• The Korean Journal of Petroleum Geology
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• v.2 no.2 s.3
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• pp.83-90
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• 1994

Thermal maturation and diagenesis of the Gyeongsang Supergroup in the Euiseong area are studied by means of organic geochemical techniques and illite crystallinity. Black mudrocks of the Singdong Group contain organic matter of $0.5{\~}2{\%}$ derived from higher plants, being compared to type Ⅲ. Thermal maturity of organic matter reached dry gas generation phase. Tmax by Rock Eval pyrolysis varies between $578^{\circ}C$ and $593^{\circ}C$ regardless of stratigraphic position and localities, and vitrinite reflectance is about 2.9 and $3{\~}4{\%}Ro$ in the Jinju and the Nagdong Formations, respectively. Vitrinite reflectance measurements indicate that the maturation is mainly due to burial and partly to be affected by post-depositional intrusions. Illite crystallinity values from the Nagdong, Hasandong, Jiniu Formations and part of the Iljig Formation are plotted around the boundary between diagenesis and anchizone, indicating dry gas generation stage. However, the values are not dependent on stratigraphic position. The values from the Iljig, Hupyeongdong, Geomgog, and Sagog Formations fall into the range of anchizone, probably resulted from the post-depositional intrusions which occur locally. Both organic geochemical and illite crystallinity data indicate thermal maturation stage of dry gas generation. Diagenesis of the Gyeongsang strata is mostly controlled by burial, and partly affected by post-depositional intrusions. Paleotemperature of the Sindong Group is estimated at around $200^{\circ}C$ on the basis of illite crystallinity.

• Applied Chemistry for Engineering
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• v.30 no.2
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• pp.247-253
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• 2019

In this study, compounds with azo-mesogenic groups at 4-, 3,5-, or 3,4,5-positions of one phenyl ring were synthesized, and their liquid crystallinity and photochemistry were investigated. The compounds in the Azo1 and Azo2 series had linear and planar geometries, respectively, while those in the Azo3 series had relatively bulky structures. Compounds of BA-Azo2 and BA-Azo3 did not show any liquid crystallinity. Compounds of BE-Azo1 and BE-Azo2 exhibited a monotropic liquid crystallinity, while the other compounds showed an enantiotropic liquid crystallinity. The liquid crystalline behavior was imparted by the azo-mesogenic groups, and most of the liquid crystalline compounds formed a smectic phase. All the RM-AzoX compounds exhibited photoisomerism because of the presence of the azo groups in the molecule. The rate of photoisomerization followed the order of RM-Azo3 < RM-Azo1 < RM-Azo2 and was considered to depend on the steric hindrance around the azobenzene groups in the molecule. These results suggest that the liquid crystallinity and photochemical property of the compounds are affected by the position or the number of azo-mesogenic groups phenyl ring of the molecule.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.6
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• pp.872-879
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• 2010

Layered copper hydroxides [LCHs, $Cu_2(OH)_3{\cdot}NO_3$] has the agricultural potentials as a fungicide because of its high crystallinity, excellent anion exchange capacity, and its regular layered particle size. The study, for the first time, has synthesized LCHs in highly concentrated solution and evaluated its physicochemical properties including the crystallinity and suspension stability. Optimal synthetic condition of LCHs was determined by crystallinity and stability of suspension as follow; 1) concentrations of $Cu(NO_3)_2$ and NaOH solutions were 3.0 M respectively, 2) reaction temperature and solution pH were $25^{\circ}C$ and 6.0, respectively, and 3) aging time after reaction was 2hr. Crystallinity of LCHs enhanced with increase in pH up to 9.0. Whereas, stability of suspension was decrease by increase in crystal size. Especially, increase in reaction temperature decreased stability of suspension. XRD patterns and SEM images exhibited that LCHs had regular layered particle size with 0.2~0.8 ${\mu}m$ and high crystallinity in optimal synthetic condition. The particle size was increased with increase in reaction temperature and pH. These results showed that LCHs synthesized in highly concentrated solution exhibited high stability of suspension as well as high crystallinity suitable to their potential as a fungicide.

• Proceedings of the Materials Research Society of Korea Conference
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• 1996.05a
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• pp.131-131
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• 1996

• Proceedings of the Materials Research Society of Korea Conference
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• 1994.05a
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• pp.78-78
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• 1994

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 1998.05a
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• pp.73-73
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• 1998

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 1998.11a
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• pp.24-24
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• 1998

• Fibers and Polymers
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• v.7 no.4
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• pp.367-371
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• 2006

Thermal properties of copolyetherester/silica nanocomposites were examined by using DSC and TGA. The segmented block copolyetheresters with various hard segment structures and hard segment contents (HSC) were synthesized and their silica nanocomposite films were prepared by solution casting method. The nano-sized fumed silica particles were found to act as a nucleating agent of the copolyetheresters. The nanocomposites always showed reduced degree of supercooling or faster crystallization than the corresponding copolyetheresters. The nanocomposites also showed increased hard segment crystallinity except HSC 35 sample which had short hard segment length. In case of 2GT [poly(ethylene terephthalate)] copolyetheresters, which were not developed commercially because of their low crystallization rate, the hard segment crystallinity increased considerably. The copolyetherester/silica nanocomposites showed better thermal stability than copolyetheresters.

• Proceedings of the KIEE Conference
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• 1999.07d
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• pp.1792-1794
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• 1999

PVDF(Polyvinylidene Fluoride) thin films were prepared by using a physical vapor deposition system. Thin films were studied by X-ray diffraction (XRD), differential scanning calorimeter (DSC). The melting point$(T_m)$ of PVDF thin films increases with increasing substrate temperature. It is found that the degree of crystallinity of PVDF thin films increases from 49.8 to 67% with increasing substrate temperature from 30 to $80^{\circ}C$.

• Bulletin of the Korean Chemical Society
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• v.33 no.2
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• pp.449-452
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• 2012

A polyaniline-gold composite was prepared via the polymerization of aniline hydrochloride with or without water-soluble graphite oxide using auric acid as an oxidant. The reaction products were characterized using Xray photoelectron spectroscopy. The thermal stability and embedded crystallinity of the composites were also investigated using thermogravimetric and X-ray diffraction analyses. The electrical properties of the composites were examined using cyclic voltammetric measurements at room temperature and temperature-dependent DC conductivity within 300-500 K. Compared to pure graphene oxide and polyaniline-gold composite, the polyaniline-gold-graphene composite exhibited higher crystallinity and thermal stability, and higher current density response under equivalent conditions.