IMEP on pressure at the referenced crank angles increases as the mixture becomes leaner for both engines. The mixture distribution in the combustion chamber was varied with the coolant temperature and intake valve deactivation due to the evaporation of fuel and air motion. The correlation between pressure related parameters were also compared for the coolant temperatures and air motion.

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PWR Core Stability Against Xenon-Induced Spatial Power Oscillation (경수로심의 제논진동 해석)

  • Ho Ju Moon;Ki In Han
    • Nuclear Engineering and Technology
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    • v.14 no.2
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    • pp.51-63
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    • 1982
  • Stability of a PWR core against xenon-induced axial power oscillation is studied using one-dimensional xenon trausient analysis code, DD1D, that has been developed and verified at KAERI. Analyzed by DD1D utilizing the Kori Unit 1 design and operating data is the sensitivity of axial stability in a PWR core to the changes in core physical parameters including core power level, moderator temperature coefficient, core inlet temperature, doppler power coefficient and core average turnup. Through the sensitivity study the Kori Unit 1 core is found to be stable against axial xenon oscillation at the beginning of cycle 1. But, it becomes less stable as turnup progresses, and unstable at the end of the cycle. Such a decrease in stability is mainly due to combined effect of changes in axial power distribution, moderator temperature coefficient and doppler power coefficient as core turnup progresses. It is concluded from the stability analysis of the Kori Unit 1 core that design of a large PWR with high power density and increased dimension can not avoid xenon-induced axial power instabilities to some extents, especially at the end of cycle.

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A Study on the Rotordynamic Characteristics of the Micro Turbo Generator (터보 방식으로 구동되는 마이크로 파워 시스템의 회전체 동역학적 특성에 관한 연구)

  • Ryu, Keun;Lee, Yong-Bok;Lee, Byoung-Su;Kim, Chang-Ho
    • 유체기계공업학회:학술대회논문집
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    • 2004.12a
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    • pp.109-115
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    • 2004
  • The micro turbo generator is new portable power source based on the Brayton cycle, which consists of a compressor, a turbine, a generator, and a combustion chamber. In this paper, the thermodynamic analysis was performed to find the required condition for hundreds watts power in the micro turbo generator, and also the rotordynamic stability was predicted using the numerical analysis of air foil bearings which support the micro turbo generator. By experimental works, the rotordynamic stability of the micro turbo generator with foil bearings was verified. While various transient dynamic situation, the micro turbo generator had stable performances. From the result, it was demonstrated that air foil bearings could be adapted to the micro turbo generator as a excellent lubrication element.

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High-Reliability Three-Phase Dual-Buck Grid-Connected Inverter without Shoot-Through Problem

  • Fu, Zhenbin;Feng, Zhihua;Chen, Xi;Zheng, Xinxin
    • Journal of Power Electronics
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    • v.19 no.2
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    • pp.454-462
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    • 2019
  • When compared to traditional bridge-type inverters, the dual-buck inverter has a higher reliability due to the fact that its bridge legs do not have a shoot-through problem. In this paper, the working principle of the dual-buck inverter is analyzed. A comparison of the working modes under full-cycle and half-cycle control is discussed. With half-cycle control, the inverter can realize a higher efficiency. However, this results in current zero-crossing distortion. The corresponding control strategy of the dual-buck inverter is proposed in order to realize both high efficiency and low current harmonic distortion. In addition, the system stability is analyzed. Dead-time is unnecessary due to the advantages of the topology. Thus, the current harmonic distortion can be further reduced. An inverter with the proposed control strategy has the advantages of high reliability, high efficiency and low current harmonic distortion. Finally, simulation and experimental results are given to verify the theoretical analysis.

A Study on the Numerical Approach for Industrial Life Cycle: Empirical Evidence from Korea

  • LEE, Kangsun;CHOI, Kyujin;CHO, Daemyeong
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.5
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    • pp.667-678
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    • 2021
  • The industrial life cycle theory was extended to the product life cycle theory and the corporate life cycle theory, but a conceptual life cycle was presented, and quantitative empirical evidence for this was insufficient. It is intended to improve appropriate resource planning and resource allocation by quantitatively predicting the industrial cycle and its position (age) in the cycle. Human resources, tangible assets, and industrial output analysis were conducted based on 28 years of actual data of 39 industries in Korea by applying the Gompertz model, which is a population ecology prediction model. By predicting with the Gompertz model, the coefficient of determination R2 value was 97% or more, confirming the high suitability with the actual cumulative sales value of the industry. A numerical model for calculating the life cycle of each industry, calculating the saturation of input resources for each industry, and diagnosing the financial stability of the industry was presented. These results will contribute to the decision-making of industrial policy officers for budget planning appropriately for each stage of industry development. Future research will apply the numerical model of this study to foreign national industries, complete an inter-industry convergence diagnostic model (e.g. ease of convergence, suitability of convergence, etc.) for renewal of fading industries.

Identification of Linear and Nonlinear Dynamic Stability Characteristics of a Medium-size High-speed Turbocharger Rotor Supported by 3-lobe Bearings (3-로브 베어링으로 지지된 중형 고속 터보차저 로터의 선형 및 비선형 동적 안정성 특성 규명)

  • Lee, An-Sung;Kim, Byung-Ok
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.21 no.6
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    • pp.562-569
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    • 2011
  • In this study linear and nonlinear dynamic stability characteristics of a medium-size high-speed turbocharger, whose rotor is supported by two 3-lobe journal bearings, are analyzed to evaluate and identify the effects of its bearing design variables. The rotor has the rated speed of 40,500 rpm and maximum continuous speed of 45,000 rpm. At first, utilizing the linear stability analysis method, bearing designs of yielding stable or unstable LogDecs as small as possible are searched by manipulating with machined bearing clearances and preloads. As next, utilizing the nonlinear analysis method, limit cycles of the rotor responses at the rated and maximum continuous speeds are simulated to check their acceptances. Results have shown that for the turbocharger rotor-bearing system considered, the 3-lobe journal bearing design with a smaller machined clearance and a larger preload are preferred for the stable rotor responses. More importantly, since there exists a good correlation between the linear and nonlinear stability analysis results, it is concluded that firstly the linear stability analysis method may be applied to screen quickly the ranges of bearing designs for stable or least unstable solutions and then, lastly the nonlinear stability analysis method may be deployed to check an absolute motion stability in terms of the limit cycle.