• 대한기계학회논문집A
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• 제29권7호
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• pp.1022-1027
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• 2005

In this study, ball milling process was applied to reduce the particle size of bio-material down to submicron size. The material used was Ibuprofen. The ball milling was performed at low temperature of about $-180^{\circ}C$. The effect of processing conditions (milling time, milling speed) on the particle size was determined. The results showed that the degree of crystallite of Ibuprofen was slightly reduced by the ball milling process. The results also showed that the size of Ibuprofen was significantly reduced by the ball milling process. The effect of milling time was significant within the milling time of six hours while it was small thereafter.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.149-149
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• 2011

CdS films were deposited on glass substrates by R.F. magnetron sputtering method and the films were annealed at various substrate temperatures ranging from room temperature to $300^{\circ}C$. Structural properties of the films were studied by X-ray diffraction analysis. The structural parameters as crystallite size have been evaluated. The crystallite sizes were found to increase, and the X-ray diffraction patterns were seen to sharpen by increasing substrate temperatures. X-ray diffraction patterns of these films indicated that they contain both cubic (zincblende) and hexagonal (wurtzite) structures as a mixture. Optical properties of the films were measured at room temperature by using UV/VIS spectrometer in the wavelength range of 190 to 1100nm and optical absorption coefficients were calculated using these data. The energy gap of the films was found to decrease, and the band edge sharpness of the optical absorption was seen to oscillate by annealing. The results show that heat treatments under optimal annealing condition can provide significant improvements in the properties of CdS thin films.

• 대한화학회지
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• 제13권4호
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• pp.395-399
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• 1969

On the soft carbon made from petroleum coke, it was found that the graphitization began at around 2,000$^{\circ}C and crystallite diameters were almost saturated at 2,400$^{\circ}C., and that the molecular planes were difficult to arrange into an ideal graphite lattice in spite of the saturation of crystallinity by heat treatment temperature. On the hard carbon made from cross-linked thermosetting plastics, phenol-formaldehyde filler and phenol-benzaldehyde binder, it was very difficult to rotate the molecular planes into a regular directional arrangement and into a consecutive order corresponding to the large graphite crystals. In addition to the above mentioned crystallinity, it was also determined in relation to electric conductivity, resistivity, hardness and apparent density of carbons.

• Macromolecular Research
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• 제10권1호
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• pp.44-48
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• 2002

The supermolecular structures of poly(ethylene terephthalate) (PET), poly(ethylene 2,6-naphthalate) (PEN), and their blend were investigated with optical microscopy and small angle light scattering. With increasing the crystallization temperature, incomplete spherulitic texture was developed for the PET samples. At a high crystallization temperature of 220 $^{\circ}C$, the light scattering pattern represented a random collection of uncorrelated lamellae. The general morphological appearances for the PEN samples were similar to that of the PET. A notable feature was that the spherulites of the PEN formed at 200 $^{\circ}C$ showed regular concentric bands arising from a regular twist in the radiating lamellae. The spherulitic morphology of the PET/PEN blend was largely influenced by the changes of the sequence distribution in polymer chains determined by the level of transesterifcation. The increased sequential irregularity in the polymer chains via transesterification caused a morphological transition from a regular folded crystallite to a tilted lamellar crystallite.

• 한국세라믹학회지
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• 제21권2호
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• pp.156-164
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• 1984

The characteristic of pyrolytic carbon deposited in a fluidized bed as measured by density apparent crystallite size and viewed metallographically under polarized light can be easily controlled by adjusting the deposition parameters such as deposition temperature and propane flow rate or silicon content. The density of isotopic pyrolytic carbons deposited from propane between 120$0^{\circ}C$ and 140$0^{\circ}C$ increases with increasing propane flow rate and decreasing deposition temperature from 1, 73g/cc to 2.08g/cc. The apparent crystallite size Lc parameter appears to depend only on deposition temperature being entirely independent of the propane flow rate. The carbon matrix density of the silicon-alloyed carbonds deposited from propane and methyltrichlorosil-ane from 2.05g/cc for a silicon content around 9wt% to 2.67g/cc for a silicon content of 36.7wt% The Lc parameter of the deposition temperature being entirely independent of the silicon content.

• 한국염색가공학회지
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• 제8권3호
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• pp.16-23
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• 1996

In order to know the change of weight loss, crystallinity, crystallite size(010) plane, and thermal properties of PET films which had before drawn and annealed at various temperature. It were treated in sodium triethylene glycolate-triethylene glycol(STEG-TEG) were prepared. The following results were abtain. The weight loss of PET films were increasing with increaing treated time in STEG-TEG solution and It showed a linear rlationship to the treated time. The crystallinity and crystallite size(010) plane of PET films decreased with increasing decomposition ratio when PET films were treated with before annealed under 16$0^{\circ}C$. The crystalline region on the surface of samples were decompose to thermal unstable crystalline structure

• Journal of Magnetics
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• 제18권1호
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• pp.1-4
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• 2013

Structural and magnetic properties of $Fe_{50}Mn_{50}$ nanocrystalline alloys prepared by the mechanical alloying technique (using commercial Fe and Mn powders as the precursors) are studied as a function of milling time, 1 hr to 48 hrs. The nano-crystallite size and shape are examined by using scanning electron microscopy (SEM). The effect of milling time on structural characterization was investigated using X-ray diffractometer (XRD) and extended X-ray absorption fine structure spectroscopy (EXAFS). Both XRD and EXAFS studies showed that the alloying process should be completed after 36 hrs milling. Concerning the magnetic behavior, the data obtained from superconducting quantum interference devices (SQUID) exhibited both magnetic saturation ($M_s$) and coercivity ($H_c$) depend strongly on the milling time, which are related to the changes in the crystallite size and magnetic dilution.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2002년도 춘계공동학술발표회요약집
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• pp.251-251
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• 2002

• 한국수소및신에너지학회논문집
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• 제16권3호
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• pp.238-243
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• 2005

Mg and Mg-based alloys are most important hydrogen storage materials. It is a lightweight and low-cost materials with high hydrogen storage capacity. However, the formation of hydride at high temperature, the deterioration effect, the hydriding and dehydriding kinetics are bad factor for application. In this study, Mg and Ni have been produced by hydrogen induced mechanical alloying(HIMA) process. The raw materials, Mg(purity 99.9%) chip and Ni(purity 99.95%) chip was prepared by using a planetary ball mill apparatus(FRITSCH pulverisette 5). The balls to chips mass ratio(BCR) are 30:1. The hydrogen pressure induced 2.0MPa and milling times were 12, 24, 48, 72, 96 hours with a rotating speed of 200rpm. X-ray diffraction(XRD) analysis was made to characterize the crystallite size and misfit strain. The crystallite size measured by laser particle size analysis(PSA). Microstructure changes were investigated by scanning electron microscopy(SEM) and the transmission electron microscopy(TEM). The hydrogen storage properties were evaluated by using an Sivert's type automatic pressure-composition-therm(PCT) apparatus.

• 산업기술연구
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• 제20권A호
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• pp.247-256
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• 2000

Precursor gels with the composition of $xZrO_2{\cdot}(100-x)SiO_2$ systems (x=10, 20 and 30 mol%) were prepared by the sol-gel method. Kinetic parameters, such as activation energy, Avrami's exponent, n, and dimensionality crystal growth value, m, have been simultaneously calculated from the DTA data using Kissinger and Matusita equations. The crystallite size dependence on tetragonal to monoclinic transformation of $ZrO_2$ was investigated using XRD, in relation to the fracture toughness. The crystallization of tetragonal $ZrO_2$ occurred through 3-dimensional diffusion controlled growth(n=m=2) and the activation energy for crystallization was calculated using Kissinger and Matusita equations, as about $310{\sim}325{\pm}10kJ/mol$. The growth of $t-ZrO_2$, in proportion to the cube of radius, increased with increasing heating temperature and heat-treatment time. It was suggested that the diffusion of Zr4+ions by Ostwald ripening was rate-limiting process for the growth of $t-ZrO_2$ crystallite size. The fracture toughness of $xZrO_2{\cdot}(100-x)SiO_2$ systems glass ceramics increased with increasing crystallite size of $t-ZrO_2$. The fracture toughness of $30ZrO_2{\cdot}70SiO_2$ system glass ceramics heated at $1,100^{\circ}C$ for 5 h was $4.84Mpam^{1/2}$ at a critical crystaliite size of 40 nm.