Wetting Properties of Biopolyester Films Prepared by Thermo-Compression Method

  • Published : 2007.04.30

Abstract

Water resistance of three biopolyester films, such as poly-L-lactate (PLA), poly-hydroxybutyrate-co-valerate (PHBV), and Ecoflex, and low density polyethylene (LDPE) film was investigated by measuring contact angle of various probe liquids on the films. The properties measured were initial contact angle of water, dynamic change of the water contact angle with time, and the critical surface energy of the films. Water contact angle of the biopolyester films ($57.62-68.76^{\circ}$) was lower than that of LDPE film ($85.19^{\circ}$) indicating biopolyester films are less hydrophobic. The result of dynamic change of water contact angle also showed that the biopolyester films are less water resistant than LDPE film, but much more water resistant than cellulose-based packaging materials. Apparent critical surface energy for the biopolyester films (35.15-38.55 mN/m) was higher than that of LDPE film (28.59 mN/m) indicating LDPE film is more hydrophobic.

Keywords

References

  1. Kaplan DL. Introduction to biopolymers from renewable resources. pp. 1-29. In: Biopolymers from Renewable Resources. Kaplan DL (ed). Springer-Verlag, Berlin, Germany (1988)
  2. Petersen K, Nielsen PY, Berteksen G, Lawther M, Olsen MB, Nilsson NH, Mortensen G. Potential of biobased materials for food packaging. Trends Food Sci. Tech. 10: 52-68 (1999) https://doi.org/10.1016/S0924-2244(99)00019-9
  3. Lenz RW, Marchessault RH. Bacterial polyesters: Biosynthesis, biodegradable plastics and biotechnology. Biomacromolecules 6: 18 (2005)
  4. Mohanty AK, Misra M, Drzal LT, Selke SE, Harte BR, Hinrichsen G Natural fibers, biopolymers, and biocomposites: An introduction. pp. 1-36. In: Natural Fibers, Biopolymers, and Biocomposites. Mohanty AK, Misra M, Drzal LT (eds). CRC Press, Inc., Boca Raton, FL, USA (2005)
  5. Clarinval AM, Halleux J. Classification of biodegradable polymers. pp. 3-31. In: Biodegradable Polymers for Industrial Applications. Smith R (ed). CRC Press, Inc., Boca Raton, FL, USA (2005)
  6. Scholz C, Gross RA. Biopolyesters and biocatalysis introduction. pp. 1-11. In: Polymers from Renewable Resources: Biopolyesters and Biocatalysis. ASC Symposium Series 764. Scholz C, Gross RA (eds). American Chemical Society, Washington, DC, USA (2000)
  7. Choi WS, Han JH. Film-forming mechanism and heat denaturation effects on the physical and chemical properties of pea-proteinisolate edible films. J. Food Sci. 67: 1399-1406 (2002) https://doi.org/10.1111/j.1365-2621.2002.tb10297.x
  8. Han JH, Krochta JM. Wetting properties and water vapor permeability of whey- protein-coated paper. Trans. ASAE 42: 1375-1382 (1999) https://doi.org/10.13031/2013.13300
  9. Han JH, Krochta JM. Physical properties and oil absorption of whey-protein-coated paper. J. Food Sci. 66: 294-299 (2001) https://doi.org/10.1111/j.1365-2621.2001.tb11335.x
  10. Rhim JW, Lee JH, Hong SI. Water resistance and mechanical properties of biopolymer (alginate and soy protein) coated paperboards. Lebensm. -Wiss. Technol. 39: 806-813 (2006) https://doi.org/10.1016/j.lwt.2005.05.008
  11. Rhim JW, Lee JH, Hong SI. Increase in water resistance of paperboard by coating with poly(lactide). Packaging Technol. Sci. 20: in press (2007)
  12. Hong SI, Han JH, Krochta JM. Optical and surface properties of whey protein isolate coatings on plastic films as influenced by substrate, protein concentration, and plasticizer type. J. Appl. Polym. Sci. 92: 335-343 (2004) https://doi.org/10.1002/app.20007
  13. Good RJ. Contact angle, wetting, and adhesion: A critical review. pp. 3-36. In: Contact Angles, Wettability, and Adhesion. Mittal KL (ed). VSP, Utrecht, The Netherlands (1993)
  14. Rhim JW, Mohanty AK, Singh SP, Ng PKW. Effect of processing methods on performance of polylactide (PLA) films: Thermocompression and solvent casting methods. J. Appl. Polym. Sci. 101: 3736-3742 (2006) https://doi.org/10.1002/app.23403
  15. Rhim JW. Mechanical and water barrier properties of biopolyester films prepared by thermo-compression method. Food Sci. Biotechnol. 16: 62-66 (2007)
  16. Biresaw G, Carriere CJ. Interfacial properties of starch/biodegradable esters blends. Polym. Reprints 41: 64-65 (2000)
  17. Karbowiak T, Debeaufort F, Voilly A. Importance of surface tension characterization for food, pharmaceutical and packaging products: A review. Crit. Rev. Food Sci. 46: 391-407 (2006) https://doi.org/10.1080/10408390591000884
  18. Nakajima A, Hashimoto K, Watanabe T. Transparent superhydrophobic thin films with self-cleaning properties. Langmuir 16: 7044-7047 (2000) https://doi.org/10.1021/la000155k
  19. Morillon V, Debeaufort F, Blond G, Capelle M, Voilley A. Factors affecting the moisture permeability of lipid-based edible films: A review. Crit. Rev. Food Sci. 42: 67-89 (2002) https://doi.org/10.1080/10408690290825466
  20. Hernandez RJ, Selke SEM, Culter JD. Plastic Packaging: Properties, Processing, Applications, and Regulations. Hanser Gardners Publications, Cincinnati, OH, USA. pp. 313-352 (2000)