• Journal of the Korean GEO-environmental Society
• /
• v.3 no.2
• /
• pp.23-33
• /
• 2002

Examined a practical use possibility of paper fly ash that is industrial by-product as a stabilization/hardening agent. Performed unconfined compression test, scanning electron microscopy and pH analysis etc. for 100% paper fly ash-soil mixtures and each paper fly ash-soil mixtures that add cement as the second addition and sulfate component of small quantity for strength promotion and so on. In all cases, strength of admixtures increased according as curing time and mixing ratio increases but almost strength is revealed at mixing early and expressed maximum strength increase efficiency at mixing ratio 9% with raw soil. Compare with the case that use paper fly ash only, in case of cement amount 10~30% was included in paper fly ash, strength of admixtures increases two times and 40% was included, that increases from five to eight times.

• Smart Structures and Systems
• /
• v.25 no.6
• /
• pp.751-764
• /
• 2020

Real-time monitoring of stiffness and strength in cement based system has received significant attention in past few decades owing to the development of advanced techniques. Also, use of environment friendly supplementary cementitious materials (SCM) in cement, though gaining huge interest, severely affect the strength gain especially in early ages. Continuous monitoring of strength- and stiffness- gain using an efficient technique will systematically facilitate to choose the suitable time of removal of formwork for structures made with SCM incorporated concrete. This paper presents a technique for monitoring the strength and stiffness evolution in hydrating fly ash blended cement systems using electro-mechanical impedance (EMI) based technique. It is important to observe that the slower pozzolanic reactivity of fly ash blended cement systems could be effectively tracked using the evolution of equivalent local stiffness of the hydrating medium. Strength prediction models are proposed for estimating the strength and stiffness of the fly ash cement system, where curing age (in terms of hours/days) and the percentage replacement of cement by fly ash are the parameters. Evaluation of strength as obtained from EMI characteristics is validated with the results from destructive compression test and also compared with the same obtained from commonly used ultrasonic wave velocity (UPV). Statistical error indices indicate that the EMI technique is capable of predicting the strength of fly ash blended cement system more accurate than that from UPV. Further, the correlations between stiffness- and strength- gain over the time of hydration are also established. From the study, it is found that EMI based method can be effectively used for monitoring of strength gain in the fly ash incorporated cement system during hardening.

• Advances in nano research
• /
• v.4 no.1
• /
• pp.15-29
• /
• 2016

A low cost environmentally benign surface coating binder is highly desirable in the field of material science. In this report, castor oil based hyperbranched polyester/bitumen modified fly ash nanocomposites were fabricated to achieve the desired performance. The hyperbranched polyester resin was synthesized by a three-step one pot condensation reaction using monoglyceride of castor oil based carboxyl terminated pre-polymer and 2,2-bis (hydroxymethyl) propionic acid. Also, the bulk fly ash of paper industry waste was converted to hydrophilic nano fly ash by ultrasonication followed by transforming it to an organonano fly ash by the modification with bitumen. The synthesized polyester resin and its nanocomposites were characterized by different analytical and spectroscopic tools. The nanocomposite obtained in presence of 20 wt% styrene (with respect to polyester) was found to be more homogeneous and stable compared to nanocomposite without styrene. The performance in terms of tensile strength, impact resistance, scratch hardness, chemical resistance and thermal stability was found to be improved significantly after formation of nanocomposite compared to the pristine system after curing with bisphenol-A based epoxy and poly(amido amine). The overall results of transmission electron microscopic (TEM) analysis and performance showed good exfoliation of the nano fly ash in the polyester matrix. Thus the studied nanocomposites would open up a new avenue on development of low cost high performing surface coating materials.

• Advances in concrete construction
• /
• v.11 no.5
• /
• pp.419-428
• /
• 2021

The pH of cement-based materials (CBMs) is an important factor for their durability, sustainability, and long service life. Currently, the use of supplementary cementitious materials (SCMs) is becoming mandatory due to economic, environmental, and sustainable issues. There is a decreasing trend in pH of CBMs due to incorporation of SCMs. The determination of numerical values of pH is very important for various low and high volume SCMs blended cement mortars for the better understanding of different defects and durability issues during their service life. In addition, the effect of cement hydration and pozzolanic reaction of SCMs on the pH should be determined at initial and later ages. In this study, the effect of low and high-volume fly ash (FA) and ground granulated ballast furnace slag (GGBFS) cement mortars in different curing conditions on their pH values has been determined. Thermal gravimetric analysis (TGA) was carried out to support the findings from pH measurements. In addition, thermal conductivity (k-value) and strength activity indices of these cement mortars were discussed. The results showed that pH values of all blended cement mortars were less than ordinary Portland cement (OPC) mortar in all curing conditions used. There was a decreasing tendency in pH of all mortars with passage of time. In addition, the pH of cement mortars was not only dependent on the quantity of Ca(OH)₂. The effect of adding SCMs on the pH value of cement mortar should be monitored and measured for both short and long terms.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.7 no.3
• /
• pp.85-90
• /
• 2012

In this study, temperature profile of the fly ash concrete were studied in accordance with the change of heating curing method combination for the slab concrete in order to develop efficient protection method of the concrete subjected to $-20^{\circ}C$. The slab concretes with the size of $1200mm{\times}600mm{\times}200mm$ were fabricated with W/B of 50% and exposed to $-20^{\circ}C$ for 7 days. Five different combinations of heat curing methods were applied to the slab concrete specimen; two combinations of heat supplying by electrical heater and surface heat insulation material such as polyethylene film and quadrupled layer bubble sheet based on heat enclosure installment; three combinations of heating coil embedment and surface heat insulation materials such as polyethylene film, sawdust and quadrupled layer bubble sheet based on heat enclosure installment. Test results showed that by applying both heating coil and bubble sheet and heat enclosure, the concrete exposed to $-20^{\circ}C$ can be effectively protected from early-age frost damage.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1994.04a
• /
• pp.142-147
• /
• 1994

Lately, among concrete component used in construction works, the aggregate is the most important material because it hold about 70~80 Vo1% of most structural materials. Considering that the demand of aggregate is on the continuous increase in the construction works year after year, it is a very urgent thing to develop a substitute aggregate for river aggregate. This paper, an experimental study on the effect of corrosion protection by tighting concrete used fly-ash and silica fume, is to investigate workability and engineering properties of concrete used fly-ash and silica fume. As a test results, contrary to SF, workability of concrete used FA is inclined to be improved. And in the case of containing SF, the compressive strength containing admixtures is higher than plain concrete with increasing curing age.

• Geomechanics and Engineering
• /
• v.8 no.3
• /
• pp.361-375
• /
• 2015

Constructions over soft and loose soils are one of the most frequent problems in many parts of the world. Cement and cement-lime mixture have been widely used for decades to improve the strength of these soils with the deep soil mixing method. In this study, to investigate the freeze-thaw effect of sand improved by polymers (i.e., styrene-acrylic-copolymer-SACP, polyvinyl acetate-PVAc and xanthan gum) and fly ash, unconfined compression tests were performed on specimens which were exposed to freeze-thaw cycles and on specimens which were not exposed to freeze-thaw cycles. The laboratory test results concluded that the unconfined compressive strength increased with the increase of polymer ratio and curing time, whereas, the changes on unconfined compressive strength with increase of freeze-thaw cycles were insignificant. The overall evaluation of results has revealed that polymers containing fly ash is a good promise and potential as a candidate for deep soil mixing application.

• Advances in concrete construction
• /
• v.1 no.2
• /
• pp.151-162
• /
• 2013

The performance characteristics of high-strength and high-performance concrete are discussed in this review. Recent developments in the field of high-performance concrete marked a giant step forward in high-tech construction materials with enhanced durability, high compressive strength and high modulus of elasticity particularly for industrial applications. There is a growing awareness that specifications requiring high compressive strength make sense only when there are specific strength design advantages. HPC today employs blended cements that include silica fume, fly ash and ground granulated blast-furnace slag. In typical formulations, these cementitious materials can exceed 25% of the total cement by weight. Silica fume contributes to strength and durability; and fly ash and slag cement to better finish, decreased permeability, and increased resistance to chemical attack. The influences of various mineral admixtures such as fly ash, silica fume, micro silica, slag etc. on the performance of high-strength concrete are discussed.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2003.05a
• /
• pp.787-792
• /
• 2003

The purpose of this study is to suggest the fundamental data of durability which effects on the Carbonation of concrete by adding various admixture additives. Thus, We have experimented the accelerated test on the concrete blending which was admixed by blast furnace slag, fly-ash, silica fume , durability amelioration and it was cured 7weeks after twenty eight days water curing. The result of this experiment is that Carbonation speed increased extremely when water cement ratio went up, and by growing of replace cement ratio of admixture additives. The specimen which was added fly-ash, blast furnace slag, silica fume has the faster Carbonation speed than the specimen which was not added admixture additives. All of these specimen, fly-ash has the fastest progress speed.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1998.10c
• /
• pp.42-47
• /
• 1998

Experimental investigation was undertaken to determine early-age strength development and the relationships between the mechanical properties of type I, V and V/fly ash cement concrete with different curing temperature. The tests for mechanical properties, i.e., compressive strength, splitting tensile strength and modulus of elasticity were carried out for type, I, V and V with 15% replacement with fly ash cement concrete. For this purpose 480 concrete cylinders cured at isothermal conditions of 10, 23, 35 and 5$0^{\circ}C$ were tested at ages of 1, 3, 7 and 28days. According to the experiments, the concrete subjected to high temperature at early age got greater strength at early age, however eventually lower strength at late age. The derived relationships between compressive strength and splitting tensile strength and elastic modulus of elasticity appeared to be identical for all types of cement.