• 제목/요약/키워드: critical surface tension

검색결과 168건 처리시간 0.032초

Local dynamic buckling of FPSO steel catenary riser by coupled time-domain simulations

  • Eom, T.S.;Kim, M.H.;Bae, Y.H.;Cifuentes, C.
    • Ocean Systems Engineering
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    • 제4권3호
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    • pp.215-241
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    • 2014
  • Steel catenary riser (SCR) is a popular/economical solution for the oil/gas production in deep and ultra-deep water. The behavioral characteristics of SCR have a high correlation with the motion of floating production facility at its survival and operational environments. When large motions of surface floaters occur, such as FPSO in 100-yr storm case, they can cause unacceptable negative tension on SCR near TDZ (touch down zone) and the corresponding elastic deflection can be large due to local dynamic buckling. The generation, propagation, and decay of the elastic wave are also affected by SCR and seabed soil interaction effects. The temporary local dynamic buckling vanishes with the recovery of tension on SCR with the upheaval motion of surface floater. Unlike larger-scale, an-order-of-magnitude longer period global buckling driven by heat and pressure variations in subsea pipelines, the sub-critical local dynamic buckling of SCR is motion-driven and short cycled, which, however, can lead to permanent structural damage when the resulting stress is greatly amplified beyond the elastic limit. The phenomenon is extensively investigated in this paper by using the vessel-mooring-riser coupled dynamic analysis program. It is found that the moment of large downward heave motion at the farthest-horizontal-offset position is the most dangerous for the local dynamic buckling.

Wetting Properties of Biopolyester Films Prepared by Thermo-Compression Method

  • Rhim, Jong-Whan;Hong, Seok-In
    • Food Science and Biotechnology
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    • 제16권2호
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    • pp.234-237
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    • 2007
  • Water resistance of three biopolyester films, such as poly-L-lactate (PLA), poly-hydroxybutyrate-co-valerate (PHBV), and Ecoflex, and low density polyethylene (LDPE) film was investigated by measuring contact angle of various probe liquids on the films. The properties measured were initial contact angle of water, dynamic change of the water contact angle with time, and the critical surface energy of the films. Water contact angle of the biopolyester films ($57.62-68.76^{\circ}$) was lower than that of LDPE film ($85.19^{\circ}$) indicating biopolyester films are less hydrophobic. The result of dynamic change of water contact angle also showed that the biopolyester films are less water resistant than LDPE film, but much more water resistant than cellulose-based packaging materials. Apparent critical surface energy for the biopolyester films (35.15-38.55 mN/m) was higher than that of LDPE film (28.59 mN/m) indicating LDPE film is more hydrophobic.

Characterization of CNT-ink and fabrication of a cold cathode using jet-printing technique.

  • Lee, Dae-Sik;Lim, Seong-Chu;Lee, Young-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.1532-1534
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    • 2008
  • Aquesous carbon nanotubes (CNTs) solutions were prepared using SDS (sodium dodecyl sulfonate) and NADDBS (sodium dodecylbenzene sulfonate). Our inks are found to have the viscosity of 1-2 cps. In addition, the surface tension of inks inversely decreased with increasing surfactant concentration and then saturated at critical micelle concentration (CMC). The low surface tension at CMC gave rise to lower contact angles on Indium layers, resulting in larger printable feature sizes. In the fabrication of cold cathode, jet-printing is feasible to modify and scale up the cathode structures. These feasibilities could contribute jet-printing method to be more adaptable for making large-area cold cathodes.

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레이저를 이용한 균일 금속 액적 생성 (Uniform metal droplet generation using laser)

  • 강대현;양영수;김용욱;조성규;박성민
    • 한국레이저가공학회지
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    • 제5권1호
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    • pp.23-31
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    • 2002
  • The uniform metal droplet generation using Nd-YAG laser was studied and experiment was carried out. The shape and volume of developed droplet was measured and the Young-Laplace equation and equilibrium condition of force were applied this model. The differential equation predicting shape of droplet using equilibrium condition of force instead of Navier-stokes equation was induced and numerical solution of differential equation compared with experimentation data. The differential equation was solved by Runge-Kutta method. Surface tension coefficient of droplet was determined with numerical solution relate to experimental result under the statical condition. In case of dynamic vibration, metal droplet shape and detaching critical volume are predicted by recalculating proposed model. The result revealed that this model could reasonably describe the behavior of molten metal droplet on vibration.

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전파이론을 통한 $NH_3\;-H_2O$ 흡수과정의 마란고니 대류 안정성 해석 (Stability Analysis of Marangoni Convection for $NH_3\;-H_2O$ Absorption Process)

  • 최창균;김제익;강용태
    • 설비공학논문집
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    • 제14권6호
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    • pp.450-455
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    • 2002
  • Convective instability driven by surface tension is analyzed in an initially quiescent water absorbing ammonia gas using the linear stability theory. The propagation theory is adapated to find the critical conditions of the onset of solutal Maragoni convection. In this theory, the solutal penetration depth is chosen as the length scale factor. The results show that the liquid layer becomes more stable with decreasing the Schmidt number It is interesting that for a smaller Biot number than 100, the system becomes stable with decreasing Bi but for a larger Bi, it becomes unstable with decreasing Bi.

Silver-polyner 적합도전류물에서 은립자의 분석상태가 전기운도에 미치는 영향 (Effect of Dispersion of Silver Particles on the Electrical Conduction in Silver-Polymer Composites.)

  • 김한성;김재호
    • 대한전기학회논문지
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    • 제37권1호
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    • pp.55-62
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    • 1988
  • The variation of electrical resistivity of silver particle-filled polymers with the volume percent of silver particles was investigated. Also, the relationships between the surface tension of polymer and dispersion effect of silver particles were studied to find the steep drop of electrical resisivity, in view of agglomerate morphology. The critical volume precent of silver particles varied depending on the polymer species and increased with the increasing surface tension of polymer. The steep variation of resistivity with the increasing temperature was explained with the expansion of polymer at the melting temperature of polymer. The conductive break down current increased with the increasing volume percent of silver particles in the Ag/LDPE system and that was attributed to heat of Joule taken througn the contact area between the silver particle.

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양쪽성 이온 계면활성제의 유도체합성 및 계면성에 관한 연구(제2보);N-알킬 혹은 아실히드록시 술포베타인류의 계면성 (Synthesis and Surface Active Properties of Amphoteric Surfactant Derivatives(II);Surface Active Properties of N-Alkyl or Acyl Hydroxy sulfobetaines)

  • 이진희;하정욱;박홍조;노윤찬;남기대
    • 한국응용과학기술학회지
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    • 제11권1호
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    • pp.79-85
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    • 1994
  • All the activities and physical properties including surface tension' foaming power, foam stability, emulsifying power, dispersion effect of 3-(N, N-dimethyl N-alkylammonio)-2-hydroxyY-1-propane sulfonate (HSB)류와 3-CN-alkylamidopropyl-N,N-dimethylamm-onjo)-2-hydroxy-1-propane sulfonate (APSB) aquous solution were measured and critical micelle concentration was evaluated. Their cmc of hydroxy sulfobetaine derivatives evaluated by the surface tension method was $1.0{\times}10^{-3}{\sim}1.0{\times}10^{-4}$ mol/l, and surface tension of the aquous solution was decreased to $27{\sim}38dyne/cm$. The experimental results for foaming power, foam stability, emulsifying power in liquid paraffin showed a good surface active properties, especially, dispersion effect in ferric oxide exhibited some efficient surface active properties, and then it would be expected to application as detergent and dispersion agent.

EFFECT OF STRENGTH MISMATCH AND DYNAMIC LOADING ON THE DUCTILE CRACK INITIATION FROM NOTCH ROOT

  • An, Gyn-Baek;Yoshida, Satoshi;Ohata, Mitsuru;Toyoda, Masao
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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    • pp.145-150
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    • 2002
  • It has been well known that ductile fracture of steels is accelerated by triaxial stresses. The characteristics of ductile crack initiation in steels are evaluated quantitatively using two-parameters criterion based on equivalent plastic strain and stress triaxiality. It has been demonstrated by authors using round-bar specimens with circumferential notch in single tension that the critical strain to initiate ductile crack from specimen center depends considerably on stress triaxiality, but surface cracking of notch root is in accordance with constant strain condition. In order to evaluate the stress/strain state in the specimens, especially under dynamic loading, a thermal, elastic-plastic, dynamic finite element (FE) analysis considering the temperature rise due to plastic deformation has been carried out. This study provides the fundamental clarification of the effect of strength mismatching, which can elevate plastic constraint due to heterogeneous plastic straining, loading mode and loading rate on critical condition to initiate ductile crack from notch root using equivalent plastic strain and stress triaxiality based on the two-parameter criterion obtained on homogeneous specimens under static tension. The critical condition to initiate ductile crack from notch root for strength mismatched bend specimens under both static and dynamic loading would be almost the same as that for homogeneous tensile specimens with circumferential sharp notch under static loading.

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고분자 계면활성제에 관한 연구(제6보) -알파 술폰 지방산 음이온성 올리고머 계면활성제의 계면성- (Studies on the Polymeric Surface Active Agent(VI) -The Surface Activities of Anionic Oligomer Surfactant with α-Sulfo Alkanoic Acid-)

  • 정노희;박상석;정환경;조경행;남기대
    • 공업화학
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    • 제4권4호
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    • pp.683-691
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    • 1993
  • Sodium dodecyl polyoxyethylene ${\alpha}$-sulfa alkanoates류 15종에 대하여 표면장력, 기포력 및 그 안정성, 유화력, 분산성, 습윤성 및 가용화능 등의 계면활성을 실험하였다. 이들 시료의 묽은 수용액에 대한 임계미셀농도는 $10^{-4}{\sim}10^{-5}mo1/{\ell}$ 범위였고 그 농도범위에서의 표면장력은 30~47dyne/cm였으며, 일정농도 수용액에 대한 기포력 및 그 안정성, 벤젠 및 대두유에 대한 유화력, 탄산칼슘 및 산화철에 대한 분산성, 그리고 습윤력과 Orange OT에 대한 가용화능을 실험하여 검토한 결과 O/W형 유제 및 분산제로서의 응용성이 기대된다.

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세 개의 히드록실기를 가진 양이온 계면활성제 합성 및 계면 특성에 관한 연구 (Synthesis and Characterization of Interfacial Properties of a Cationic Surfactant Having Three Hydroxyl Groups)

  • 이병민;김지현;김승수;임종주
    • 공업화학
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    • 제23권5호
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    • pp.433-439
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    • 2012
  • 본 연구에서는 도데실 글리시딜 에테르와 아미노에탄올을 반응시킨 후 디메틸 설페이트로 4급화시켜 분자 내에 2개의 라우릴기, 3개의 히드록실기를 가진 양이온 계면활성제 BHMAS (N,N-bis-(3'-n-dodecyloxy-2'-hydroxypropyl)-N-methyl-2-hydroxyethylammonium methyl sulfate)를 합성하였고, 생성물의 분자구조는 $^{1}H-NMR$, FT-IR 등의 기기분석을 통하여 확인하였다. 합성한 계면활성제의 CMC (critical micelle concentration)는 $9.12\;{\times}\;10^{-4}$ mol/L이며, CMC에서의 표면장력은 28.71 mN/m이었다. Maximum bubble pressure tensiometer를 사용하여 동적 표면장력을 측정한 결과, 공기와 수용액의 계면이 계면활성제 단분자에 의하여 포화되는 데 비교적 오랜 시간이 소요되었다. 1 wt% 계면활성제 수용액과 n-decane 사이의 계면장력은 0.045 mN/m이며, 평형에 도달하는 데 약 5 min의 시간이 소요되었다. 합성된 계면활성제의 흡착 특성이 매우 우수하였으며, 합성한 양이온 계면활성제가 섬유표면에 효과적으로 흡착되어 유연효과를 나타낼 수 있음을 확인하였다.