• Title/Summary/Keyword: curable

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Synthesis and Comparison of EB- and UV-curable Monomers for Anti-fogging Coatings (전자선 및 자외선 경화형 방무코팅용 모노머의 합성 및 물성비교)

  • Cho, Jung-Dae;Lee, Jae-Sung;Kim, Yang-Bae;Hong, Jin-who
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.449-455
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    • 2005
  • Electron beam (EB) and ultraviolet (UV) curable monomers (AF-1 with mono functionality and AF-2 with tetra functionality) containing hydroxy and acrylate group for anti-fogging coating were synthesized and applied to EB and UV-curable coating systems. The synthesized reactive AF-1 and AF-2 monomers were first formulated into UV-curable system and the optimization of film properties for anti-fogging coating was investigated. The 5:17.5 ratio for AF-1 and AF-2 was found to be the best optimized formulation for anti-fogging coating without destroying the other essential properties such as hardness, solvent resistance, and adhesion. The optimized formulation was applied to the EB-curable system, and EB and UV-curable systems were compared. The results demonstrated that both EB and UV-cured films coated on PC sheet showed excellent anti-fogging properties; however, the EB-cured film exhibited better hardness, adhesion, and water repellent properties than the UV-cured film.

A Novel Patterning Method for Silver Nanowire-based Transparent Electrode using UV-Curable Adhesive Tape (광경화 점착 테이프를 이용한 은 나노와이어 기반 투명전극 패터닝 공법)

  • Ju, Yun Hee;Shin, Yoo Bin;Kim, Jong-Woong
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.3
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    • pp.73-76
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    • 2020
  • Silver nanowires (AgNWs) intrinsically possess high conductivity, ductility, and network structure percolated in a low density, which have led to many advanced applications of transparent and flexible electronics. Most of these applications require patterning of AgNWs, for which photolithographic and printing-based techniques have been widely used. However, several drawbacks such as high cost and complexity of the process disturb its practical application with patterning AgNWs. Herein, we propose a novel method for the patterning of AgNWs by employing UV-curable adhesive tape with a structure of liner/adhesive layer/polyolefin (PO) film and UV irradiation to simplify the process. First, the UV-curable adhesive tape was attached to AgNWs/polyurethane (PU), and then selectively exposed to UV irradiation by using a photomask. Subsequently, the UV-curable adhesive tape was peeled off and consequently AgNWs were patterned on PU substrate. This facile method is expected to be applicable to the fabrication of a variety of low-cost, shape-deformable transparent and wearable devices.

Physical Properties of UV-Curable Powder Coatings with Different Photoinitiator Contents (광개시제의 함량에 따른 UV 경화형 분체도료의 물리적 특성)

  • Moon, Je-Ik;Choi, Jae-Hoon;Hwang, Hyun-Deuk;Kim, Hyun-Joong;Kim, Nam-Hong
    • Journal of Adhesion and Interface
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    • v.9 no.2
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    • pp.32-37
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    • 2008
  • A series of UV-curable powder coatings with different contents of photoinitiator (0.5 wt%, 1 wt%, 2 wt%) were formulated and measured gel content, tensile strength of cured film. Heat-sensitive substrates such as MDF, plywood and PVC were coated UV-curable powder and cured coatings were measured physical properties by pendulum hardness tester, glossmeter, pull-off adhesion tester. With increasing photoinitiator content, adhesion force between coating and substrate decreased because of crosslinking density increasing. The results of pendulum hardness was not significantly changed but gloss was changed according to different substrates. Adhesion of UV-curable coatings was enough to apply for heat-sensitive substrates. From these results, we concluded that contents of photoinitiator was a effective factor in UV-curable powder coatings. UV-curable coatings was a portential candidate for heat-sensitive substrates.

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Upper Endoscopy up to 3 Years Prior to a Diagnosis of Gastric Cancer Is Associated With Lower Stage of Disease in a USA Multiethnic Urban Population, a Retrospective Study

  • Shah, Shailja C.;Nakata, Chiaki;Polydorides, Alexandros D.;Peek, Richard M. Jr;Itzkowitz, Steven H.
    • Journal of Preventive Medicine and Public Health
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    • v.52 no.3
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    • pp.179-187
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    • 2019
  • Objectives: In the USA, certain races and ethnicities have a disproportionately higher gastric cancer burden. Selective screening might allow for earlier detection and curative resection. Among a USA-based multiracial and ethnic cohort diagnosed with non-cardia gastric cancer (NCGC), we aimed to identify factors associated with curable stage disease at diagnosis. Methods: We retrospectively identified endoscopically diagnosed and histologically confirmed cases of NCGC at Mount Sinai Hospital in New York City. Demographic, clinical, endoscopic and histologic factors, as well as grade/stage of NCGC at diagnosis were documented. The primary outcome was the frequency of curable-stage NCGC (stage 0-1a) at diagnosis in patients with versus without an endoscopy negative for malignancy prior to their index exam diagnosing NCGC. Additional factors associated with curable-stage disease at diagnosis were determined. Results: A total of 103 racially and ethnically diverse patients were included. Nearly 38% of NCGC were stage 0-Ia, 34% stage Ib-III, and 20.3% stage IV at diagnosis. A significantly higher frequency of NCGC was diagnosed in curable stages among patients who had undergone an endoscopy that was negative for malignancy prior to their index endoscopy that diagnosed NCGC, compared to patients without a negative endoscopy prior to their index exam (69.6% vs. 28.6%, p=0.003). A prior negative endoscopy was associated with 94.0% higher likelihood of diagnosing curable-stage NCGC (p=0.003). No other factors analyzed were associated with curablestage NCGC at diagnosis. Conclusions: Endoscopic screening and surveillance in select high-risk populations might increase diagnoses of curable-stage NCGC. These findings warrant confirmation in larger, prospective studies.

A Study on Properties of UV-Curing Silver Paste for Touch Panel by Photoinitiator Characteristic (광개시제 특성에 따른 터치 패널용 UV 경화형 Ag 페이스트의 물성 연구)

  • Nam, Su-Yong;Koo, Yong-Hwan;Kim, Sung-Bin
    • Journal of the Korean Graphic Arts Communication Society
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    • v.29 no.2
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    • pp.1-13
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    • 2011
  • The recent spotlight on electronic touch-screen display, a rapid breakthrough in the information society is evolving. Touch panel input device such as a keyboard or mouse without the use of, the on-screen character or a specific location or object on the person's hand touches a particular feature to identify the location of a panel is to be handled. The touch screen on the touch panel is used in the Ag paste is used mostly for low-curable paste. The thermal-curing paste according to the drying process of thermal energy consumption and improve the working environment of organic solvents have problems. In this study, Ag paste used in the non-thermal curing friendly and cost-effective UV curable paste was prepared. Current commercially available thermal-curable binder, was used instead of the flow characteristics of UV-curable oligomers and monomers with functional groups to give a single conductive Ag paste with the addition of a pattern could be formed. Ag paste as a result, thermal-curing adhesive, hardness, resistance and excellent reproduction of fine patterns and was available with screen printing environmentally friendly could see its potential as a patterning technology.

Development of Build-up Printed Circuit Board Manufacturing Process Using Rapid Prototyping Technology and Screen Printing Technology

  • Im, Yong-Gwan;Cho, Byung-Hee;Chung, Sung-Il;Jeong, Hae-Do
    • International Journal of Precision Engineering and Manufacturing
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    • v.4 no.4
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    • pp.51-56
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    • 2003
  • Generally, the build-up printed circuit board manufactured by a sequential process involving etching, plating, drilling, etc, which requires many types of equipments and long lead time. Etching process is suitable for mass production, however, it is not adequate for manufacturing a prototype in the development stage. In this study, we introduce a screen printing technology for prototyping a build-up printed circuit board. As for the material, photo/thermal curable resin and conductive paste are used for the formation of dielectric and conductor. The build-up structure is made by subsequent processes such as formation of a liquid resin thin layer, solidification by a UV/IR light, and via hole filling with a conductive paste. By use of photo curable resin, productivity is greatly enhanced compared with thermal curable resin. Finally, the basic concept and the possibility of build-up printed circuit board prototyping are proposed in comparison with the conventional process.

Investigating the Antibacterial Qualities of Copper Particle-Infused UV-Curable Paint for Wood Flooring Boards (구리입자 기반 UV경화도료 코팅 목질 마루판의 항균 특성)

  • Lee, Dong-Gun;Lim, Nam-Gi;Koh, Jae-Song
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.4
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    • pp.393-404
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    • 2023
  • This research evaluates the antibacterial and transparency properties of UV-curable paint augmented with 20wt% copper particles. The transparency assessment indicated that the paint maintained a total luminous transmittance of 90% or above, thereby matching or surpassing the performance of standard UV-curing paints. To further test its antibacterial capabilities, wooden flooring boards were coated with the UV-curable paint laced with 20wt% copper particles, which had been surface-modified with a silane coupling agent. Following the fatigue tests of these treated boards, an impressive bacterial reduction rate of 99.9% was noted after a span of 6 hours, demonstrating the paint's exceptional antibacterial performance.

Process Conditions for the Fabrication of Hydrophobic Surfaces with Different Photo-curable Resins (광경화성 레진의 성분 변화에 대한 소수성 표면 제작을 위한 공정 조건)

  • Hong, Sung-Ho;Woo, Heung-Sik
    • Tribology and Lubricants
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    • v.36 no.5
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    • pp.267-273
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    • 2020
  • This study experimentally investigates hydrophobic surfaces fabricated via additive manufacturing. Additive manufacturing, commonly known as 3D printing, is the process of joining materials to fabricate parts from 3D model data, usually in a layer-upon-layer manner. Digital light processing is used to fabricate hydrophobic surfaces in this study. This method uses photo-curable resins and ultraviolet (UV) sources. Moreover, this technique generally has faster shaping speeds and is advantageous for the fabrication of small components because it enables the fabrication of one layer at a time. Two photo-curable resins with different compositions are used to fabricate micro-patterns of hydrophobic surfaces. The resins are composed of a photo-initiator, monomer, and oligomer. Experiments are conducted to determine suitable process conditions for the fabrication of hydrophobic surfaces depending on the type of resin. The most important factors affecting the process conditions are the UV exposure time and slice thickness. The fabrication capability according to the process conditions is evaluated using the side and top views of the micro-patterns observed using a microscope. The micro-patterns are collapsed and intertwined when the exposure time is short because sufficient light (heat) is not applied to cure the photo-curable resin with a given slice thickness. On the other hand, the micro-patterns are attached to each other when the exposure time is prolonged because the over-curing time can cure the periphery of a given shape. When the slice is thicker, the additional curing area is enlarged in each slice owing to the straightness of UV light, and the slice surface becomes rough.

Sub 150nm Soft-Lithography using the monomer based thermally curable resin (Monomer based thermally curable resin을 이용한 150nm 급 Soft-Lithography)

  • Yang K.Y.;Hong S.H.;Lee H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.676-679
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    • 2005
  • Nano imprint Lithography (NIL) is regarded as one of the next-generation lithography technologies with EUV lithography, immersion lithography, Laser interference lithography. Because a Si wafer stamp and a quartz stamp, used to imprinting usually are very expensive and easily broken, it is suggested that master stamp is duplicated by PDMS and the PDMS stamp uses to imprint .For using the PDMS stamp, a thermally curable monomer resin was used for the imprinting process to lower pressure and temperature. As a result, NIL patterns were successfully fabricated.

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