• Title/Summary/Keyword: cubic surfaces

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LOW TEMPERATURE DIAMOND GROWTH USING MICROWAVE PLASMA CVD

  • Sakamoto, Yukihiro;Takaya, Matsufumi;Shinohara, Kibatsu
    • Journal of the Korean institute of surface engineering
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    • v.29 no.5
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    • pp.487-493
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    • 1996
  • Diamond films were grown at lower temperatures (630-813K) on Si, Al (1100P), and Al-Si(8A, 8B, BC) alloy substrates using improved microwave plasma CVD apparatus in a mixed methane and hydrogen plasma. Improved microwave plasma CVD apparatus equipped water cooled substrate holder and the substrates were set up lower position than bottom line of the applicator waveguide. When the methane concentration was high and growth was conducted at lower pressures the diamond films were synthesized. Moreover the deposits on the scratched substrates formed flat surfaces consisting of fine grains. XRD results, the deposits were identified to cubic diamond. An analysis using Raman spectroscopy, further confirmed that diamond films deposited on the Si substrates were high quality. The deposits on the Al substrates, in contrast, contained amorphous carbon. While the quality of the deposits on the Al-Si substrates were differed with the substrate alloys.

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First-principles studies of the structural and electronic properties of rigid carbon nanofoam

  • Park, So-Ra;Kittimanapun, Kritsada;Ahn, Jeung-Sun;Tomanek, David;Kwon, Young-Kyun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.76-76
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    • 2010
  • Using ab initio density functional calculations, we investigate the structural and electronic properties of porous schwarzite structures formed by $sp^2$ carbon minimal surfaces with negative Gaussian curvature. We calculate the equilibrium geometries, elastic properties and electronic structure of two systems with cubic unit cells containing 152 and 200 carbon atoms, which are metallic and very rigid. The porous schwarzite structure can be efficiently doped by electron donors as well as accepors, making it a promising candidate for the next generation of alkali ion batteries. Furthermore, the schwarzite structures can be magnetic when doped and thus act as arrays of interconnected quantum spin dots. We also propose that two interpenetrating schwarzite structures be used as a ultimate super-capacitor.

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CFD Study on the Influence of Atmospheric Stability on Near-field Pollutant Dispersion from Rooftop Emissions

  • Jeong, Sang Jin;Kim, A Ra
    • Asian Journal of Atmospheric Environment
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    • v.12 no.1
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    • pp.47-58
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    • 2018
  • The aim of this work is to investigate the effect of atmospheric stability on near-field pollutant dispersion from rooftop emissions of a single cubic building using computational fluid dynamics (CFD). This paper used the shear stress transport (here after SST) k-${\omega}$ model for predicting the flow and pollutant dispersion around an isolated cubic building. CFD simulations were performed with two emission rates and six atmospheric stability conditions. The results of the simulations were compared with the data from wind tunnel experiments and the result of simulations obtained by previous studies in neutral atmospheric condition. The results indicate that the reattachment length on the roof ($X_R$) obtained by computations show good agreement with the experimental results. However, the reattachment length of the rooftop of the building ($X_F$) is greatly overestimated compared to the findings of wind tunnel test. The result also shows that the general distribution of dimensionless concentration given by SST k-${\omega}$ at the side and leeward wall surfaces is similar to that of the experiment. In unstable conditions, the length of the rooftop cavity was decreased. In stable conditions, the horizontal velocity in the lower part around the building was increased and the vertical velocity around the building was decreased. Stratification increased the horizontal cavity length and width near surface and unstable stratification decreased the horizontal cavity length and width near surface. Maintained stability increases the lateral spread of the plume on the leeward surface. The concentration levels close to the ground's surface under stable conditions were higher than under unstable and neutral conditions.

Evaluation of High-Viscosity Grouting Injection Perfomance for Reinforcement of Rock Joint in Deep -Depth Tunnels (대심도 터널 암반 절리 보강을 위한 고점도 그라우팅 주입 성능 평가)

  • Inkook Yoon;Junho Moon;Younguk Kim
    • Journal of the Korean GEO-environmental Society
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    • v.25 no.5
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    • pp.15-19
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    • 2024
  • This study aimed to develop high-efficiency grouting techniques under deep-depth conditions by experimentally verifying the applicability of various injection materials. Particle size analysis and injection model experiments were conducted with Ordinary Portland Cement (OPC) and Micro Cement (MC) to evaluate the injection performance of each material. Using Barton's Cubic Network theory, the rock fracture spacing was calculated for domestic deep-depth standards, specifically below 40 meters underground. The analysis of particle size passability under selected conditions showed that MC could pass through the rock fracture gaps, while OPC could not. According to the results of the injection model experiments using experimental devices and area calculation software, OPC failed in injection due to its larger particle size, whereas MC was capable of injection even under high-viscosity conditions. Based on these findings, the study quantitatively and visually derived the applicability of grouting materials under deep-depth conditions, and high-viscosity MC material is expected to be effective for waterproofing enhancement in deep-depth rock fracture surfaces.

A Study on Tribological Properties of 3D-Printed Surface with Respect to Sliding Orientation (3D 프린팅된 표면의 슬라이딩 방향에 따른 트라이볼로지적 특성 연구)

  • Sim, Jae Woong;Caro, Christian Nicholas De;Seo, Kuk-Jin;Kim, Dae-Eun
    • Tribology and Lubricants
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    • v.35 no.6
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    • pp.337-342
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    • 2019
  • This paper presents an experimental investigation of friction and wear characteristic with respect to patterns occurring on the surface of 3D printed polymer products by fused deposition modeling method. The purpose of this study was to investigate the effect of the patterns and sliding directions on the tribological properties of 3D printed polymer surface. A cubic specimen was printed using polylactic acid filament as the printing material. Friction tests were conducted for different directions with respect to the patterns that were generated on the top and the side surfaces of the specimen, by using a ball-on-reciprocating type tribotester. SUJ2 bearing ball of which the diameter was 11 times greater than the width of the largest pattern was used as the counter surface to assess the frictional behavior. Friction tests were conducted on the top and the side surfaces with respect to the patterns in 3 (0°, 45°, 90°) different directions respectively. Coefficient of friction increased as cycles increased in all cases. The results of the tests showed that the lowest coefficient of friction was measured with the 45° sliding direction on the side surface. The wear rate was the lowest at 45° sliding direction on the side surface, while it was the highest at 0° sliding direction on the top surface. Coefficient of friction of about 0.45 was determined to be the converging value on the top compared to the side surface.

Numerical Analysis of Laboratory Heating Experiment on Granite Specimen (화강암의 실내 가열실험에 대한 수치해석적 검토)

  • Dong-Joon, Youn;Changlun, Sun;Li, Zhuang
    • Tunnel and Underground Space
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    • v.32 no.6
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    • pp.558-567
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    • 2022
  • The evolution of temperature and thermal stress in a granite specimen is studied via heating experiment in the context of a high-level radioactive waste repository. A heating condition based on the decay-induced heat is applied to a cubic granite specimen to measure the temperature and stress distributions and their evolution over time. The temperature increases quickly due to heat conduction along the heated surfaces, but a significant amount of thermal energy is also lost through other surfaces due to air convection and conduction into the loading machine. A three-dimensional finite element-based model is used to numerically reproduce the experiment, and the thermo-mechanical coupling behavior and modeling conditions are validated with the comparison to the experimental results. The most crucial factors influencing the heating experiment are analyzed and summarized in this paper for future works.

Coupled electro-elastic analysis of functionally graded piezoelectric material plates

  • Wu, Chih-Ping;Ding, Shuang
    • Smart Structures and Systems
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    • v.16 no.5
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    • pp.781-806
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    • 2015
  • A unified formulation of finite layer methods (FLMs), based on the Reissner mixed variational theorem (RMVT), is developed for the three-dimensional (3D) coupled electro-elastic analysis of simply-supported, functionally graded piezoelectric material (FGPM) plates with open- and closed-circuit surface conditions and under electro-mechanical loads. In this formulation, the material properties of the plate are assumed to obey an exponent-law varying exponentially through the thickness coordinate, and the plate is divided into a number of finite rectangular layers, in which the trigonometric functions and Lagrange polynomials are used to interpolate the in- and out-of-plane variations of the primary field variables of each individual layer, respectively, such as the elastic displacement, transverse shear and normal stress, electric potential, and normal electric displacement components. The relevant orders used for expanding these variables in the thickness coordinate can be freely chosen as the linear, quadratic and cubic orders. Four different mechanical/electrical loading conditions applied on the top and bottom surfaces of the plate are considered, and the corresponding coupled electro-elastic analysis of the loaded FGPM plates is undertaken. The accuracy and convergence rate of the RMVT-based FLMs are assessed by comparing their solutions with the exact 3D piezoelectricity ones available in the literature.

Study of Reverse Design for an Axial Turbine Blade Profile and Design Parameters for Designing Blade Geometry (축류형 터빈 익형의 역설계 및 형상설계를 위한 설계변수에 관한 연구)

  • Cho, Soo-Yong;Oh, Koon-Sup;Choi, Bum-Seog
    • The KSFM Journal of Fluid Machinery
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    • v.3 no.2 s.7
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    • pp.7-14
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    • 2000
  • For a given axial turbine blade, reverse design method is developed to improve blade efficiency, optimize blade profile, or repair parts etc. In this process, design parameters for designing axial turbine blade are induced. The induced design parameters are as follows; ellipse at leading edge, radios of trailing edge, axial chord, tangential chord, wedge angle at the inlet, and unguided turning angle. Suction and pressure surfaces of turbine blade are described by cubic polynomials. Two sample blades we chosen and their blade profiles are measured at the mean radius. Values of design parameters for sample blades are obtained by the reverse design method. Re-designed blade profiles using calculated design parameters are compared with the measured data, and they show good agreement. So, the developed design method could be applied to design general turbine blades. Various blade shapes are designed, and they show that designed blade profiles can be adjusted by controlling design parameters.

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Preparation and Characterization of $Fe_3O_4$/MWNTs Composites (산화철이 혼입된 다중벽탄소나노튜브 복합체의 제조 및 특성)

  • Park, Soo-Jin;Kim, Young-Ha
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.406-409
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    • 2009
  • In this work, the magnetite ($Fe_3O_4$)/multi-walled carbon nanotubes (MWNTs) composites for lithium secondary battery were prepared. Nano-$Fe_3O_4$ was deposited by chemical coprecipitation of $Fe^{2+}$ and $Fe^{3+}$ in the presence of MWNTs in alkaline solutions. Transmission electron spectroscopy (TEM) and X-ray diffraction (XRD) analyses indicated that nano-$Fe_3O_4$ particles had a good crystallinity of cubic specimens and many tiny particles attached on the surfaces of the MWNTs. The electrochemical properties of $Fe_3O_4$/MWNTs composites as anodes in lithium-secondary batteries were evaluated by cyclic voltammetry and galvanostatic charge/discharge techniques. The as-prepared $Fe_3O_4$/MWNTs composites showed an initial lithium storage capacity of 1120 mAh/g and a reversible capacity of 394 mAh/g after 100 cycles, demonstrating better performance than that of the commercial graphite anode materials.

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Synthesis and Microstructural Changes of Nanostructured Tungsten Carbide Powder by Chemical Vapor Condensation Process (화학기상응축법에 의한 나노구조 텅스텐카바이드 분말의 제조와 미세구조 변화)

  • ;;;;O.V.Tolochko
    • Journal of Powder Materials
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    • v.9 no.3
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    • pp.174-181
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    • 2002
  • Nanosized tungsten carbide powders were synthesized by the chemical vapor condensation(CVC) process using the pyrolysis of tungsten hexacarbonyl($W(CO)_6$). The effect of CVC parameters on the formation and the microstructural change of as-prepared powders were studied by XRD, BET and TEM. The loosely agglomerated nanosized tungsten-carbide($WC_{1-x}$) particles having the smooth rounded tetragonal shape could be obtained below $1000^{\circ}C$ in argon and air atmosphere respectively. The grain size of powders was decreased from 53 nm to 28 nm with increasing reaction temperature. The increase of particle size with reaction temperature represented that the condensation of precursor vapor dominated the powder formation in CVC reactor. The powder prepared at $1000^{\circ}C$ was consisted of the pure W and cubic tungsten-carbide ($WC_{1-x}$), and their surfaces had irregular shape because the pure W was formed on the $WC_{1-x}$ powders. The $WC_{1-x}$ and W powders having the average particles size of about 5 nm were produced in vacuum.