• Carbon letters
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• 제19권
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• pp.89-98
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• 2016

Taguchi’s experimental design was employed in the melt spinning of molten mesophase pitch to produce carbon fibers. The textures of the obtained carbon fibers were radial with varied crack angles, as observed by scanning electron microscopy and polarized optical imaging. The diameter, crack angle, preferred orientation, and tensile modulus of the produced samples were examined to investigate the influence of four spinning variables. The relative importance of the variables has been emphasized for each characteristic. The results show that thicker carbon fiber can be obtained with a smaller entry angle, a higher spinning temperature, a reduced winding speed, and an increased extrusion pressure. The winding speed was found to be the most significant factor in relation to the fiber diameter. While it was observed that thicker carbon fiber generally shows improved preferred orientation, the most important variable affecting the preferred orientation was found to be the entry angle. As the entry angle decreased from 120° to 60°, the shear flow was enhanced to induce more ordered radial alignment of crystallite planes so as to obtain carbon fibers with a higher degree of preferred orientation. As a consequence, the crack angle was increased, and the tensile modulus was improved.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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• pp.102-102
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• 2003

TLCP/polyester composite fibers (TPCFs) based on melt blends of PEN, PET, and TLCP were prepared by melt blending and spinning process to achieve high performance fibers. Reinforcement effect and TLCP fibrillar structure resulted in improvement of mechanical properties for TPCFs. The increase in the apparent crystallite size was attributed to the development of larger crystallites and more ordered crystalline structures in the annealed TPCFs. Molecular orientation was an important factor to determine mechanical property of TPCFs.

• 한국의류학회지
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• 제20권3호
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• pp.467-480
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• 1996

Interactions between PET POY and solvents were estimated by the changes in microstructure and surface morphology. Changes in microstructure and surface morphology by the solvent treatments were: an increase in crystallite size, a decrease in interplanar spacing, a change in degree of orientation of crystalline region, a change in surface characteristics.

• 한국표면공학회지
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• 제17권4호
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• pp.106-119
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• 1984

Brass was electrodeposited over the range of the current densities from 2 to 8 A/$dm^2$ in cyanide bath at 20 and 40$^{\circ}C$. The cathode overpotential increased and the cathode efficiency was decreased respectively with decreasing temperature, increasing current density and addition of organic substance. The perferred orientation of the deposits were associated with the cathode overpotential and the nucleation energy of lattice planes. The (111) preferred orientation developed at the low current density and low cathode overpotential (440-520mV). On the other hand, the (111)+(100) preferred orientation developed at higher cathode overpotential (528-680mV). The (111)+(100) preferred orientation developed over the whole range of overpotential in the cyanide solution with organic additive. The copper content of deposit decreased with increasing current density and decreasing temperature. The morphology of the deposits with no additive was the polygonal body type of structure and the structure of the cross section was columnar structure. The morphology of the deposits with additive, on the other hand, was fine crystallite type of structure. And the structure of the cross section of them was the finer granular structure.

• Journal of the Korean Wood Science and Technology
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• 제22권3호
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• pp.26-31
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• 1994

To provide further information for reutilization of the waste wood obtained after cultivating oak mushroom in Kangwon-do, the crystal structures of the waste wood were investigated and compared to those of normal woods by a series of x-ray diffraction analysis. The results obtained are as follows: 1. An x-ray diffraction diagram of cultivated wood for 5 years was same as that of typical cellulose with some orientation of cellulose crystallites, but that of cultivated wood for 8 years a random. 2. Crystallinity indices in normal and cultivated woods for 5 years ranged from 57% to 60%. In the cultivated wood for 8 years, however, the value showed about 40%. 3. Crystallite widths of cultivated woods for 5 years and for 8 years were 3 nm and 2.5 nm, respectively. 4. Intensity ratios of equatorial and meridional layers did not show any significant differences. From the above results, it is clear that the waste wood obtained after cultivating oak mush room for 5 years showed basically same crystal structures with normal wood. Therefore, we think that the waste wood may be used available for cellulosic material instead of normal wood.

• 한국세라믹학회지
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• 제23권1호
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• pp.44-50
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• 1986

Si-ZnO n-n heterojunction diodes were prespared by r.f diode sputtering of the sintered ZnO target on n-type Si single crystal wafers and their structures and electrical properties were studied. The films were grown orientedly with the c-axis of crystallites perpendicular to the substrate surface at low r.f. powder and grown to polycrystalline films with random orientation at high r. f. powder. The crystallite size increased with the increasing substrate temperture The oriented texture films only were used to prepare the photovoltaic diodes and these didoes showed the photovoltaic effect veing positive of the ZnO side for the photons in the wavelength range of 380-1450nm. The sign reversal of phootovoltage which is the property os isotype heterojunction was not observed because of the degeneration of the ZnO films. The diode showed the forward rectification when it was biased with the ZnO side positive. The current-voltage characteristics exhibited the thermal-current type relationship J∝exp(qV/nkT) with n=1.23 at the low forward bias voltage and the tunnelling-current type relationship J∝exp($\alpha$V) where $\alpha$ was constant independent of temperature at the high forward bias voltage. The crystallite size of ZnO films were influenced largely on the photovoltaic properties of diodes ; The diodes with the films of the larger crystallites showed the poor photovoltaic properties. This reason may be cosidered that the ZnO films with the large crystallites could not grow to the electrically continuous films because the thickness of films was so thin in this experiment.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 하계학술대회 논문집 C
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• pp.1397-1399
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• 2002

Effects of bottom electrode materials (Al, Cu, Ti, and Mo), included in film bulk acoustic resonators (FBARs), on the orientation of piezoelectric AlN thin films and the frequency response characteristic of resonators were investigated. The texture coefficient (TC) for (002) orientation, crystallite size, full width half maximum (FWHM), and surface roughness of deposited AlN films were measured for the various bottom electrodes. The return tosses estimated from the frequency responses of fabricated resonators were also compared. Experimental results showed that the difference of lattice constant and thermal expansion coefficient between the bottom electrode and the AlN film were the most important factors for achieving a high performance resonator.

• 한국재료학회지
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• 제9권1호
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• pp.30-34
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• 1999

A polyacrylonitrile(PAN)-based carbon fiber tow was heat-treated by directly passing electric current through the tow. The effects of the stretching stress applied during high temperature heat-treatment of PAN-based carbon fibers were investigated by measuring the electric resistance changes taking place during the internal resistance heating. The structure parameters characterizing the stacks of carbon layer, such as interlayer spacing, sizes and orientation of the carbon fibers heat-treated with hot-stretching were evaluated as a function of surface temperature of tow during heat treatment in the range of $1000~2400^{\circ}C$. Though the layer extent in the fiber axis direction depends strongly on the electric resistance, the changes in a crystallite parameter is independent of the longitudinal strain.

• 한국염색가공학회지
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• 제8권6호
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• pp.33-39
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• 1996

The purpose of this study was to investigate the structural characteristics, mechanical properties, and stress-relaxation behavior of PET filament, which were prepared at various spinning speeds(1650, 3300, 4500, 5000, 5500, and 6000 m/min) and anneal(12$0^{\circ}C$, 20 min & 15$0^{\circ}C$, 40 min). In 4500 m/min of spinning speed the crystallinity, crystallite size, and degree of orientation of PET filament rapidly increased. By increasing spinning speed, the temperature dependence of stress-relaxation sharply decreased. Same results were obtained from heat-treated samples. As a result, activation energy for stress-relaxation increased with the crystallinity and spinning speed.

• 한국표면공학회지
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• 제30권3호
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• pp.202-212
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• 1997

The composition and the microstructure of the Sn-Ni alloy electrodeposited in pyrophosphate bath were investigated according to the electrolysis conditions. The cathode current efficiency increased with the addition of $NH_4CI$ and glycine, while it decreased with the increase of current density. The Sn content of the alloy deposits increased with the increase of $NH_4CI$ in the bath. The alloys with 51~71wt.% Sn had the NiSn single phase structure. The preferred orientation of the single phase alloys changed from (110) to (110)+(101) with the increase of current density and cathode overpotential. The single phase alloys with 50~60wt.%Sn had the smooth surface structure with fine crystallite, while the multiphase alloys showed the surface structure with crystal size and cracks at high curret density.