• Title/Summary/Keyword: crystalline

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1차원 InN 단결정 나노선의 구조특성에 대한 고찰 (Structural Characteristic of One Dimensional Single Crystalline of InN Nanowires)

  • 변윤기;정용근;이상훈;최성철
    • 한국세라믹학회지
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    • 제44권4호
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    • pp.202-207
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    • 2007
  • High-Quality 1-Dimensional InN single crystalline have been grown by Halide Vapor-Phase Epitaxy on the Au catalyst coated Si substrate using the vapor-liquid-solid growth mechanism. We have been grown 1-dimension InN nanowires having controlled the growth conditions for substrate temperature and gases flow rate. The grown InN nanowire of characteristics for morphologies, crystal structure, and element analysis were carried out by SEM, HR-TEM, and EDS respectively. And the defects of InN crystalline were analyzed by indexing of selective area diffraction pattern with attached HR-TEM. We have successfully obtained the defect-free 1-dimensional InN single crystalline nanowire at the atmosphere pressure.

삼상 실리콘 기판을 사용한 저가 전극 함몰형 태양전지 (Buried contact solar cells using tri-crystalline silicon wafer)

  • 권재홍;이수홍
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.1
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    • pp.176-180
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    • 2003
  • Tri-crystalline silicon (Tri-Si) wafers have three different orientations and three grain boundaries. In this paper, tri-Si wafers have been used for the fabrication of buried contact solar cells. The optical and micro-structural properties of these cells after texturing in KOH solution have been investigated and compared with those of cast multi-crystalline silicon (multi-Si) wafers. We employed a cost effective fabrication process and achieved buried contact solar cell (BCSC) energy conversion efficiencies up to 15% whereas the cast multi-Si wafer has efficiency around 14%.

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Neutral Beam assisted Chemical Vapor Deposition at Low Temperature for n-type Doped nano-crystalline silicon Thin Film

  • 장진녕;이동혁;소현욱;유석재;이봉주;홍문표
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.52-52
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    • 2011
  • A novel deposition process for n-type nanocrystalline silicon (n-type nc-Si) thin films at room temperature has been developed by adopting the neutral beam assisted chemical vapor deposition (NBa-CVD). During formation of n-type nc-Si thin film by the NBa-CVD process with silicon reflector electrode at room temperature, the energetic particles could induce enhance doping efficiency and crystalline phase in polymorphous-Si thin films without additional heating on substrate; The dark conductivity and substrate temperature of P-doped polymorphous~nano crystalline silicon thin films increased with increasing the reflector bias. The NB energy heating substrate(but lower than $80^{\circ}C$ and increase doping efficiency. This low temperature processed doped nano-crystalline can address key problem in applications from flexible display backplane thin film transistor to flexible solar cell.

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Effect of Silica Content on the Dielectric Properties of Epoxy/Crystalline Silica Composites

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • 제13권6호
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    • pp.322-325
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    • 2012
  • Crystalline silica was synthesized by annealing amorphous silica at $1,300^{\circ}C$ or $1,400^{\circ}C$ for various times, and the crystallinity was estimated by X-ray diffraction (XRD) analysis. In order to prepare a low dielectric material, epoxy/crystalline silica composites were prepared, and the effect of silica content on the dielectric properties was studied under various functions of frequency and ambient temperature. The dielectric constant decreased with increasing crystalline silica content in the epoxy composites, and it also decreased with increasing frequency. At 120 Hz, the value of 5 wt% silica decreased by 0.25 compared to that of 40 wt% silica, and at 23 kHz, the value of 5 wt% silica decreased by 0.23 compared to that of 40 wt% silica. The value increased with increasing ambient temperature.

Solvent-Assisted Soft-Lithographic Patterning of Lyotropic Liquid Crystalline Polymer Film by Flow Control through Patterned Channels

  • Park, Chang-Sub;Park, Kyung-Woo;Kang, Shin-Won;Kwak, Gi-Seop;Kim, Hak-Rin
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.641-644
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    • 2009
  • We demonstrated a solvent-assisted soft-lithographic patterning method for producing patterned structure and patterned ordering with lyotropic liquid crystalline polymer (LCP) film. Experimental results showed that the liquid crystalline ordering of lyotropic film could be controlled by shearing effects of the fluidic solvent though the patterned mold channels. In this work, two types of lyotropic LCPs were used to investigate the effects of the alkyl chain length of the lyotropic LCP on producing liquid crystalline ordering through the solvent-assisted fluidic patterning.

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벌크 마이크로 머쉬닝에 의한 다결정 실리콘 압력센서 제작 관한 연구 (A Study on Fabrication of Piezorresistive Pressure Sensor)

  • 임재홍;박용욱;윤석진;정형진;윤영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.677-680
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    • 1999
  • Rapid developing automation technology enhances the need of sensors. Among many materials, silicon has the advantages of electrical and mechanical property, Single-crystalline silicon has different piezoresistivity on 야fferent directions and a current leakage at elevated temperature, but poly-crystalline silicon has the possibility of controling resistivity using dopping ions, and operation at high temperature, which is grown on insulating layers. Each wafer has slightly different thicknesses that make difficult to obtain the precisely same thickness of a diaphragm. This paper deals with the fabrication process to make poly-crystalline silicon based pressure sensors which includes diaphragm thickness and wet-etching techniques for each layer. Diaphragms of the same thickness can be fabricated consisting of deposited layers by silicon bulk etching. HF etches silicon nitride, HNO$_3$+HF does poly -crystalline silicon at room temperature very fast. Whereas ethylenediamice based etchant is used to etch silicon at 11$0^{\circ}C$ slowly.

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Syntheses of Novel Liquid Crystalline Compounds with Partially Fluorinated Side Chains

  • 엄용섭;김용배;김성훈
    • Bulletin of the Korean Chemical Society
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    • 제21권4호
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    • pp.441-445
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    • 2000
  • A new series of three ring type liquid crystalline compounds containing partially fluorinated alkenyl or alkyl side chains together with fluorine substituted cyclohexylbiphenyls were designed and synthesized in this study. The structures of synthe sized compounds were established by 1 H, 13 C and 19 F NMR spectroscopy. The phase transition temperatures of fluorinated liquid crystalline compounds were determined by cross-polarizing mi-croscopy equipped withhot stage. All compounds were found to have nematic liquid crystalline phase with rel-atively low phase transition temperature and wide liquid crystalline temperature range. The dependence of phase transition temperatures on the chainlength falls into three categories; (a) decreasing transition tempera-tures for 4-fluoro-4'-[4-fluoro-4-(1-fluoroalkyl)cyclohexyl]biphenyl (15) series, (b) higher transition tempera-tures for odd numbered chains for 4-fluoro-4'-[4-fluoro-4-(1-fluoroalk-1-enyl)cyclohexyl]biphenyl (14) series, (c) higher transition temperatures for even numbered chains for 4-[4-(1,2-difluoroalk-1-enyl)-4-fluorocyclo-hexyl]-4'-fluorobiphenyl (16) series.

열경화성 액정 에폭시 수지의 액정상 변화를 포함한 시간-온도-전이 다이어그램 (Time-Temperature-Transition Diagrams with Liquid Crystalline Phase Changes of Liquid Crystalline Epoxy)

  • 조승현
    • Composites Research
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    • 제37권3호
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    • pp.215-218
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    • 2024
  • Diglycidyl ether of 4,4'-dihydroxy-α-methylstilbene (DGE-DHMS)에 aniline을 2:1의 비율로 첨가한 액정에폭시올리고머인 DD-A를 합성하고 촉매성 경화제인 1-Methyl Imidazole을 이용하여 경화시키며 겔화 및 유리화 시간을 측정하여 액정 변화가 포함된 Time-Temperature-Transition Diagram을 작성하였다. 경화제의 농도가 높아질수록 겔화 및 유리화 시간이 감소함을 확인할 수 있었고 유리화 곡선은 전형적인 S-형태를 보였다.

Lyotropic Mesomorphisms of a Lamellar Liquid Crystalline Phase in Non-hydrous Condition: A Phospholipid Hydrated by Different Polar Solvents

  • Lee, Dong-Kyu;Jeong, Kwan-Young
    • Bulletin of the Korean Chemical Society
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    • 제31권5호
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    • pp.1165-1171
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    • 2010
  • The lyotropic mesomorphism of lamellar liquid crystalline phase was examined by observing the swelling behavior of Distearoylphosphatidylcholine(DSPC) in glycerin and panthenol without water. The lyotropic mesomorphism was examined by using DSC, XRDs and Cryo-SEM. Increase of two polar solvents under non-hydrous condition showed distinctive differences in the lyotropic mesomorphism from forming different anisotropic structures with DSPC. Glycerin did not affect to the crystalline region of lamellar phase, whereas typical swelling mesomorphism was shown in the noncrystalline region. In contrast, panthenol showed some effect on the crystalline region, but common swelling mesomorphism was found in the non-crystalline region. In this case, the isopropyl and propyl groups in panthenol were the main factor to affect to the lipophilic domain in the crystalline region of lamellar phase. Also, it was found that the formation of well-arranged lamellar structure only by introducing glycerin and panthenol as a solvent without water, was possible. These results were confirmed by examination of the swelling mesomorphism of liquid crystal membrane triggered by introducing the two polar solvents.

Multi-crystalline Silicon Solar Cell with Reactive Ion Etching Texturization

  • Park, Seok Gi;Kang, Min Gu;Lee, Jeong In;Song, Hee-eun;Chang, Hyo Sik
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.419-419
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    • 2016
  • High efficiency silicon solar cell requires the textured front surface to reduce reflectance and to improve the light trapping. In case of mono-crystalline silicon solar cell, wet etching with alkaline solution is widespread. However, the alkali texturing methods are ineffective in case of multi-crystalline silicon wafer due to grain boundary of random crystallographic orientation. The acid texturing method is generally used in multi-crystalline silicon wafer to reduce the surface reflectance. However the acid textured solar cell gives low short-circuit current due to high reflectivity while it improves the open-circuit voltage. To reduce the reflectivity of multi-crystalline silicon wafer, double texturing method with combination of acid and reactive ion etching is an attractive technical solution. In this paper, we have studied to optimize RIE experimental condition with change of RF power (100W, 150W, 200W, 250W, 300W). During experiment, the gas ratio of SF6 and O2 was fixed as 30:10.

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