• Journal of the Korean Ceramic Society
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• v.21 no.3
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• pp.239-244
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• 1984

The effect of tetragonal $ZrO_2$ phase on the mechanical behavior in 7 mole% calcia partially stabilized zirconia has been studied. The $ZrO_2$ powder containg 7 mole% CaO prepared by Hot Petroleum Drying Method calcined at 80$0^{\circ}C$ for 1 hour was nearly 100% tetragonal but as the calcining temperature increased certain amount of monoclinic phase appeared. The sintered specimen at 1$700^{\circ}C$ for 5 hours was aged at 130$0^{\circ}C$ for 0, 24, 48, 72 hours. X-ray diffraction data showed that in the aged specimen monoclinic tetragonal and cubic phase coexisted. The Kc value of aged specimen for 48 hr was about 4.5MN/m3/2 much greater than unaged sample. But aged for 72 hr the KiC value was decreased. The increasing of toughness in PSZ is based on the Stress-Induced Phase Transformation that is metastable tetra-gonal $ZrO_2$ changes t stable monoclinic phase within the stress field of crack and the mechanical fracture energy absorption is occured But in this case due to certain amount of tetragonal phase transformed to monoclinic phase during cooling the microcrack effect by transformation also considered. Trerefore both Stress-Induced Phase Transformation and inclusion induced microcracking effect contrbute to the increase of fracture toughness of 7 mole% CaO-$ZrO_2$ containing monoclinic and tetragnola phase simulataneously.

• Bulletin of the Korean Chemical Society
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• v.35 no.8
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• pp.2505-2511
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• 2014

Indium oxide nanocrystals ($In_2O_3$ NCs) with sizes of 5.5 nm-10 nm were synthesized by hot injection of the mixture precursors, indium acetate and oleic acid, into alcohol solution (1-octadecanol and 1-octadecence mixture). Field emission transmission electron microscopy (FE-TEM), High resolution X-Ray diffraction (X-ray), Nuclear magnetic resonance (NMR), and Fourier transform infrared spectroscopy (FT-IR) were employed to investigate the size, surface molecular structure, and crystallinity of the synthesized $In_2O_3$ NCs. When covered by oleic acid as a capping group, the $In_2O_3$ NCs had a high crystallinity with a cubic structure, demonstrating a narrow size distribution. A high mobility of $2.51cm^2/V{\cdot}s$ and an on/off current ratio of about $1.0{\times}10^3$ were observed with an $In_2O_3$ NCs thin film transistor (TFT) device, where the channel layer of $In_2O_3$ NCs thin films were formed by a solution process of spin coating, cured at a relatively low temperature, $350^{\circ}C$. A size-dependent, non-monotonic trend on electron mobility was distinctly observed: the electron mobility increased from $0.43cm^2/V{\cdot}s$ for NCs with a 5.5 nm diameter to $2.51cm^2/V{\cdot}s$ for NCs with a diameter of 7.1 nm, and then decreased for NCs larger than 7.1 nm. This phenomenon is clearly explained by the combination of a smaller number of hops, a decrease in charging energy, and a decrease in electronic coupling with the increasing NC size, where the crossover diameter is estimated to be 7.1 nm. The decrease in electronic coupling proved to be the decisive factor giving rise to the decrease in the mobility associated with increasing size in the larger NCs above the crossover diameter.

• Journal of Mechanical Science and Technology
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• v.20 no.5
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• pp.710-716
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• 2006

Micro-PIV system with a high speed CCD camera is used to measure the flow field near the advancing meniscus of a water slug in microchannels. Image shifting technique combined with meniscus detecting technique is proposed to measure the relative velocity of the liquid near the meniscus in a moving reference frame. The proposed method is applied to an advancing front of a slug in microchannels with rectangular cross section. In the case of hydrophilic channel, strong flow from the center to the side wall along the meniscus occurs, while in the case of the hydrophobic channel, the fluid flows in the opposite direction. Further, the velocity near the side wall is higher than the center region velocity, exhibiting the characteristics of a strong shear-driven flow. This phenomenon is explained to be due to the existence of small gaps between the slug and the channel wall at each capillary corner so that the gas flows through the gaps inducing high shear on the slug surface. Simulation of the shape of a static droplet inside a cubic cell obtained by using the Surface Evolver program is supportive of the existence of the gap at the rectangular capillary corners. The flow fields in the circular capillary, in which no such gap exists, are also measured. The results show that a similar flow pattern to that of the hydrophilic rectangular capillary (i.e., center-to-wall flow) is always exhibited regardless of the wettability of the channel wall, which is also indicative of the validity of the above-mentioned assertion.

• Korean Journal of Materials Research
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• v.21 no.8
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• pp.439-443
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• 2011

The crystal structure and magnetic properties of a new solid solution type ferrite $(Fe_2O_3)_5-(Al_2O_3)_{3.4}-(Ga_2O_3)_{0.6}-SiO$ were investigated using X-ray diffraction and M$\"{o}$ssbauer spectroscopy. The results of the X-ray diffraction pattern indicated that the crystal structure of the sample appears to be a cubic spinel type structure. The lattice constant (a = 8.317 ${\AA}$) decreases slightly with the substitution of $Ga_2O_3$ even though the ionic radii of the Ga ions are larger than that of the Al ions. The results can be attributed to a higher degree of covalency in the Ga-O bonds than in the Al-O and Fe-O bonds, which can also be explained using the observed M$\"{o}$ssbauer parameters, which are the magnetic hyperfine field, isomer shift, and quadrupole splitting. The drastic change in the magnetic structure according to the Ga ion substitution in the $ (Fe_2O_3)_5(Al_2O_3)_{4-x}(Ga_2O_3)_xSiO$ system and the low temperature variation have been studied through a M$\"{o}$ssbauer spectroscopy. The M$\"{o}$ssbauer spectrum at room temperature shows the superpositions of two Zeeman patterns and a strong doublet. It shows significant departures from the prototypical ferrite and is comparable with the diluted ferrite. The doublet of spectrum at room temperature appears to originate from superparamagnetic clusters and also the asymmetry of the doublet appears to be caused by the preferred orientation of the crystallites. The M$\"{o}$ssbauer spectra below room temperature show various complicated patterns, which can be explained by the freezing of the superparamagnetic clusters. On cooling, the magnetic states of the sample were various and multi critical.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.44 no.2
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• pp.149-153
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• 1999

Prediction of rice developmental stage is necessary for proper crop management and a prerequisite for growth simulation as well. The objectives of the present study were to find out the relationship between the plastochrone index(PI) and the developmental index(DVI) estimated by non-parametric phenology model which simulates the duration from seedling emergence(DVI=0) to heading(DVI=l) by employing daily mean air temperature and daylength as predictor variables, and to confirm the correspondency of developmental indice to panicle developmental stages based on this relationship. Four japonica rice cultivars, Kwanakbyeo, Sangpungbyeo, Dongjinbyeo, and Palgumbyeo which range from very early to very late in maturity, were grown by sowing directly in dry paddy field five times at an interval of two weeks. Data for seedling emergence, leaf appearance, differentiation stage of primary rachis branch and heading were collected. The non-parametric phenology model predicted well the duration from seedling emergence to heading with errors of less than three days in all sowings and cultivars. PI was calculated for every leaf appearance and related to the developmental index estimated for corresponding PI. The stepwise polynomial analysis produced highly significant square-rooted cubic or biquadratic equations depending on cultivars, and highly significant square-rooted biquadratic equation for pooled data across cultivars without any considerable reduction in accuracy compared to that for each cultivar. To confirm the applicability of this equation in predicting the panicle developmental stage, DVI at differentiation stage of primary rachis branch primordium was calculated by substituting PI with 82 corresponding to this stage, and the duration reaching this DVI from seedling emergence was estimated. The estimated duration revealed a good agreement with that observed in all sowings and cultivars. The deviations between the estimated and the observed were not greater than three days, and significant difference in accuracy was not found for predicting this developmental stage between those equations derived for each cultivar and for pooled data across all cultivars tested.

• Archives of design research
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• v.14 no.2
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• pp.47-56
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• 2001

What is 'fusion'\ulcorner And how should we accept it, which has been appeared before us with an irresistible force in the 21 century through the whole area of scientific branches\ulcorner And does it mean a mere physical 'mixture' or a chemical 'compound' among the fused parties\ulcorner And is it an impartial fusion among the parties or a partial Fusion absorbed by the stronger party\ulcorner We cannot give a right answer without full comprehension of the meaning and process of Fusion. In this respect, 1 would like to touch upon many of these matters on Fusion and stir a attention to the fact that our life quality must not be damaged by the sudden appearance of Fusion in this era. In the future, there will be a bigger Fusion in so many a field than now between the advanced and the underdeveloped countries of the world. Nevertheless, it doesn't always follow that Fusion gives us the best way of arriving to happy lives. There are still too many undesirable things in it. And then, I conclude that it is through the multidisciplinary research and its systematic analyses that we can solve many negative problems on Fusion.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.6-6
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• 2010

Indium Tin Oxide (ITO)를 포함한 Transparent Conduction Oxide (TCO)는 LCD, OLED와 같은 Display, 그리고 Solar Cell 등 광신호와 전기신호간 변환이 필요한 모든 Device에 반드시 필요한 핵심 물질로, 특히 고특성 Display의 투명전극에서 요청되는 95% 이상의 투과도와 $15\;{\Omega}/{\square}$ 이하의 면저항 특성을 동시에 만족할 수 있는 기술은 현재까지 Plasma Sputtering 공정으로 $160^{\circ}C$ 이상에서 증착된 ITO 박막이 유일하다. 그러나, 최근 차세대 기술로서 Plastic Film을 기반으로 하는 Flexible Display 및 Flexible Solar Cell 구현에 대한 요구가 급증하면서, Plastic Film 기판위에 Plasma Damage이 없이 상온에 가까운 저온 ($100^{\circ}C$ 이하)에서 특성이 우수한 ITO 투명전극을 형성 할 수 있는 기술의 확보가 중요한 현안이 되고 있다. 지난 10년 동안 $100^{\circ}C$이하 저온에서 고특성의 ITO 또는 TCO 박막을 얻기위한 다양한 연구와 구체적인 공정이 활발히 연구되어 왔으나, ITO의 결정화 온도 (통상 $150{\sim}180^{\circ}C$)이하에서 증착된 ITO박막은 비정질 상태의 물성적 특성을 보여 원하는 전기적, 광학적 특성확보가 어려웠다. 본 논문에선 기본적으로 절연체 특성을 가져야 하는 산화물인 TCO가 반도체 또는 도체의 물리적 특성을 보여주는 기본원리의 고찰을 토대로, 재료학적 특성상 Crystalline 구조를 보여야 하는 ITO (Complex Cubic Bixbyte Structure)가 Plasma Sputtering 공정으로 저온에서 증착될 때 비정질 구조를 갖게 되는 원인을 규명하고, 이를 바탕으로 저온에서 증착된 ITO가 Crystalline 구조를 유지 할 수 있게 하고, Stress Control에 유리한 Nano-Crystalline 박막을 형성하면서 Crystallinity를 임의로 조절 할 수 있는 새로운 기술인 Magnetic Field Shielding Sputtering (MFSS) 공정과 최근 성과를 소개한다. 한편, 또 다른 새로운 저온 TCO 박막형성 기술로서, 유기반도체와 같은 Process Damage에 매우 취약한 유기물 위에 Plasma Damage 없이 TCO 박막을 직접 형성할 수 있는 Neutral Beam Assisted Sputtering (NBAS) 기술의 원리를 설명하고, 본 공정을 적용한 Top Emission OLED 소자의 결과를 소개한다. 또한, 고온공정이 수반되는 Solar Cell용 투명전극의 경우, 통상의 TCO박막이 고온공정을 거치면서 전기적 특성이 열화되는 원인을 규명하고, 이에 대한 근본적 해결 방법으로 ITO 박막의 Dopant인 Tin (Sn) 원자의 활성화를 증가시킨 Inductively Coupled Plasma Assisted DC Magnetron Sputtering (ICPDMS)의 원리와 박막의 물성적 특성과 내열 특성을 소개한다.

• Journal of Korean Society of Rural Planning
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• v.3 no.2
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• pp.36-49
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• 1997

The drastic change of mountain community, which have led existing villages to a size reduction or an extinction, makes this study concentrate on finding out the new community unit as a spatial zone of dayily life and agricultural production. The communality which has played a key role in a aura settlement consistency has been focused on the socio-economic aspect till now, neglecting the spatia] nature. The settlement-communality( SC) putting a stress on the spatial aspect can be, therefore, shapec as being multi-dimensional, composed of both a horizontally areal coverage on the surface of the residential place and a vertically hierarchial relationship between settlements, by analyzing thro( elements of communality that are the economic, socio -cultural and spatial activities. The research site is located administratively in Milan-Myoun, Pyoungchang-Gun, Gangwon-Do that ha: the characteristics as a typical mountain community. The results of field survey of which the method i: to draw the activity zone from an interview with every village's head and some residents with th( prepared questionaire can be summarized as followings. Firstly, the SC in almost all villages tended to be weakened or extincted, none the less, the spatia zone of that overally enlarged and got out of natural village unit(hamlet). However the areal coverall on which the SC has an influence reaches up to the alliant domain of a few villages generally congruen with the lowest level administrative district, Secondly, the economic and social activity pattern in village life has a tendency to be directly linked with a upper central place, so that has induced the function of a central village in the middle-low settlement hierarchy to be largely shrinked. Not only the conventional residents'access to goods service but also the recent service-delivers'access to residents has gradually formed the vertical communality with direct linkage between the upper and the bottom level settlements Lastly, the enfeeblement of the SC in the lowest settlement level tends to be supplemented by enlarging the horizontal zone of the SC or especially by strengthening the vertical direct linkage system. The very this point makes the mountain community open to the external world and also makes the spatial unit of community be multi-dimensional just like a cubic.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.43 no.10
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• pp.875-887
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• 2015

The optimal layout design is used in the development of various areas of industry. In the field of space systems, components must be placed properly in the limited space of spacecraft by considering mechanical, thermal and electrical interfaces. When applying optimal layout design, a proper, even ideal placement of components is possible in the limited space of a satellite platform. Through the optimal placement design, the minimized moment of inertia enhances efficient attitude control, rapid maneuver and mission performance of the satellite. This paper proposes 3D optimal layout design that minimizes the spacecraft's moment of inertia and effect of thermal dissipation between inner components as well as interference between inner components based on a cubic-structure satellite platform. This study proposes the new genetic algorithm for 3D optimal layout design of the satellite platform.

• Journal of the Korean Magnetics Society
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• v.17 no.1
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• pp.26-29
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• 2007

Fe-based powders, Fe-M(M=Cr, Mn, Cu, Zn), were prepared in Ar gas by mechanical alloying and their crystallographic and magnetic properties were investigated. X-ray diffraction indicates that the cubic lattice parameter increases for the M substitution. The distance of closest approach around M can explained the increase of lattice constant in Fe-M powders. $M\"{o}ssbauer$ spectroscopy measurements on Fe-M samples indicates the coexistence of ferromagnetic phases and paramagnetic phase that are created by the distribution of local environment M on Fe atom. On the other hand, The spread of line-width on $M\"{o}ssbauer$ spectra can be explained by the distribution of hyperfine magnetic fields. The results of quadrupole shift and isomer shift revealed that M substitutions in Fe-M powders didn't change both structure and the local charge distribution around Fe atom severely.