• 제목/요약/키워드: crystal impedance

검색결과 104건 처리시간 0.023초

Analysis of Coplaner $LiNBO_3$ Waveguide Structures Applicable Electrooptic Modulator with FDTD method

  • Lee, Byung-Je;Byun, Joon-Ho;Kim, Nam-Young;Kim, Jong-Heon;Lee, Jong-Chul
    • 한국전자파학회논문지
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    • 제11권7호
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    • pp.1211-1217
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    • 2000
  • The three-dimensional finite-difference time-domain (FDTD) method and the two-dimensional quasi-static formulation have been used to calculate the characteristic impedance and the microwave effective index of coplanar waveguide structures on Lithium Niobate ($LiNBO_3$) single crystal substrates with a yttria-stabilized zirconia (YSZ) or $SiO_2$ buffer layer. The results shown can be a good source to predict the modulator characteristics. The effects of the thin buffer layer and anisotropy of the $LiNBO_3$ crystal (x-cut and z-cut) are discussed. The comparison between the FDTD and quasi-static results shows good agreement. In this paper, the efficient modeling technique of the FDTD method for the coplanar waveguide (CPW) structures based on an anisotropic substrate with a thin buffer layer is developed.

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Q.C.M.을 이용한 메로시아닌 색소 LB막의 광학적 특성 분석 (Analysis of Optical Properties of Merocyanine Dye LB Films by Using Q.C.M.)

  • 강기호;김정명;신훈규;장정수;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 춘계학술대회 논문집 전자세라믹스 센서 및 박막재료 반도체재료 일렉트렛트 및 응용기술
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    • pp.130-133
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    • 2000
  • The optical characteristics of merocyanine dyes have been investigated widely due to their possible application to the high efficiency photo-electric devices. The optical systems are mostly fabricated using vacuum evaporation. casting and Langmuir-Blodgett method and the arrangement and orientation of dye molecules is one of the most important factors in the study on the optical characteristics. In this study. we fabricated the molecular systems through the LB techniques and investigated the optical characteristics of merocyanine dye LB film using the oscillation characteristics of quartz crystal. It was quite interesting behavior that the resistance and frequency shift at the parallel resonance under the UV irradiation.

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Electrocatalytic properties of Te incorporated Ni(OH)2 microcrystals grown on Ni foam

  • Lee, Jung-Il;Oh, Seong Gyun;Kim, Yun Jeong;Park, Seong Ju;Sin, Gyoung Seon;Kim, Ji Hyeon;Ryu, Jeong Ho
    • 한국결정성장학회지
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    • 제31권2호
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    • pp.96-101
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    • 2021
  • Developing effective and earth-abundant electrocatalyst for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is critical for the commercialization of a water splitting system. In particular, the overpotential of the OER is relatively higher than the HER, and thus, it is considered that one of the important methods to enhance the performance of the electrocatalyst is to reduce the overpotential of the OER. We report effects of incorporation of metalloid into Ni(OH)2 microcrystal on electrocatalytic activities. In this study, Te incorporated Ni(OH)2 (��Te-Ni(OH)2) were grown on three-dimensional porous NF by a facile solvothermal method with �� = 1, 3 and 5. Homogeneous microplate structure on the NF was clearly observed for the Ni(OH)2/NF and ��Te-Ni(OH)2/NF samples. However, irregular and collapsed nanostructures were found on the surface of nickel foam when Te precursor ratio is (��) over 3. Electrocatalytic OER properties were analysed by Linear sweep voltammetry (LSV) and Electrochemical impedance spectroscopy (EIS). The amount of Te incorporation used in the electrocatalytic reaction was found to play a crucial role in improving catalytic activity. The optimum Te amount (��) introduced into the Ni(OH)2/NF was discussed with respect to their OER performance.

Recent Advances in Electrochemical Studies of π-Conjugated Polymers

  • Park, Su-Moon;Lee, Hyo-Joong
    • Bulletin of the Korean Chemical Society
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    • 제26권5호
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    • pp.697-706
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    • 2005
  • We review the evolution of electrochemical studies of conducting polymers into the current state-of-the-art based primarily on our work. While conventional electrochemical experiments sufficed for the needs in the phase of studies of both electrochemical synthesis and characterization of conducting polymers, developments of various new experimental techniques have led to their introduction to this field for more refined information. As a result, the conventional electrochemical, spectroelectrochemical, electrochemical quartz crystal microbalance, impedance, and morphological as well as electrical characterization studies all made important contributions to a better understanding of the polymerization mechanisms and the conductive properties of these classes of polymers. From this review, we hereby expect that the electrochemical techniques will continue to play important roles in bringing this field to the practical applications such as nanoscale electronic devices.

Erbium 도핑된 p-GaSe 단결정의 홀 효과 특성 (Hall-effect properties of single crystal semiconductor P-GaSe dopes with $Er^{3+}$)

  • 이우선;오금곤;정용호;정창수;손경춘;김남오
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 추계학술대회 논문집 학회본부 C
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    • pp.726-728
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    • 1998
  • Optical and electrical properties of GaSe:$Er^{3+}$ single crystals grown by the Bridgeman technique was been investigated by using optical absorption and Hall-effect measurements. The Hall coefficients were measured by using a high impedance electrometer in the temperature range from 360K to 150K. The temperature dependence of hole concentration shows the characteristic of a partially compensated p-type semiconductor. carrier density($N_H$) of GaSe doped with Erbium was measured about $3.25{\times}10^{16}\;[cm^{-3}}$ at temperature 300K, which was high than undoped specimen. Photon energy gap ($E_{gd}$) was measured about 1.7geV.

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$Li_{3x}La_{(2/3-x)}TiO_3$계의 리튬 이온전도특성 (Lithium Ion Conductivity in $Li_{3x}La_{(2/3-x)}TiO_3$ system)

  • 정훈택;정태석;김호기
    • 한국세라믹학회지
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    • 제33권3호
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    • pp.293-298
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    • 1996
  • Room temperature Li+ ion conductivities of Li3xLa(2/3-x)TiO3 system with x=0.117~0.317 were measured by complex impedance method. ICP, SEM and XRD analysis were conducted to study the main factor which influence the Li+ ion conductivity. Li+ ion conductivity seems to have a close relationship with the crystal structure of primitive cell increase as the primitive cell as close to cubic.

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Erbium 도핑된 p-GaSe 단결성의 홀 효과 특성 (Hall-effect Properties of Single Crystal Semiconductor p-GaSe Dopes with $Er^{3+}$)

  • 이우선;김남오;손경춘
    • 한국전기전자재료학회논문지
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    • 제13권1호
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    • pp.1-5
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    • 2000
  • Optical and electrical properties of GaSe:Er\ulcorner single crystals grown by the Bridgenman technique have been investigated by using optical absorption and h\Hall-effect measurement system. The Hall coefficients were mea-sured by using a high impedance electrometer in the temperature range from 360K to 150K. The temperature dependence of hole concentration show the characteristic of a partially compensated p-type semiconductor. Carrier density(N\ulcorner) of GaSe doped with Erbium was measured about 3.25$\times$10\ulcorner [cm\ulcorner] at temperature 300K, which was higher than undoped specimen. Photon energy gap (E\ulcorner) of GaSe:Er\ulcorner specimen was measured about 1.79eV.

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Effect of Microstructure on Corrosion Behavior of TiN Hard Coatings Produced by Two Grid-Attached Magnetron Sputtering

  • Kim, Jung Gu;Hwang, Woon Suk
    • Corrosion Science and Technology
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    • 제5권1호
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    • pp.15-22
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    • 2006
  • The introduction of two-grid inside a conventional process system produces a reactive coating deposition and increases metal ion ratio in the plasma, resulting in denser and smoother films. The corrosion behaviors of TiN coatings were investigated by electrochemical methods, such as potentiodynamic polarization test and electrochemical impedance spectroscopy (EIS) in deaerated 3.5% NaCl solution. Electrochemical tests were used to evaluate the effect of microstructure on the corrosion behavior of TiN coatings exposed to a corrosive environment. The crystal structure of the coatings was examined by X-ray diffractometry (XRD) and the microstructure of the coatings was investigated by scanning electron microscopy (SEM) and transmission electron spectroscopy (TEM). In the potentiodynamic polarization test and EIS measurement, the corrosion current density of TiN deposited by two grid-attached magnetron sputtering was lower than TiN deposited by conventional magnetron type and also presented higher Rct values during 240 h immersion time. It is attributed to the formation of a dense microstructure, which promotes the compactness of coatings and yields lower porosity.

Electrochemistry of Conductive Polymers 46. Polymer Films as Overcharge Inhibitors for Lithium-Ion Rechargeable Batteries

  • Choi, Shin-Jung;Park, Su-Moon
    • Journal of Electrochemical Science and Technology
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    • 제1권1호
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    • pp.1-9
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    • 2010
  • Conducting polymer films grown from various aromatic compounds have been evaluated as overcharge protecting additives for lithium ion rechargeable batteries. The polymer films were grown electrochemically under the conditions similar to those encountered during the overcharging processes of lithium batteries and subsequently characterized by potentiodynamic, electrochemical quartz crystal microbalance, electrochemical impedance spectroscopic, and scanning electron microscopic experiments. Results indicate that bicyclic and polycyclic aromatic hydrocarbons would be poor candidates for inhibitors, while biphenyl, terphenyl, and benzene derivatives displayed excellent performances. Mixed polymer films grown from o-terphenyl and p-xylene show the best performance among the candidates.

탄성표면파 듀플렉서용 마이크로 스트립라인 집중소자 해석 및 실험 (Analysis and Experiment of Micro-strip Line Lumped Elements for SAW Duplexers)

  • 이승희;노용래
    • 한국전기전자재료학회논문지
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    • 제15권1호
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    • pp.85-92
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    • 2002
  • In this study, we analyzed and experimented micro-strip line inductors and capacitors for a SAW duplexer, an important devise for mobile communication. For SAW duplexers, micro-strip line lumped elements must have small impedance values, below several tens of nH or several tens of pF, and a small area pattern. In this study, we performed theoretical analysis of flat line type, meander line type, and spiral line type inductors and interdigital capacitors on a LiTaO$_3$ Piezo-crystal. We proposed a measurement method to evaluate small values of lumped elements accurately with network analyzer. In experiments, we confirmed validity of the theoretical analysis method through fabrication and characterization of micro-strip line lumped elements. The analysis method in this paper can be applied to SAW duplexers well as other microwave devices.