Polymer(Korea) (폴리머)

The Polymer Society of Korea (한국고분자학회)
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Synthesis of Novel Aromatic Polyimides

새로운 방향족 폴리이미드의 합성

  • Shin Gyo-Jic (Polymer Research Institute/Center for Advanced Functional Polymers, Department of Materials Science & Engineering, Pohang University of Science & Technology(POSTECH)) ;
  • Chi Jun-Ho (Polymer Research Institute/Center for Advanced Functional Polymers, Department of Materials Science & Engineering, Pohang University of Science & Technology(POSTECH)) ;
  • Zin Wang-Cheol (Polymer Research Institute/Center for Advanced Functional Polymers, Department of Materials Science & Engineering, Pohang University of Science & Technology(POSTECH)) ;
  • Chang Tai-Hyun (Department of Chemistry, Pohang University of Science & Technology(POSTECH)) ;
  • Ree Moon-Hor (Department of Chemistry, Pohang University of Science & Technology(POSTECH)) ;
  • Jung Jin-Chul (Polymer Research Institute/Center for Advanced Functional Polymers, Department of Materials Science & Engineering, Pohang University of Science & Technology(POSTECH))
  • 신교직 (포항공과대학교 신소재공학과 고분자합성 연구실) ;
  • 지준호 (포항공과대학교 신소재공학과 고분자합성 연구실) ;
  • 진왕철 (포항공과대학교 신소재공학과 고분자합성 연구실) ;
  • 장태현 (포항공과대학교 화학과) ;
  • 이문호 (포항공과대학교 화학과) ;
  • 정진철 (포항공과대학교 신소재공학과 고분자합성 연구실)
  • Published : 2006.03.01
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Abstract

In spite of excellent thermomechanical performance the majority of aromatic polyimides are so poor in processability due to their high backbone rigidity that their applications are greatly limited. The introduction of long side chains not only enhances their processiblity but also makes useful contribution to discovering new application fields. In this article, a variety of novel aromatic polyimides with flexible side chains were prepared either from new dimines or new dianhydrides to measure the influence of the side chains on structure and properties of the polymers and their new applications as liquid crystal alignment layers, photosensitive polymers, alternating multilayer nano-films and photoluminescent materials are discussed.

방향족 강직사슬 폴리이미드는 높은 주사슬 간의 인력으로 인해 유기용제에 용해되지 않고 상전이온도가 분해 온도보다 높아 응용분야에 많은 제한이 되고 있다. 방향족 폴리이미드의 가공성을 향상시키기 위해서 긴 곁사슬을 도입하면 가공성 향상뿐만 아니라 곁사슬과 주사슬 사이에 독특한 구조를 가지게 됨으로써 새로운 응용분야를 개척할 수가 있다. 본 논문에서는 여러 가지 형태의 곁사슬을 가지는 방향족 폴리이미드의 합성과 화학구조에 따른 물성변화에 대해 논의하고 또한 폴리이미드의 액정배향막, 감광재료, 교대 다층박막, 발광재료 등으로의 응용특성에 관해서도 조감한다.

Keywords

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