• Title/Summary/Keyword: crytal structure

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Streptomyces sp. YJB-599가 생산하는 Genistein의 분리 및 정제

  • 함병권;배동훈;유주현
    • Microbiology and Biotechnology Letters
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    • v.24 no.3
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    • pp.311-315
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    • 1996
  • A cytotoxic material was produced by strain No. 5-99 which was isolated from soil. Analyzing the cell wall components, LL-diaminopimelic acid was identified. From the existance of glycine in the cell wall, this strain was identified to Streptomyces sp. which has cell wall chemotype I and peptidoglycan type A3 connected by glycine. So, we named this strain to Streptomyces sp. YJB-599. The Active material was purified through solvent extraction, silica gel column chromatography and crystallized to needle-shaped white -crystal. Analyzing the structure of this crytal by instrumental analysis and database, it was determined to genistein.

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Vertically Aligned Nematics at Polymer interfaces and Its device implications

  • Srinivasarao, Mohan;Park, Jung-Ok;Zhou, Jian
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.558-561
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    • 2005
  • In-situ photopolymerization of alkyl acrylate monomers in the presence of a nematic fluid provides a cellular matrix of liquid crystalline droplets in which the chemical structure of the encapsulating polymer exerts control over the alignment (anchoring) of the liquid crystalline molecules. Control is obtained by variation of the alkyl side chains and through copolymerization of two dissimilar monofunctional acrylates. Two monofunctional acrylates with opposing tendencies on copolymerization provide control over the tunability of anchoring over a wide temperature range. Using various acrylates we show that a uniform vertical alignment can be achieved over a large area. Utilizing this technique and a nematic with negative dielectric anisotropy, we have fabricated highly flexible liquid crytal based devices, with high contrast and fast response time, without using any alignment layer.

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Differences on Tension, Compression JC Constitutive Equation Parameter of Strain Rate Effect for Ti-6Al-4V (Ti-6Al-4V 변형률 속도 변화에 따른 인장, 압축형 JC 구성방정식 변수의 변화)

  • Woo, Sang-Hyun;Lee, Chang-Soo;Park, Lee-Ju
    • Korean Journal of Materials Research
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    • v.27 no.1
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    • pp.19-24
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    • 2017
  • This paper is concerned with a test method that can be used to investigate the parameters of the Johnson-Cook constitutive model. These parameters are essential for accurately analyzing material behavior under impact loading conditions in numerical simulation. Ti-6Al-4V alloy (HCP crytal structure) was used as a specimen for the experiments. In the $10^{-3}-10^3/s$ strain rate range, three types of experimental methods (convention, compression and tension) were employed to compare the differences using MTS-810, SHPB and SHTB. Finite element analysis results when applying these parameters were displayed along with the experiment results.

Mixing effect on Properties of NTC Thermistor in Mn-Co-O System (Mn-Co-O계 NTC 써미스터의 물성에 미치는 혼합의 영향)

  • Yoon, Sang-Sik;Kim, Kyung-Sik;Yoon, Sang-Ok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.459-462
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    • 2001
  • Interface effects on properties of NTC thermistors having Mn-Co-O spinel crytal structure system are analyzed by a mixing rule in case of mixed types and layered types between CuO and $Al_{2}O_{3}$ added compounds. With adding CuO and $Al_{2}O_{3}$, The compounds form completely solid solution and their resistance and B constant are changed due to the variation of conduction electrons by their ionic substitutions. The properties of mixed NTC thermistors are depended on the logarithmic mixing rule by a dispersed phase and they show slightly lower values due to the lattice mixing affect in compared with calculated values. The resistance of layered NTC thennistors is depended upon the series mixing rule containing the value of an interface layer and effected by the variation of its thickness, and it is changed rapidly to the logarithmic mixing rule by the connection between two layers with increasing the interface layer.

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Crytal Structure Study of Random Copolymers by CPMAS Solid-State NMR Spectrosecopy (고체상태에서의 CPMAS NMR분광법을 이용한 랜덤 공중합체의 결정구조 연구)

  • Yoo, Hee-Yeoul;Shim, Mi-Ja;Kim, Sang-Uk
    • Korean Journal of Materials Research
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    • v.3 no.4
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    • pp.344-351
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    • 1993
  • The crystal structunes of poly(ethylene terephthalate-eo-1, 4 cyciohexylene dimethylene terephthalate), P(ET CT), copolymers were studied by CPMAS solid state NMR spectroscopy. With the estimation of methylene resonance peaks, the bulkier CT component of the copolymer in the range of 0 20 mol% CT is excluded from the ET crystal lattice, whereas smaller ET component of the copolymer in the range of 66 100 mol% CT can be partially included into the CT crystal lattice. Those different crystallization behavior can be explained with the difference in chain bulkiness and crystal lattice dimension be tween two copolymer compurwnts.

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The Crytal and Molecular Structure of Morpholinothiosemicarbazide (Morpholinothiosemicarbazide의 結晶 및 分子構造)

  • Chung Hoe Koo;Hoon Sup Kim;Hyun So Shin;Yungja Lee
    • Journal of the Korean Chemical Society
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    • v.17 no.2
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    • pp.105-114
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    • 1973
  • The crystal structure of morpholinothiosemicarbazide has been determined by single crystal X-ray analysis. The lattice constants are a = 4.19(2), b = 6.56(2) and c = 26.67(4)${\AA}$. The unit cell contains 4 molecules and the space group is$P2_12_12_1$. The atomic parameters have been refined by least-squares method to a final R value of 0.07, based on the 651 observed reflexions. The amino nitrogen atom forms hydrogen bonds to the sulfur atoms of the other molecules related by the two-fold screw axis parallel to the a-axis, the distances of the hydrogen bonds being 3.48 and 3.49${\AA}$. On the other hand, the imino nitrogen atom forms a hydrogen bond to the amino nitrogen atom of the other molecule related by the two-fold screw axis parallel to the a-axis, the distance of the hydrogen bond being 3.04${\AA}$. These three hydrogen bonds arrange the molecules around the two-fold screw axis. Apart from the hydrogen bonding system the structure is held together by van der Waals forces.

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