• 제목/요약/키워드: cross combination

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Redistribution/Dehydrocoupling of Tertiary Alkylstannane $n-Bu_3 SnH$ Catalyzed by Group 4 and 6 transition Metal Complexes

  • 우희권;송선정;김보혜
    • Bulletin of the Korean Chemical Society
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    • v.19 no.11
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    • pp.1161-1164
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    • 1998
  • The catalytic transformation of sterically bulky tertiary stannane n-Bu3SnH by the Cp2MCl2/Red-Al (M=Ti, Zr, Hf) and M(CO)6 (M=Cr, Mo, W) catalysts yielded two kinds of catenated products: one is a cross-linked polystannane as minor product, and the other is hexabutyldistannane (n-Bu3Sn)2 as major product. The distannane was produced by simple dehydrocoupling of n-Bu3SnH, whereas the cross-linked polystannane could be obtained via redistribution/dehydrocoupling combination process of n-Bu3SnH. The redistribution/dehydrocoupling combination process may initially produce a low-molecular-weight oligostannane with partial backbone Sn-H bonds which could then undergo an extensive cross-linking reaction of backbone Sn-H bonds, resulting in the formation of an insoluble polystannane.

Dynamic Scene Segmentation Algorithm Using a Cross Mask and Edge Information (Cross Mask와 에지 정보를 사용한 동영상 분할)

  • 강정숙;박래홍;이상욱
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.26 no.8
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    • pp.1247-1256
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    • 1989
  • In this paper, we propose the dynamic scene segmentation algorithm using a cross mask and edge information. This method, a combination of the conventioanl feature-based and pixel-based approaches, uses edges as features and determines moving pixels, with a cross mask centered on each edge pixel, by computing similarity measure between two consecutive image frames. With simple calcualtion the proposed method works well for image consisting of complex background or several moving objects. Also this method works satisfactorily in case of rotaitional motion.

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Encapsulation of Nanomaterials within Intermediary Layer Cross-linked Micelles Using a Photo-Cross-linking Agent

  • Kim, Jin-Sook;Youk, Ji-Ho
    • Macromolecular Research
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    • v.17 no.11
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    • pp.926-930
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    • 2009
  • A new method for encapsulating nanomaterials within intermediary layer cross-linked (ILCL) polymeric micelles using a bifunctional photo-cross-linking agent was developed. For ILCL polymeric micelles, an amphiphilic triblock copolymer of poly(ethylene glycol)-b-poly(2-hydroxyethyl methacrylate)-b-poly(methyl methacrylate) (PEG-PHEMA-PMMA) was synthesized via consecutive atom transfer radical polymerization (ATRP), Di(4-hydroxyl benzophenone) dodecanedioate (BPD) was used as a bifunctional photo-cross-linking agent. The PMMA-tethered Au nanoparticles and BPD, or pyrene and BPD were encapsulated in the PEG-PHEMA-PMMA micelles, and their intermediary layers were photo-cross-linked by UV irradiation for 1 h. The HEMA units donated labile hydrogens to the excited-state benzophenone groups in BPD, and they were subsequently cross-linked by BPD through radical-radical combination. The spherical structures of the PEG-PHEMA-PMMA micelles containing the Au nanoparticles or pyrene were unaffected by the photo-cross-linking process.

Dehydrocoupling of Bis(1-sila-3-butyl)benzene and 2-Phenyl-1,3-disilapropane to Polymers Using Zirconocene Combination Catalysts

  • Lee, Jun;Kim, Jong-Hyun;Mo, Soo-Yong;Woo, Hee-Gweon;Kim, Do-Heyoung;Jun, Jin
    • Journal of Integrative Natural Science
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    • v.4 no.3
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    • pp.177-181
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    • 2011
  • The catalytic dehydrocoupling of bis(1-sila-3-butyl)benzene 1 and 2-phenyl-1,3-disilapropane 2 by $Cp_2ZrCl_2$/Red-Al and $Cp_2ZrCl_2$/n-BuLi was reported to compare their catalytic efficiency. The dehydrocoupling of monomeric silanes 1 with the $Cp_2ZrCl_2$/Red-Al and $Cp_2ZrCl_2$/n-BuLi combination catalysts produced two phases of polymers: one is a highly cross-linked insoluble solid, and the other is noncross-linked or slightly cross-linked soluble oil and could be a precursor for the solid polymer. The dehydrocoupling of 2 with the $Cp_2ZrCl_2$/n-BuLi combination catalyst similarly produced two phases of polymers. By contrast, the catalytic reaction of 2 with the $Cp_2ZrCl_2$/Red-Al combination catalyst produced a soluble polymer via redistribution/dehydrocoupling process.

The Characteristics of Fatigue Cracks Emanating from Small Hole Defects Located Opposite Position of the Shaft Cross Section (축단면 내 대칭위치에 존재하는 원공결함에서 발생하는 피로균열 거동)

  • Song, Sam-Hong;An, Il-Hyeok;Lee, Jeong-Mu
    • Journal of the Korean Society for Precision Engineering
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    • v.19 no.10
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    • pp.84-91
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    • 2002
  • The shaft with the circular cross section have symmetric structural combination parts to keep the rotating balance. Hence the crack usually emanate from symmetric combination parts due to the stress concentration of these parts. In this study to estimate the fatigue behavior of symmetric cracks, the fatigue test was performed by using rotary bending tester and the specimen with symmetric defects in circular cross section. From the facts the characteristics of crack initiation and propagation on the symmetric surface cracks in circular cross section was examined. Also we observed the internal crack using oxidation coloring and investigated the fatigue behavior using the relationship between surface crack and internal crack. As a result of fatigue lift of symmetric cracks was reduced to 35% compared to single crack’s. We examined the characteristics of fatigue behavior in element with symmetric cracks using internal crack propagation rate and maximum stress intensity factor range obtained from approximation method.

Behavioral Characteristics of Fatigue Cracks in Small Hole Defects Located on Opposite Sides of the Shaft Cross Section

  • Sam-Hong;Il-Hyuk;Jeong-Moo
    • International Journal of Precision Engineering and Manufacturing
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    • v.5 no.4
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    • pp.36-42
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    • 2004
  • The shaft with the circular cross section has symmetric structural combination parts to keep the rotating balance. Hence the crack usually initiates from symmetric combination parts due to the stress concentration of these parts. In this study to estimate the fatigue behavior of symmetric cracks, the fatigue test was performed by using a rotary bending tester and the specimen with symmetric defects in circular cross section. The characteristics of crack initiation and propagation on the symmetric surface cracks in circular cross section were examined. We also observed the internal crack using the oxidation coloring method and investigated the fatigue behavior using the relationship between the surface crack and the internal crack. As a result, the fatigue life of symmetric cracks was reduced by 35% compared to that of a single crack. We examined the characteristics of fatigue behavior of elements with symmetric cracks using internal crack propagation rate and maximum stress intensity factor range that were obtained from an approximation method.

Clinical Study on East-West Combination Treatment in Joint Disorders (관절.류마티스 질환의 한.양방 협진에 관한 임상적 고찰)

  • Shin, Ye-Jji;Kim, Chan-Young;Kwon, Na-Hyoun;Kwon, Sin-Ae;Lee, Jung-Woo;Koh, Hyung-Kyun;Woo, Hyun-Su;Park, Dong-Suk;Baek, Yong-Hyeon
    • Journal of Acupuncture Research
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    • v.26 no.6
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    • pp.121-132
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    • 2009
  • Objectives : To evaluate the current status of East-West combination treatment in joint disorders. Methods : The medical records of patients who visited the Joints & Rheumatism Center at the Kyung Hee East-West Neo Medical Center from April 2006 to June 2009 were evaluated. The general characteristics of patients who underwent combination treatment, trend in number of cross-system referrals, and disorders and involved body regions of patients referred to the Eastern medical hospital from the Western medical hospital were initially assessed. 6 major disorders were found from the initial scanning. The trend in number of cross-hospital referrals, number of visits to the Eastern medical hospital, current status of combination treatment, treatment modality, and reason for cross-system referral was evaluated. Results : 1. 1510 patients were referred from the Eastern medical hospital to the Western medical hospital, and 1065 patients were referred from the Western medical hospital to the Eastern medical hospital. First visit patients reached a peak at the second quarter of 2007 and fourth quarter of 2006 respectively, and have steadily decreased from then on. Referrals of female patients were twice as common as male patient referrals. Patients in their sixth or seventh decade of life were most commonly referred, and more outpatients were referred compared to inpatients. 2. Patients with knee joint disorders were most commonly referred from the Western medical hospital to the Eastern medical hospital, followed by hip, shoulder, ankle, wrist, and elbow joint disorders. The most common disorders for each of the above regions in referred patients were knee osteoarthritis, avascular necrosis of the hip, adhesive capsulitis, and ankle strain and sprain. The generalized disorders rheumatoid arthritis and ankylosing spondylitis followed. 3. Patients referred to the Eastern hospital received approximately 3 to 10 Eastern medical treatment sessions. 45 percent remained on constant combination treatment, and 98 percent of referred patients received acupuncture treatment. Conclusions : In regard to the number of patients and duration of combination treatment, combination treatment was successfully performed for knee osteoarthritis, rheumatoid arthritis, and ankylosing spondylitis, while it was not so for avascular necrosis of the hip, adhesive capsulitis, and ankle strain and sprain. Further research on this subject is required.

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An Enhancement of Japanese Acoustic Model using Korean Speech Database (한국어 음성데이터를 이용한 일본어 음향모델 성능 개선)

  • Lee, Minkyu;Kim, Sanghun
    • The Journal of the Acoustical Society of Korea
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    • v.32 no.5
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    • pp.438-445
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    • 2013
  • In this paper, we propose an enhancement of Japanese acoustic model which is trained with Korean speech database by using several combination strategies. We describe the strategies for training more than two language combination, which are Cross-Language Transfer, Cross-Language Adaptation, and Data Pooling Approach. We simulated those strategies and found a proper method for our current Japanese database. Existing combination strategies are generally verified for under-resourced Language environments, but when the speech database is not fully under-resourced, those strategies have been confirmed inappropriate. We made tyied-list with only object-language on Data Pooling Approach training process. As the result, we found the ERR of the acoustic model to be 12.8 %.

Cross-flow Analogy and Euler Solutions for Missile Body Aerodynamics

  • Lee, Jae-Myung;Park, Seung-O;Kim, In-Sun
    • International Journal of Aeronautical and Space Sciences
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    • v.1 no.2
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    • pp.9-16
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    • 2000
  • For aerodynamic design of missile bodies of non-circular cross-section, the combination of the slender body theory and the cross-flow analogy can hardly be applied owing to the lack of experimental data. An alternative is to utilize the Euler solution in the design stage. For enhanced accuracy, however, an adequate viscous correction is necessary to the Euler solution. In this work, such a procedure is examined to compensate the viscous effect by utilizing the concept of proportionality factor in cross-flow analogy. Predictions of aerodynamic coefficients combining the Euler solution and the viscous correction via proportionality factor are made for a missile body of elliptic cross-section. Results indicate that the present approach can be adopted in designing missile bodies of non-circular cross-sections.

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