• Title/Summary/Keyword: crystal alignment

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New Liquid Crystal Photoalignment Materials Based on Photosensitive Polyimides Having Long Alkoxy Cinnamate Chains

  • Wu, Jing-Jing;Jeong, Seok-Jin;Lee, Seung-Hee;Lee, Myong-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.893-896
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    • 2007
  • A series of new photosensitive polyimides having long alkoxy cinnamate chains were synthesized for liquid crystal (LC) photoalignment material. The polymer after irradiating linearly polarized UV light induced homogeneous and stable LC alignment. The chemical structure of the polymeric material was characterized and their photochemical LC alignment behavior was evaluated.

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Study of wide viewing angle and response time by using new VA-$\pi$ cell mode cell mode (새로운 VA-$\pi$ cell mode cell mode를 이용한 광시야각 및 응답속도에 관한 연구)

  • 이정호;김진호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.549-552
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    • 1999
  • We have developed an novel vertical-alignment (VA) - $\pi$ cell mode that provides a wide viewing angle and fast response times for negative dielectric anisotropy nematic liquid crystal (NLC) on a homeotropic polyimide (PI) surfaces. We had the good voltage-transmittance curves and low driving voltages were achieved with the novel VA - $\pi$ cell mode without negative compensation film. Iso-viewing angle characteristics using the novel VA - $\pi$ cell mode without negative compensation film of NLC was also successfully observed. As well a fast response time of 31.7ms for the novel VA - $\pi$ cell mode was measured. Consequently, It is seen that by using the novel VA - $\pi$ cell mode the iso-viewing angle, fast response time, and low driving voltage characteristics can be achieved.

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Improvement of viewing angle characteristics using a VA-1/6$\pi$ cell (VA-1/6$\pi$셀을 이용한 시야각 특성의 개선)

  • 황정연;서대식;한은주;김재형
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.515-518
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    • 2000
  • We studied the viewing angle characteristics of a negative dielectric anisotropy nematic liquid crystal (NLC) using the new vertical-alignment (VA)-1/6 cell on a rubbed polyimide (PI) surface. Good voltage-transmittance (V-T)characteristics using the new VA-1/6 cell without a negative compensation film were obtained. The iso-viewing angle characteristics using the new VA-1/6 cell without the negative compensation film can be achieved.

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Liquid crystal alignment by photo-dimerization reaction of PCEMA photo polymer (PCEMA 광폴리머의 광중합 작용을 이용한 액정배향)

  • 황정연;서대식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.541-544
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    • 1999
  • We synthesised a novel photo-alignment material of PCEMA (poly(cinnamolyethyl methacrylate)) on photo-dimerization reaction. Next we investigated the electro-optical (EO) characteristics of photo-aligned twisted nematic (TN)-liquid crystal display (LCD) with linearly polarized ultraviolet (UV) light irradiation on PCEHA surface. The excellent voltage-transmittance characteristics of photo-aligned TN-LCD on PCEMA surface were obtained. The threshold voltage of photo-aligned TN-LCD decreases with increasing the UV light irradiation time on PCEMA surface. Also, the response time of photo-aligned TN-LCD on PCEMA surface is almost the same as rubbing-aligned TN-LCD.

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Electro-optical characteristics of New Pixel structure in PVA mode. (PVA 모드에서의 새로운 화소구조의 전기광학 특성)

  • Jeon, Yeon-Mun;Kim, Youn-Sik;Kim, Sang-Gyun;Lyu, Jae-Jin;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.04a
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    • pp.43-44
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    • 2006
  • We have studied effect of Patterned Vertical Alignment (PVA) mode on electro-optical characteristics and stability of liquid crystal director upon electrode pattering. In the present studies, LC director field and stability of conventional PVA mode electrode patterns were analyzed and new type of electrode patterns were suggested. At last, comparison between this new type of electrode patterns to conventional electrode pattern types were followed.

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Effect of Liquid Crystal Alignment for Photo-Aligned VA-LCD on the Photo-Dimerized Polymer Surface

  • Hwang, Jeoung-Yeon;Seo, Dae-Shik
    • Journal of the Optical Society of Korea
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    • v.5 no.1
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    • pp.16-19
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    • 2001
  • A photopolymer, copoly (M4Ch-ChMA), copoly ((4-methacryloyloxy) chalcone-cholesteryl methacrylate), was synthesized in this study. The electro-optical (EO) characteristics for the photo-aligned vertical-alignment (VA)-liquid crystal display (LCD) were investigated. Excellent voltage-transmittance curves for the VA-LCD photo-aligned by polarized UV exposure on the copoly (M4Ch-ChMA) surface were observed. The response time for the photo-aligned VA-LCD decrease with increasing UV exposure time. consequently, the photo-dimerized chalcone moiety increased with increasing UV exposure time, which then contributed to a low response time for the VA-LCD photo-aligned.

Dimerization Behavior of Cinnamate Group attached to Flexible Polymer Backbone and Its Application to Liquid Crystal Alignment

  • Sung, Shi-Joon;Cho, Ki-Yun;Hah, Hyun-Dae;Kim, Won-Sun;Jeong, Yong-Cheol;Park, Jung-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1163-1166
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    • 2004
  • Cinnamate group is well-known for the dimerization reaction by ultra-violet irradiation and cinnamate polymers are studied for photo-alignment materials. The cinnamate groups of flexible polymer are found to produce LC alignment parallel to polarization direction of ultra-violet light, which is contrary to the LC orientation on conventional cinnamate polymers. The un-reacted cinnamate groups in the flexible polymer are also found to participate in cycloadducts formation by additional thermal reaction that preserves the orientation of cycloadducts, leading to the enhancement of thermal stability of LC alignment.

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Study of the Photo-alignment Technique through the Surface Modification

  • Song, Dong-Mee;Shin, Dong-Myung
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.197-198
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    • 2000
  • A surface-assisted photo-control of the liquid crystal (LC) alignment has been achieved by modifying the topmost surface of the polyimide film with photo-reactive molecules. Recently, photo-alignment technique using a thin film of poly(vinyl cinnamates) have been reported. However their commercial potentiality is limited by their low thermal stability. To enhance thermal stability, we synthesized the chalcone derivatives as the photo-reactive molecules and introduced the materials on the surface-modified polyimide film.. We identified that the photo-chemical reaction of the chalcone derivatives occur in few minutes with irradiation of UV light. The photo-alignment characteristics of the modified polyimide films treated by polarized UV light and their LC cells are investigated as a function of exposure dose.

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Electro-optical properties of photo-aligned VA-LCD by irradiation of unpolarized UV light. (비편광 UV조사에 의한 광배향 VA-LCD의 전기광학특성)

  • 박두석;서대식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.545-548
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    • 1999
  • The electro-optical characteristics of photo-aligned vertical-alignment (VA)-liquid crystal display (LCD) with non-polarized ultraviolet (UV) light irradiation of 45\`on homeotropic polyimide (Pl) surface were investigated. LC alignment on photo-aligned VA-LCD is attributed to photo-depolymerized reaction of the polymer with non-polarized UV light irradiation on PI surface. We had good voltage-transmittance (V-T) characteristics of photo-aligned VA-LCD. The response time of photo-aligned VA-LCD was slower than that of the rubbing-aligned VA-LCD. Finally, we suggest that the slow response time of photo-aligned VA-LCD depends on the LC domain.

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Electro-Optical Characteristics on the flexible substrate using the Rubbing method (플렉시블 기판에 러빙법을 이용한 전기광학특성)

  • Lee, Whee-Won;Choi, Sung-Ho;Hwang, Jeoung-Yeon;Kang, Hyung-Ku;Bae, Yu-Han;Moon, Hyun-Chan;Kim, Jong-Hwan;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.487-488
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    • 2005
  • We have investigated the Electro-Optical Characteristics for a nematic liquid crystal (NLC) alignment with rubbing alignment method on polyimide surfaces using plastic substrates. It was found that monodomain alignment of NLC is obtained with rubbing alignment method on polyimide surfaces using thin plastic substrates. EO characteristics of the TN-LCD with a rubbed PI surface based on polymer are almost the same as that of the TN-LCD with a rubbed PI surface based on glass. However, the transmittances of the TN-LCD with a rubbed PI surface based on polymer is less than that with a rubbed PI surface based on glass.

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