• Resources Recycling
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• v.29 no.4
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• pp.58-66
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• 2020

Carbonation (step I) and cryo-crystallization (crystallization at low temperature) (step II) were performed to synthesize Na compounds from sodium concentrated solution. In the step 1, the solubility and pH of carbon dioxide (95 wt.%) affecting carbonation could be changed by the variation of reaction temperature. The step II was performed at 2 ℃ after carbonation. The injection of carbon dioxide was carried out twice for the stable production and the saturated solubility of carbonate ions in solution. Firstly, we tried to inject CO₂ for controlling the solubility of CO₂ by changing the reaction temperature from 35 ℃ to 10 ℃, and the second injection was aimed at 10 ℃ for inducing nucleation of Na compound through carbonation after NaCl solution addition. In the cryo-crystallization step, the crystal growth of Na compounds could be induced by slowing the carbonation rate through reaction temperature change from 10 ℃ to 2 ℃. In this study, the effect on NaOH concentration was examined and the purity of Na compound was increased when 2M NaOH was used. In addition, the synthesized Na compounds were mostly rod-shaped and consisted of sodium carbonate or sodium carbonate with monohydrate.

• Radiation Oncology Journal
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• v.12 no.1
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• pp.27-31
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• 1994

There are a number of reports suggesting that there may be a correlation between the clinical response to radiotherapy in various tumors and the clonogenic survival of cell lines derived from these tumors following exposure to 2 Gy(SF2). Authors conducted this study to determine SF2 for cells in primary culture from surgical specimens. The tumor tissues with squamous cell carcinoma of uterine cervix and head and neck were obtained. The tumor tissues were disaggregated to single cells by incubating with collagenase type w for 2 hours with constant stirring. Single cell suspensions were inoculated in four 24-well plates precoated with cell adhesive matrix. After 24 hours of incubation at 37$ ^{\circ}C $, rows of four wells were then irradiated, consisting of control set and five other sets each receiving doses of 1,2,3,4, and 6 Gy. After incubation for a total of 13 days, the cultures were stained with crystal violet and survival at each dose was determined by quantitative image analysis system, To determine whether cell growth was of epithelial origin, immunocytochemical staining with a mixture of cytokeratin and epithelial monoclonal antibodies were performed on cell cultures. During the period of this study, we received 5 squamous cell carcinoma specimens of head and neck and 20 of uterine cervical carcinoma. Of these, 15 yielded enough cells for radiosensitivity testing. This resulted an overall success rate of 60$ \% $. The mean SF2 value for 15 tumours was 0.55$\pm$0.17 ranging from 0.20 to 0.79. These results indicate that there is a broad range of sensitivities to radiation in same histologic type. So with a large patient population, we plan to determine whether a different SF2 value is associated with tumours that are controlled with radiotherapy than those that are not.

• The Journal of the Petrological Society of Korea
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• v.6 no.3
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• pp.185-209
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• 1997

Granitic rocks in the Cheongsan area cosist of three plutons-Baegrog granodiorite, Cheongsan porphyritic granite, and two mica granite. Amphilboles from the Baegrog granodiorite belong to the calcic amphilbole group and show compositional variations from magnesio-hornblende in the core to actinolitic hornblende in the rim. Biotites from the three granites represent intermediate compositions between phlogopite and annite. Muscovites from the two mica granite are considered to be primary muscovite in terms of the occurrence and mineral chemistry. Each granitic rock reveals systematic variation of major oxide contents with $SiO_2$. Major oxide variation trends of the Baegrog granodiorite are fairly different from those of Cheongsan porphyritic granite and two mica granite. The latter two granitic rocks are also different with each other in variation trends for some oxides. Thus three granitic rocks in the Cheongsan area were solidifield from the independent magmas of chemically different, heterogeneous origin. The granitic rocks in the area show calc-alkaline nature. The whole rock geochemistry shows that the Baegrog granodiorite and Cheongsan porphyritic granite belong to metaluminous, I-type granite, whereas the two mica granite to peraluminous, I/S-type granite. The opaque mineral contents and magnetic susceptibility represent that the granitic rocks in the area are ilmenite-series granite, indicating that each magma was solidified under relatively reducing environment. The tectonic environment of the granitic activity in the area seems to have been active continental margin. Alkali feldspar megacryst in the Cheongsan porphyritic granite is considered to be magmatic, judging from the crystal size, shape, arrangement, and distribution pattern of inclusions. The petro-graphical characteristics of the Cheongsan porphyritic granite can be explained by two stage crystallization. Under the smaller degree of undercooling the alkali feldspar megacrysts rapidly grew owing to slow rate of nucleation and fast growth rate. At the larger degree of undercooling the nucleation rate and density drastically increased and the small crystals of the matrix were formed.