• 공업화학
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• 제26권6호
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• pp.674-680
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• 2015

리튬이차전지 실리콘 전극에 활용하기 위해, 유기용매에 용해성이 있는 폴리이미드(Polyimide, PI) 고분자 바인더를 두 단계 반응을 이용해 합성하였다. 두 가지 단량체(Bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic Dianhydride (BCDA)와 4,4-oxydianiline (ODA))의 개환 반응 및 축합 반응을 통해 PI 고분자 바인더를 합성하였다. 합성된 PI 고분자 바인더를 이용해 실리콘(silicon, Si) 음극 전극을 제조하였다. 또한 비교군으로써, Polyvinylidene Fluoride (PVDF)을 고분자 바인더로 사용하는 동일 조성을 가진 실리콘 전극을 제조하였다. PI 바인더를 사용한 Si 전극($2167mAh\;g^{-1}$)의 초기 쿨롱 효율은 기존 PVDF 바인더 조성의 Si 전극($1,740mAh\;g^{-1}$)과 유사했지만, 방전용량은 크게 개선되었다. 특히 수명 특성에서는 PI 바인더를 사용한 Si 전극이 우수한 특성을 나타내었는데, 이는 PI 바인더를 사용한 Si 전극접착력($0.217kN\;m^{-1}$)의 전극 접착력이 PVDF를 사용한 Si 전극($0.185kN\;m^{-1}$)보다 높아, 실리콘 부피팽창에 의한 전극 구조 열화가 적절히 제어되었기 때문이라고 판단된다. Si 전극 내의 접착력은 surface and interfacial cutting analysis system (SAICAS) 장비를 통해 검증하였다.

• 한국전산유체공학회지
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• 제13권4호
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• pp.1-7
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• 2008

In the process of continuous hot-dip galvanizing, it is well known that the gas wiping through an air knife system is most effective because of its uniformity in coating thickness, possibility of thin coating, workability in high speed, and simplicity of control. However, gas wiping used in the galvanizing process brings about a problem of splashing at the strip edge above a certain high speed of process. It is also known that the problem of edge splashing is more harmful than that at the mid strip surface. For a given liquid(of a certain viscosity and surface tension), the onset of splashing mainly depends upon the strip velocity, the gas-jet pressure, and the nozzle's stand-off distance. In these connections in the present study, we proposed three kinds of air knife system having nozzles of constant expansion rate, and compared the jet structures issuing from newly proposed nozzle systems with the result by a conventional one. In numerical analysis, the governing equations are consisted of two-dimensional time dependent Navier-Stokes equations, and the standard k-${\varepsilon}$ turbulence model is employed to solve turbulence stress and so on. As the result, it is found that we had better use the constant expansion-rate nozzle which can be interpreted from the point view of the energy saving for the same coating thickness. Also, we better reduce the size of separation bubble and enhance the cutting ability at the strip surface, by using an air-knife having constant expansion-rate nozzle.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.2955-2960
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• 2007

To control the coating thickness of zinc in the process of continuous hot-dip galvanizing, it is known from early day that the gas wiping through an air knife system is the most effective because of the obtainable of uniformity of coating thickness, possibility of thin coating, working ability in high speed and simplicity of control. But, the gas wiping using in the galvanizing process brings about a problem of splashing from the strip edge for a certain high speed of coating. And, it is known that the problem of splashing is caused mainly by the existence of separation bubble at the neighbor of the strip surface. In theses connections, in the present study, we proposed two kinds of air knife systems having the same expansion rate of nozzle, and the jet structures and coating thicknesses from a conventional and new proposed nozzles are compared. In numerical analysis, the governing equations consisted of two-dimensional time dependent Navier-Stokes equations, standard ${\kappa}-{\varepsilon}$ turbulence model to solve turbulence stress and so on are employed. As a result, it is found that it had better to use the constant rate nozzle from the point view of the energy saving to obtain the same coating thickness. Also, to reduce the size of separation bubble and to enhance the cutting ability at the strip, it is recommendable to use an air knife having the constant expansion rate nozzle.

• 한국공간구조학회논문집
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• 제7권3호
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• pp.57-66
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• 2007

연성구조시스템 중 하나인 막 구조물은 대공간 구조물에 많이 사용되어진다. 막 구조물은 축강성이 강하고 휨강성이 매우 작은 재료로서 구조물의 설계는 강성구조물과는 달리 형상해석, 응력-변형해석 그리고 재단도 등의 일련의 과정을 필요로 한다. 막 구조물의 형상해석은 일반적으로 초기 불안정 상태의 막 면에 초기강성을 부여함으로서 평형상태에 이르게 되는 역학적 메커니즘을 가지고 있으며, 이와 같은 곡면을 해석적으로 구하는 데는 해석상의 수렴 및 발산 그리고 오차 발생에 따른 문제를 해결해야만 한다. 본 논문에서는 막 구조물의 초기곡면을 형성하기 위한 형상탐색기법에 대한 수렴 및 오차에 관하여 연구하고, 적용된 예제의 해석 결과를 바탕으로 해가 수렴해 가는 과정 및 제어변수에 따른 수렴속도 및 효율성을 살펴본다.

• 대한기계학회논문집A
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• 제37권2호
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• pp.213-218
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• 2013

초음파 가공(Ultrasonic Machining:USM)은 새로운 기계가공기술 분야 중의 하나이다. 초음파 가공 과정은 비열, 비화학, 그리고 비전도의 방법이기 때문에 공작물 재료의 물리적, 화학적 변화가 없다. 이러한 특성으로 인해 초음파 가공기술은 유리, 세라믹 등과 같은 취성재료의 가공에 적합하다. 그러나 단점으로는 초음파 진동을 이용하여 취성재료를 가공하는 경우 크랙이 빈번하게 발생한다. 본 논문에서는 유리와 세라믹의 미세 구멍가공에서 다구찌 방법을 이용하여 크랙발생을 최소화하는 최적의 가공조건을 얻고자 하였다. 이를 통해 공작물의 입구 및 출구에서 발생하는 크랙 현상을 감소시켰다.

• 지질공학
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• 제19권3호
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• pp.345-350
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• 2009

경주-감포간 국도건설공사 중 양북터널의 종점부측은 산악지형으로 도로가 산지의 사면으로 통과하기 때문에 대절토 구간으로 이루어져 있다. 이 구간에 사면안정공법으로 PAP옹벽을 설치하였다. 옹벽을 설치한 후 6개월 정도가 지나면서부터 PAP옹벽의 앵커체 일부가 파단되었다. 즉시 계측기를 추가 배치하고 응급조치를 한 다음 지금까지의 계측기록으로 역해석을 실시하였다. 동시에 앵커체의 정착부를 확인하기 위한 지층조사와 앵커체의 이상여부를 확인하는 인장시험을 실시하였다. 역해석 결과 당초 설계에 적용한 토질정수의 90%를 적용함이 타당한 것으로 나타났다. 이를 근거로 재설계를 시행하였으며, 재설계의 결과는 당초 허용응력 306 kN이던 앵커체를 591 kN 및 784 kN의 앵커체로 교체하고, 정착부의 위치를 당초 11.0 m에서 23.0 m를 증가시켰다. 앵커체를 교체한 후 약 5개월 정도가 지난 지금까지의 계측 결과는 안정된 상태를 보여주고 있다. 이 사례는 대형사고로 이어질 수 있었던 사례를 신속하고 정확한 조치로 사면을 안정화시킨 사례이다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.1507-1510
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• 2005

This study was carried out as a part of the research on the development of a maskless and electroless process for fabricating metal micro/nanostructures by using a nanoindenter and an electroless deposition technique. $2-\mu{m}-deep$ indentation tests on Ni and Cu samples were performed. The elastic recovery of the Ni and Cu was 9.30% and 9.53% of the maximum penetration depth, respectively. The hardness and the elastic modulus were 1.56 GPa and 120 GPa for Ni and 1.49 GPa and 100 GPa for Cu. The effect of single-point diamond machining conditions such as the Berkovich tip orientation (0, 45, and $90^{\circ}$) and the normal load (0.1, 0.3, 0.5, 1, 3, and 5 mN), on both the deformation behavior and the morphology of cutting traces (such as width and depth) was investigated by constant-load scratch tests. The tip orientation had a significant influence on the coefficient of friction, which varied from 0.52-0.66 for Ni and from 0.46-0.61 for Cu. The crisscross-pattern sample showed that the tip orientation strongly affects the surface quality of the machined area during scratching. A selective deposition of Cu at the pit-like defect on a p-type Si(111) surface was also investigated. Preferential deposition of the Cu occurred at the surface defect sites of silicon wafers, indicating that those defect sites act as active sites for the deposition reaction. The shape of the Cu-deposited area was almost the same as that of the residual stress field.

• International Journal of Naval Architecture and Ocean Engineering
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• 제9권3호
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• pp.315-325
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• 2017

The design dimension may not be satisfactory at the final stage due to the welding during the assembly stage, leading to cutting or adding the components in large structure constructions. The productivity is depend on accuracy of the welding quality especially at assembly stage. Therefore, it is of utmost importance to decide the component dimension during each assembly stage considering the above situations during the designing stage by exactly predicting welding deformation before the welding is done. Further, if the system that predicts whether welding deformation is equipped, it is possible to take measures to reduce deformation through FE analysis, helping in saving time for correcting work by arresting the parts which are prone to having welding deformation. For the FE analysis to predict the deformation of a large steel structure, calculation time, modeling, constraints in each assembly stage and critical welding length have to be considered. In case of fillet welding deformation, around 300 mm is sufficient as a critical welding length of the specimen as proposed by the existing researches. However, the critical length in case of butt welding is around 1000 mm, which is far longer than that suggested in the existing researches. For the external constraint, which occurs as the geometry of structure is changed according to the assembly stage, constraint factor is drawn from the elastic FE analysis and test results, and the magnitude of equivalent force according to constraint is decided. The comparison study for the elastic FE analysis result and measurement for the large steel structure based on the above results reveals that the analysis results are in the range of 80-118% against measurement values, both matching each other well. Further, the deformation of fillet welding in the main plate among the total block occupies 66-89%, making welding deformation in the main plate far larger than the welding deformation in the longitudinal and transverse girders.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2005년도 춘계 학술발표회 논문집
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• pp.1316-1323
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• 2005

Most tunnel lining material which has been used in the domestic is a concrete. But many problems as the construction period, the cost, and the crack occurrence for the design, construction, and management were happened in the concrete lining. For this reason, many research institutes like the Korea Highway Corporation recognize the necessity of an alternate material development and grow on the interest for that. So in this study, the behaviour characteristics for the application of the Corrugated Steel Plate Lining in cut-and-cover tunnel are evaluated as several conditions for the backfill height, the cutting slope, and the relative density of backfill soil are changed. In addition, through using that conditions, CHBDC(2000, Canadian Highway Bridge Design Code) is evaluated if it could be applied to the design by comparing with the numerical analysis results. As the behaviour characteristics of the Corrugated Steel Plate Lining by CHBDC and the static numerical analysis are analyzed, both the methods show the same linear increases of the compressive stress according to the increase of the backfill height. The CHBDC of the dead load condition has very similar tendency by comparing with the result of the static numerical analysis.

• 한국터널공학회:학술대회논문집
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• 한국터널공학회 2005년도 학술발표회 논문집
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• pp.233-247
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• 2005

Most tunnel lining material which has been used in the domestic is a concrete. But many problems as the construction period, the cost, and the crack occurrence for the design, construction, and management were happened in the concrete lining. For this reason, many research institutes like the Korea Highway Corporation recognize the necessity of an alternate material development and grow on the interest for that. So in this study, the seismic behaviour characteristics for the application of the Corrugated Steel Plate Lining in cut-and-cover tunnel are evaluated as several conditions for the backfill height, the cutting slope, and the relative density of backfill soil are changed. The compressive stress which is calculated in the Corrugated Steel Plate Lining by the seismic load is decreased as the backfill height increases and the cut slope grows gentle. Also, the moment shows the tendency of decrease according to the increase of the backfill height. But in the case of the relative density of the backfill soil is small, the moment increases according to the increase of the backfill height and affects the dynamic behaviour characteristic. So it is considered that the relative density of the backfill soil is also the important point. As the result in analyzing the seismic response characteristics of the reinforcement spacing of the Corrugated Steel Plate, the variation in the compressive force is hardly happened, but the moment and the shear force increase on the reinforcement spacing being narrow.