• 콘크리트학회논문집
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• 제18권1호
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• pp.117-124
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• 2006

본 연구에서는 복합 재질 폐플라스틱(PA)을 이용한 폴리머콘크리트의 작업성, 경화시간 및 경화수축에 미치는 결합재 첨가량 및 PA 혼입량의 영향에 대하여 검토하였다. 그 결과 복합 재질 폐플라스틱을 재활용한 폴리머콘크리트의 작업성은 결합재 첨가량, PA 혼입량 및 필러 혼입량의 증가에 따라 증가하는 경향을 나타냈다. 복합 재질 폐플라스틱을 이용한 폴리머콘크리트의 경화시간은 촉매제 첨가량 및 양생온도의 증가에 따라 짧아지는 경향을 나타냈다. 복합 재질 폐플라스틱을 이용한 폴리머콘크리트의 길이변화는 결합재 첨가량 및 PA 혼입량의 증가에 따라 증가하는 경향을 보였다. 본 연구 결과가 복합 재질 폐플라스틱 종말품의 재활용에 조금이나마 기여할 수 있을 것을 기대하며 향후 지속적인 연구개발을 통하여 더욱 광범위한 복합재질 폐플라스틱 종말품의 재활용이 이루어질 수 있을 것으로 판단된다.

• Composites Research
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• 제24권2호
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• pp.30-37
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• 2011

에폭시 수지와 유리섬유직물 간의 젖음성을 분석하였다. 에폭시 수지와 산무수물 경화제의 혼합비는 당량비 1:0.5, 1:1, 1:1.2로 하였고, 촉매는 혼합된 수지의 0.lwt%로 첨가하였다. DSC 경화거동분석 결과 이 혼합 수지는 상온에서 함침이 가능하였다. 혼합 수지에 대해 유리평판에 놓여진 유리섬유직물 위에 수지 한 액적(방울)을 투하 후 시간에 따른 접촉각 변화를 측정하였다, 또한, 일정량의 에폭시 수지 액적을 투하시켜 시간에 따른 젖음면적 변화를 측정하였다, 접촉각, 액적높이, 순수 젖음면적, 젖음계수를 측정함으로써 유리섬유직물에 대한 에폭시 수지의 젖음성을 비교 평가하였다. 그 결과 당량비 1:1.2에서 유리섬유직물에 대한 젖음성이 가장 우수하였다.

• Composites Research
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• 제27권4호
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• pp.174-181
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• 2014

본 연구에서는 탄소섬유 강화 복합재의 점탄성 성질을 적용한 유한요소 해석에 대해서 기술하였다. 고온의 성형과정에서 발생하는 가장 중요한 문제 중 하나는 잔류응력의 발생이다. 잔류응력으로 인해 성형이 끝난 후 뒤틀림, 균열이 일어 날 수 있으며 이는 완성품에 심각한 결함을 가져올 수 있다. 잔류응력의 주요 원인은 점탄성이며 고온의 성형과정에서 열팽창계수의 차이와 수지의 시간 및 온도에 대한 물성의 변화로 인해 발생하는 탄소섬유 강화 복합재의 특징이다. 화학 수축도 잔류응력에 많은 영향을 주며 이를 고려한 뒤틀림 예측에서 오차를 줄일 수 있는 중요한 요소이다. 본 연구는 복합재 성형에 사용된 온도변화에 대한 경화도와 점탄성 효과, 화학수축을 유한요소 해석으로 수행하기 위한 기법을 연구하고, 점탄성의 영향성을 연구하였다. 기존에 연구되어 있는 논문을 참고하여 서브루틴의 타당성을 검증한 후 나아가 복합재의 적층각의 변화에 따른 응력과 변형을 해석해 봄으로써 실제 복합재의 성형 시 발생하는 휨 현상에 대한 예측방법을 제시하였다.

• Journal of Welding and Joining
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• 제33권4호
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• pp.44-49
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• 2015

The structural epoxy adhesive used in car body assembly needs the highest level of joint mechanical strength under lap shear, T-peel and impact peel conditions. In this study, the effect of nano functionalized block copolymer addition on the impact peel strength of epoxy adhesive was investigated. DSC analysis showed that the addition of nano functionalized block copolymer did not affect the curing reaction of epoxy adhesive. From single lap shear test, it was found out that the addition of nano functionalized block copolymer slightly decreased the cohesive strength of cured adhesive layer. The addition of nano functionalized block copolymer showed beneficial effect on T-peel strength by changing the adhesive failure mode to the mixed mode. However, the addition of nano functionalized block copolymer just decreased the room temperature impact peel strength. It was considered that the addition of nano functionalized block copolymer could have effect on disturbing the crack propagation only for the case of slow strain rate.

• 폴리머
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• 제24권4호
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• pp.520-528
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• 2000

본 연구는 고형분 70%인 하이솔리드 아크릴 수지 (BMHA)를 합성하여, 환경친화성 도료인 하이솔리드 아크릴/폴리이소시아네이트 도료(BNHS)에 적용하고 그의 도막특성을 살펴본 것에 그 의의가 있다. BMHA는 새로운 형의 단량체로서 acetoacetoxyethyl methacrylate (AAEM)을 도입하고 여기에 n-butyl acrylate, methyl methacrylate 및 2-hydroxyethyl acrylate를 4원공중합시켜 얻었다. BMHA 합성에 있어서 T$_{g}$ 값이 낮을수록, AAEM의 양이 많을수록 각각 높은 전환율을 나타내었고, T$_{g}$값 고정하의 OH 값 변화에 따른 전환율은 큰 차이가 없었다. BMHA와 폴리이소시아네이트를 상온경화시켜 하이솔리드 BNHS 도료를 제조하고서 자동차 상도용 도료로서의 적합성 여부를 알아보기 위하여 도막물성 시험을 한 결과, BNHS내에 AAEM 도입 전후의 도막물성 비교시험에서 AAEM 도입후에 내마모성과 내용제성이 향상됨으로써 자동차 상도용 도료로서의 응용가능성을 보여주었다.다.

• 한국염색가공학회지
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• 제8권2호
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• pp.25-34
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• 1996

Diphenyl ethanolamidophosphate(DPEAD) was synthesized for the purpose of developing a new flame retardant for cotton fabric. As the intermediate material was used diphenyl chlorophosphate(DPCP) and it was synthesized by using phosphorus oxychloride and phenol as the starting materials. The final product DPEAP was obtained by the reaction of DPCP and ethanolamine. The flame retardancy of cotton fabrics treated by DPEAP through pad-dry-cure(PDC) process was examined at various conditions. The physical property change of the DPEAP treated cotton fabrics were investigated by examining the drape stiffness, the wrinkle recovery, and the tensile strength. The results are summarized as follows: (1) DPEAP has shown excellent flame retardancy on cotton fabrics in comparison to other flame retardants for cotton fabrics available commercially. (2) The optimal condition for PDC process found was that the curing temperature was 16$0^{\circ}C$, the DPEAP concentration was 10%, the catalyst $({NH_{4})_{2}HPO_{4}$ concentration was 7.0%, and the fixing agent hexamethylol melamine (HMM)/DPEAP weight ratio was 1/8. (3) The wrinkle recovery of the processed fabrics increased with increasing DPEAP concentration. (4) The drape stiffness of the cotton fabrics treated by DPEAP have shown essentially no change until increasing DPEAP concentration to 15 %, however DPEAP concentration exceeds 20% the drape stiffness increased drastically with increasing DPEAP concentration. When DPEAP concentration is kept constant the drape stiffness increased with increasing $({NH_{4})_{2}HPO_{4}$ concentration and HMM/DPEAP weight ratio. (5) The tensile strength of the processed fabrics was lower than that of untreated fabrics, but the tensile strength retention increased with increasing DPEAP concentration.

• 폴리머
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• 제34권6호
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• pp.574-578
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• 2010

본 연구에서는 고리화합물인 카프로락톤으로부터 2-hydroxyethyl acylate(2-HEA)를 개시제로 사용하여 caprolactone modified hydroxy acrylate(CHA)를 합성한 후, hexamethylene diisocyanate trimer(HDT)와 축중합을 통해 카프로락톤 변성 우레탄 아크릴레이트(UA) 올리고머를 합성하였다. 카프로락톤과 2-HEA의 몰비에 따른 CHA의 분자량은 수산가를 이용하여 계산되었으며, 계산된 분자량은 이론분자량과 거의 일치하였다. UA 올리고머의 점도는 2-HEA 대한 CHA의 함량이 증가할수록 감소하는 경향을 보였다. UA 올리고머와 반응형 희석제를 광개시제와 함께 광경화한 후, 형성된 경화필름의 내열성 및 내열 변색성을 측정하였다. 경화필름의 가교밀도가 증가할수록 내열성 및 내열변색성이 우수하였으나 가교밀도가 증가할수록 경도는 증가하지만, 신율은 상대적으로 감소하였다.

• 한국환경농학회지
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• 제28권4호
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• pp.378-385
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• 2009

Arsenic (As) is known to be very toxic and carcinogenic to human beings. Arsenic contaminated soil was collected from a timber mill site at Busan Metropolitan City, Korea, where chromated copper arsenate (CCA) had been used to protect wood from rotting caused by insects and microbial agents. The soil was stabilized using both natural oyster shells (NOS) and calcinated oyster shells (POS). The calcination of natural oyster shells was accomplished at a high temperature in order to activate quicklime from calcite. Two different oyster shell particle sizes (-#10 mesh and -#20 mesh) and curing periods of up to 28 days were investigated. The stabilization effectiveness was evaluated based on the Korean Standard Test (KST) method (1N HCl extraction). The stabilization results showed that the POS treatment was more effective than the NOS treatment at immobilizing the As in the contaminated soils. A significant As reduction (96%) was attained upon a POS treatment at 20 wt% and passed the Korean warning standard of 20 mg/kg ('Na' area). However, an As reduction of only 47% (169 mg/kg) was achieved upon a NOS treatment at 20 wt%. The -#20 mesh oyster shells seem to perform better than the -#10 materials. The scanning electron microscopy (SEM)-energy dispersive X-ray spectroscopy (EDX) results showed that As immobilization was strongly associated with Ca and O in the presence of Al and Si.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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• pp.131-131
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• 2003

The advent of photonic technologies in the field of communications and data transmission has been heavily increasing the demand in integrated optical (IO) circuits capable of accomplishing not only simple tasks like signal, but also more sophisticated functions like all-optical signal routing or active multiplexing/demultiplexing. In the last decade, sol-gel technology has been widely used to prepare optical materials. Sol-gel processes show many promises for the development of low-loss, high-performance glass integrated optical circuits. However, crack formation is likely to occur during heat treatment in thick gel films. In order to overcome the critical thickness limitation, the organic-modified silicate has been widely used. In this case coating matrices have been prepared from the organo-silanes of T structures, acidic catalyst and the as-prepared gel films have been heat-treated below 200$^{\circ}C$ to avoid the crack formation and the degradation of organic components. However, the films prepared in the acidic condition and the low heat temperature make the films contain high OH groups which is the major optical loss function. In this work, C$\sub$6/H$\sub$5/SiO$\sub$1.5/ films were prepared on silicon substrate by sol-gel method using base catalyst in a PTMS/NH$_4$OH/H$_2$O/C$_2$H$\sub$5/OH system. The sol showed spinable viscosity at 50 wt% of solid content, and neglectable viscosity change with time. The films were crack-free and transparent after curing at 450 $^{\circ}C$, and highly condensed to minimize OH content in C$\sub$6/H$\sub$5/SiO$\sub$1.5/ networks. The effects of heat treatment of the films are characterized on the critical thickness, the chemical composition and the refractive indices by means of SEM, FT-IR, TGA, prism coupler, respectively.

• 한국응용과학기술학회지
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• 제22권3호
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• pp.270-280
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• 2005

To maximize a synergy effect in flame-retardancy of flame-retardant coatings, phosphorus and chlorine were introduced in polymer chains. Two-components PU flame-retardant modified polyesters (ABTTC-10C, -20C, -30C) were prepared by curing, at room temperature, of isocyanate (allophanate-trimer) and prepared modified polyesters which contain phosphorus and chlorine. To examine the film properties of the prepared flame-retardant coatings, film specimens were prepared with the prepared coatings. The film properties of ABTTC, ABTTC-10C and ABTTC-20C, which contain 0, 10 and 20wt%, 2,4-dichlorobenzoic acid (2,4-DCBA), respectively, were proved to be good, whereas the film properties of ABTTC-30C, which contains 30wt% 2,4-DCBA, were proved to be a little bit poor. Two kinds of flame retardancy tests, $45^{\circ}$Meckel burner method and LOI method, were performed. With the $45^{\circ}$Meckel burner method, three flame-retardant coatings except ABTTC showed less than 3.4 cm of char length, and showed less than 2 seconds of afterflaming and afterglow. From this result, the prepared flame-retardant coatings were proved to have the 1st grade flame retardancy. With the LOI method, the LOI values of the coatings containing more than 10wt% 2,4-DCBA were higher than 30wt%, which means that the coatings possess good flame-retardancy. From these results, it was found that synergistic effect in flame-retardancy was taken place by the introduced phosphorus and chlorine.