• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.6
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• pp.622-632
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• 2004

We have studied how liquid crystal's rubbing direction and voltage driving method affect generation of disclination line. At first, generation of disclination line in vertical alignment(VA) cell and VA-twisted nematic(TN) cell has been examined. When liquid crystal's rubbing direction of bottom substrate was 0$^{\circ}$, the degree of generated disclination line was the smallest value. Further, the generation of disclination line above the electrode is less in the frame inversion than in the line inversion. Secondly, we have examined a generation of disclination line in reflective fringe-field switching cell. When the distance between common electrodes is over 3 ${\mu}{\textrm}{m}$ with on-state of one pixel and off-state of neighboring pixels, the reflectance appears only on-state pixel without generating reflectance in adjacent pixels.

• Prospectives of Industrial Chemistry
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• v.24 no.6
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• pp.19-31
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• 2021

자극응답성 액정 엘라스토머(liquid crystal elastomer)는 하이드로겔(hydrogel), 형상 기억 고분자(shape memory polymer)와 더불어 생체 특성을 모방한 인공 근육, 소프트 액추에이터 및 소프트 로봇을 위한 스마트 소재로 최근 높은 관심을 받고 있다. 특히, 액정 엘라스토머는 고무 탄성과 액정 이방성이 결합된 비등방성 탄성 고분자로, 열, 빛, 전기 및 수분과 같은 외부자극에 반응하여 가역적이며, 액정 분자들의 배향조절을 통한 프로그램된 변형이 가능하다. 액정 엘라스토머가 개념 증명을 하는 수준을 넘어 실제로 유용한 소프트 액추에이터 및 로봇 시스템에 적용되기 위해서는 우수한 구동력 및 작업 용량, 높은 구동 변형률, 빠른 응답 시간, 낮은 구동 온도, 다양한 외부 자극반응성 및 높은 에너지 전환 효율 등을 확보하는 것이 중요하다. 본 기고문에서는 액정 엘라스토머의 개념에 대해 소개하고, 이러한 소재가 소프트 액추에이터로써 광범위하게 활용될 수 있도록 다양한 성능들을 향상시킬 수 있는 방법에 대해 소개하고자 한다.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.29 no.3
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• pp.310-321
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• 2019

Objectives: The purpose of this study was to investigate types and characteristics of chemical substances used in LCD(Liquid crystal display) panel manufacturing process. Methods: The LCD panel manufacturing process is divided into the fabrication(fab) process and module process. The use of chemical substances by process was investigated at four fab processes and two module processes at two domestic TFT-LCD(Thin film transistor-Liquid crystal display) panel manufacturing sites. Results: LCD panels are manufactured through various unit processes such as sputtering, chemical vapor deposition(CVD), etching, and photolithography, and a range of chemicals are used in each process. Metal target materials including copper, aluminum, and indium tin oxide are used in the sputtering process, and gaseous materials such as phosphine, silane, and chlorine are used in CVD and dry etching processes. Inorganic acids such as hydrofluoric acid, nitric acid and sulfuric acid are used in wet etching process, and photoresist and developer are used in photolithography process. Chemical substances for the alignment of liquid crystal, such as polyimides, liquid crystals, and sealants are used in a liquid crystal process. Adhesives and hardeners for adhesion of driver IC and printed circuit board(PCB) to the LCD panel are used in the module process. Conclusions: LCD panels are produced through dozens of unit processes using various types of chemical substances in clean room facilities. Hazardous substances such as organic solvents, reactive gases, irritants, and toxic substances are used in the manufacturing processes, but periodic workplace monitoring applies only to certain chemical substances by law. Therefore, efforts should be made to minimize worker exposure to chemical substances used in LCD panel manufacturing process.

• Bulletin of the Korean Chemical Society
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• v.13 no.3
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• pp.268-274
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• 1992

An attempt to improve the second harmonic generation (SHG) efficiency of MAP (methyl (2,4-dinitrophenyl)aminopropanoate) by modifying the substituents on the amino group of MAP is described. Several MAP analogues have been prepared using optically active amino acids alanine, phenylalanine and serine, and their SHG efficiencies measured. None of the MAP analogues exhibited SHG efficiencies as high as that of MAP. X-ray crystal structures of three MAP analogues have been determined. In the crystal structures of two of them, which were the derivatives of phenylalanine, two crystallographically-independent molecules existing in the asymmetric unit are aligned almost antiparallel. These structures are consistent with the very low SHG efficiencies of these compounds. On the other hand, the crystal structure of a serine derivative reveals substantial alignment of the dinitroaniline chromophore along the polar axis. However, the angle of 86.2° between the molecular charge tranfer axis and the polar axis of the crystal is still far away from the optimum value of 54.74° for the phase-matchable SHG. The structure is consistent with the SHG efficiency of this compound which is much higher than those of the phenylalanine derivatives but still lower than that of MAP. This study demonstrates the importance of the orientation of molecules in the crystal lattice in determining secod-order nonlinear optical properties of crystalline materials.

• Transactions on Electrical and Electronic Materials
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• v.9 no.6
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• pp.243-246
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• 2008

We have studied the liquid crystal (LC) alignment, the pretilt angle generation, and the annealing behavior for a nematic liquid crystal (NLC) on the homogeneous polyimide (PI) surfaces by using the rubbing method and the ion beam (IB) method. An excellent LC alignment of the NLC on the PI surface with rubbing and IB irradiation were observed. The pretilt angle of NLC on the homogeneous PI surface for the rubbing method is decreased from $4.5^{\circ}$ to $3.5^{\circ}$ as rubbing time is increased, that of the for the IB irradiation method is decreased from $0.5^{\circ}$ to $0.1^{\circ}$ as the time of IB irradiation is increased. After the annealing, the pretilt angles of the rubbed PI surfaces increased up to $4^{\circ}$, these of the IB irradiated PI surfaces little increased. It is considered the side chain of the rubbed PI show the its abilities of the original capacities, while the side chain of the IB irradiated PI cannot show the its abilities of the original capacities due to the IB has already destroyed the side chain of the PI.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.11a
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• pp.186-186
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• 2009

Most liquid crystal display modes, including the twisted nematic (TN) $mode^1$, the in-plane switching (IPS) $mode^2$, the fringe field switching (FFS) $mode^3$, and the vertically aligned (VA) $mode^4$ are based on either a horizontal or a vertical alignment. However, for some applications, such as no-bias-bend (NBB) pi cell or bistable bend-splay display, an intermediate pretilt angle is essential$^5$. NBB pi cells have been a focus of interest because of their fast response time; however, the reliable control of the intermediate pretilt angle of liquid crystals that is required for the fabrication of NBB pi cells is challenging. The controllable pre-tilt angle of liquid crystals was investigated using a blend of horizontal and vertical polyimide prepared by a rubbing method. Various pretilt angles in the range from 0^{\circ}$ to 90^{\circ}$ were achieved as a function of the vertical polyimide content. We observed uniform liquid crystal alignment on the rubbing-treated blended polyimide layer. A NBB pi cell with an intermediate pretilt angle of 47.8^{\circ}$ was manufactured. This cell had no initial bias voltage and a low threshold voltage, which indicates that it has low power consumption. In addition, the response time of the NBB pi cell was rapid.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.11a
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• pp.124-127
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• 2002

LC aligning capabilities and the variation of pretilt angles with ion beam irradiation on the a-C:H thin films, and electro-optical (EO) performances of the ion beam aligned twisted nematic (TN)-liquid crystal display (LCD) with oblique ion beam exposure on the a-C:H thin film were studied. A high pretilt angle of $3.5{^{\circ}}$ via ion beam irradiation on the a-C:H thin film was measured. Also, the LC pretilt angle decreased due to the increase in surface roughness at over 2 min of IB exposure time. It is considered that this roughness increase due to increasing IB exposure time that generated destroy of oriented rings of atoms related to LC alignment. An excellent voltage-transmittance (V-T) curve of the ion beam aligned TN-LCD was observed with oblique ion beam exposure on the a-C:H thin film for 1 min. Also, a faster response time for the ion beam aligned TN-LCD with oblique ion beam exposure on the a-C:H thin film for 1 min can be achieved. Finally, the residual DC property of the ion beam aligned TN-LCD with ion beam exposure of 1 min on the a-C:H thin film is almost same as that of the rubbing aligned TN-LCD on a PI surface.

• Polymer(Korea)
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• v.30 no.2
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• pp.97-107
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• 2006

In spite of excellent thermomechanical performance the majority of aromatic polyimides are so poor in processability due to their high backbone rigidity that their applications are greatly limited. The introduction of long side chains not only enhances their processiblity but also makes useful contribution to discovering new application fields. In this article, a variety of novel aromatic polyimides with flexible side chains were prepared either from new dimines or new dianhydrides to measure the influence of the side chains on structure and properties of the polymers and their new applications as liquid crystal alignment layers, photosensitive polymers, alternating multilayer nano-films and photoluminescent materials are discussed.

• Proceedings of the KIEE Conference
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• 1999.07d
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• pp.1765-1767
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• 1999

We synthesised a photo-alignment material of PM4Ch (poly(4-methacryloylloxychalcone)). The electro-optical (EO) characteristics of photo-aligned twisted nematic (TN)-liquid crystal display (LCD) with linearly polarized ultraviolet (UV) light irradiation on PM4Ch surface were investigated. The uniform alignment of NLC with polarized UV light irradiation on PM4Ch surface was measured. Also, We had The excellent voltage-transmittance characteristics of photo-aligned TN-LCD. The low threshold voltage of photo-aligned TN-LCD was measured. Moreover, the fast response time of photo-aligned TN-LCD on PM4Ch was successfully achieved. Finally The reduction DC voltage of photo-aligned TN-LCD decreases with increasing the UV light irradiation time on photo-dimerized PM4Ch surface.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.120.2-120.2
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• 2015

We propose a novel direct writing technique with a femtosecond laser enabling selective modification of not only the morphology of conducting polymer thin films but also the orientation and alignment of the polymer crystal. Surface relief gratings resulting from photoexpansion on P3HT:PCBM and PEDOT:PSS thin films were fabricated by femtosecond laser direct writing. The photoexpansion was induced at laser fluence below the ablation threshold of the thin film. The morphology (size and shape) of photoexpansion could be quantitatively controlled by laser writing parameters such as focused beam size, writing speed, and laser fluence. GIWAX results showed that face-on P3HT crystals were largely increased in the photoexpansion in comparison with pristine region of the thin film. In addition, the face-on P3HTs in the photoexpansion were aligned with their orientation along the polarization of the laser. The micro-RAMAN spectra confirmed that neither chemical composition change nor the polymer chain breaking was observable after femtosecond laser irradiation. We believe that this laser direct writing technique opens a new door to the fabrication of more efficient OPVs via non-contact, toxic-free approach.