• Title/Summary/Keyword: critical point equation

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Experimental and numerical study of headed bars embedded in RC members under tension

  • Santana, Paulo F.M.;Silva, Patricia C.S.;Ferreira, Mauricio P.;Bezerra, Luciano M.;Oliveira, Marcos H.
    • Structural Engineering and Mechanics
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    • v.84 no.4
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    • pp.531-546
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    • 2022
  • Headed bars are often used when there is insufficient space for a straight or curved bar to be fully developed to ensure the transference of forces between steel and concrete in several types of connections between structural members. In such cases, the concrete breakout strength of the headed bars can be a critical point of the design and must be considered appropriately. This paper evaluates the tensile strength of headed bars embedded in reinforced concrete members, failing due to concrete breakout. Four experimental tests on headed bars embedded in slender concrete members are presented and discussed, showing that strength previsions from the design codes can be significantly conservative as they ignore the contribution from the flexural reinforcement. 3D finite element models were developed using Abaqus Unified FEA to simulate the tested specimens, and it was observed that they were able to reproduce the formation of the concrete cone accurately, besides the response and resistance observed in tests. Furthermore, the experimental, numerical, and design code resistances are compared and discussed. A new equation to evaluate the concrete cone strength of the tested headed bars is proposed, which takes into account parameters not explicitly considered in the current design equations.

Effects of Water Conditions and Rhizobium Inoculation on the Growth of Wisteria floribunda Seedlings in Slope Soils (절개지 토양에서 수분조건과 근류균 접종이 등나무 유묘생장에 미치는 영향)

  • Park, Chong-Min
    • Korean Journal of Environment and Ecology
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    • v.20 no.4
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    • pp.425-435
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    • 2006
  • The objectives of this research were to investigate the drought resistance as well as the growth of Wisteria floribunda seedlings with the soil water conditions. The seedlings for the research were grown in pots with strict water content control on a frame located outdoors. During the experiments, the soil water contents were adjusted to 5, 10, 20, 30, 40, 50, 60, and 70%. In addition, the effects of Rhizobium inoculation on the growth of seedlings were investigated. The experimental results are summarized as follows: 1. The seedlings in the pots with 5% soil water content withered to death due to the water stress. Withering or any distinct growth was not observed from the seedlings in the 10% soil water content. It can be inferred from these results that about 5% of soil water content is the wilting point of W. floribunda seedlings and about 10% is the critical soil water content of its growth in this experiment soils. Therefore, it seems that W. floribunda possesses a good drought resistance. 2. From the analyses of the main growth parameters such as stem elongation, diameter growth, leaf area growth and total dry weight, it was found that the seedling growth can be improved with increasing soil water contents. The relation between each growth parameter(Y) and the soil water contents(W) was well described by a quadratic equation, $Y=a+bW+cW^2$. 3. In soil water contents higher than 20%, the seedling growth(Y) was remarkable along with-its extended growing period, and related to the growing period(D) by a quadratic equation, $Y=a+bD+cD^2$. 4. The artificial inoculation of Rhizobiun promoted the growth of Wisteria floribunda seedlings. 5. Rhizobium was found to be more readily inoculated and to form more root nodules compared to seedlings grown in higher soil water contents.

Process Design of Carbon Dioxide Storage in the Marine Geological Structure: I. Comparative Analysis of Thermodynamic Equations of State using Numerical Calculation (이산화탄소 해양지중저장 처리를 위한 공정 설계: I. 수치계산을 통한 열역학 상태방정식의 비교 분석)

  • Huh, Cheol;Kang, Seong-Gil
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.11 no.4
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    • pp.181-190
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    • 2008
  • To response climate change and Kyoto protocol and to reduce greenhouse gas emissions, marine geological storage of $CO_2$ is regarded as one of the most promising option. Marine geological storage of $CO_2$ is to capture $CO_2$ from major point sources(eg. power plant), to transport to the storage sites and to store $CO_2$ into the marine geological structure such as deep sea saline aquifer. To design a reliable $CO_2$ marine geological storage system, it is necessary to perform numerical process simulation using thermodynamic equation of state. The purpose of this paper is to compare and analyse the relevant equations of state including ideal, BWRS, PR, PRBM and SRK equation of state. To evaluate the predictive accuracy of the equation of the state, we compared numerical calculation results with reference experimental data. Ideal and SRK equation of state did not predict the density behavior above $29.85^{\circ}C$, 60 bar. Especially, they showed maximum 100% error in supercritical state. BWRS equation of state did not predict the density behavior between $60{\sim}80\;bar$ and near critical temperature. On the other hand, PR and PRBM equation of state showed good predictive capability in supercritical state. Since the thermodynamic conditions of $CO_2$ reservoir sites correspond to supercritical state(above $31.1^{\circ}C$ and 73.9 bar), we conclude that it is recommended to use PR and PRBM equation of state in designing of $CO_2$ marine geological storage process.

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Influence of Oxidation Inhibitor on Carbon-Carbon Composites : 7. Studies on Work of Adhesion and Fracture Toughness of Carbon-Carbon Composites (산화억제제를 첨가한 탄소/탄소 복합재료의 물성에 관한 연구 : 7. 탄소/탄소 복합재료외 부착력과 파괴인성)

  • 박수진;서민강;이재락
    • Polymer(Korea)
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    • v.25 no.3
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    • pp.435-440
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    • 2001
  • The objective of this study was to examine the effect of oxidation inhibitor contents on the work of adhesion, fracture toughness, and impact strength of the unidirectional carbon-carbon composites (C/C composites). The molybdenum disilicide ($MoSi_2$) used as an oxidation inhibitor was impregnated with phenolic resins to improve the anti-oxidation properties of the composites in different concentrations of 4, 12 and 20 wt%. Based on Wilhelmy equation, the work of adhesion of C/C composites was calculated by contact angle methods. Fracture toughness and impact strength were pressured by three-point bending test for the critical intensity factor ($K_IC$) and Izod test method, respectively. As a result, the composites made with $MoSi_2$ resulted in an increasing of both fracture toughness and impact strength. Especially, the composites made with 12 wt% $MoSi_2$ content showed the highest value of London dispersive component, $W_A\;^L$, in work of adhesion, resulting from improving the interfacial adhesion force among fibers, filler, and matrix in this system.

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Rheological Measurement of Fiber Spinnability of PVA Solution Dopes in DMSO

  • Chae, Dong-Wook
    • Textile Coloration and Finishing
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    • v.22 no.3
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    • pp.187-193
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    • 2010
  • The effects of molecular weight (MW) and concentration on the rheological properties of poly(vinyl alcohol) (PVA) solutions in dimethyl sulfoxide (DMSO) were investigated at $30^{\circ}C$. Ubbelohde viscometer and rotational rheometer were employed for dilute and concentrated regime, respectively. In the dilute regime, the Mark-Houwink exponent ($\alpha$) of the solutions determined from three different MWs proved 0.73. The critical concentration (C*), in which the entanglement and overlap of polymer molecules began to take place, decreased with increasing the MW of PVA. Huggins constant ($K_H$) values ranged from 0.33 to 0.45 over the MW examined. In the log-log plot of $\eta_{sp}$ versus [$\eta$]C, the PVA with higher degree of polymerization (DP) gave a greater slope exhibiting the inflection point in the vicinity of C*. In the dynamic viscosity ($\eta'$) curve, the PVA solutions of DP 1700 presented Newtonian fluid behavior over most of the frequency range examined. However, the lower Newtonian flow region reduced with increasing the DP. As the PVA concentration increased, $\eta'$ was increased and the onset shear rate for pseudoplasticity was decreased. In the Cole-Cole plot, PVA solutions showed almost a single master curve in a slope of ca. 1.65 regardless of the DP. However, the increase of the concentration from 8 to 12 wt% for PVA solutions of DP 5000 decreased the slope from 1.73 to 1.57. In the tan $\delta$ curve, the onset frequency for sol-gel transition was shifted from 154 to 92 rad/s with increasing the DP from 3300 to 5000 and from 192 to 46 rad/s with increasing the concentration from 8 to 12 wt%. In addition, longer relaxation time ($\lambda$) was observed with increasing the DP and concentration.

The Phase Space Analysis of 3D Vector Fields (3차원 벡터 필드의 위상 공간 분석)

  • Jung, Il-Hong;Kim, Yong Soo
    • Journal of Digital Contents Society
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    • v.16 no.6
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    • pp.909-916
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    • 2015
  • This paper presents a method to display the 3D vector fields by analyzing phase space. This method is based on the connections between ordinary differential equations and the topology of vector fields. The phase space analysis should be geometric interpolation of an autonomous system of equation in the form of the phase space. Every solution of it system of equations corresponds not to a curve in a space, but the motion of a point along the curve. This analysis is the basis of this paper. This new method is required to decompose the hexahedral cell into five or six tetrahedral cells for 3D vector fields. The critical points can be easily found by solving a simple linear system for each tetrahedron. The tangent curves can be integrated by finding the intersection points of an integral curve traced out by the general solution of each tetrahedron and plane containing a face of the tetrahedron.

A Study on the Synthesis and Physical Properties of N-acyloxyethyl carboxybetaine Type Amphoteric Surfactants (N-acyloxyethylcarboxybetaine 형 양성계면활성제의 합성과 물성에 관한 연구)

  • Kim, Yong-In;Soh, Hie-Jeun;Oh, Yang-Hwan;Kim, Byung-Kie
    • Journal of the Korean Applied Science and Technology
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    • v.6 no.1
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    • pp.31-40
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    • 1989
  • Five novel amphoteric surfactants of N-acyloxyethylcarboxybetaine series were synthesized via Schotten-Baumman reaction between five acid chlorides containing 10, 12, 14, 16 and 18 carbon atoms in their N-alkyl groups and dimethylaminoethanol to give the intermediate products, 2-dimethylaminoethylalkanoates(2). Quaternization of these products(2) was permitted to from 2-(acyloxyethyldimethylammonic)- acetates(3), whose structures were identified by elemental analysis, IR spectrophotometry and $^1Hnmr$ spectrometry. The yield of the final products was shown in the range of 77-80% based on the intermediate products. The surface tension of the aqueous solution of (3) was measured, and the critical micelle concentrations (cmc) were shown in the range of $2.1\;{\times}\;10^{-3}\;-\;3.3\;{\times}\;10^{-4}mol/l$, and the surface tension at cmc was 28-36 dyne/cm. Cmc was lowered gradually by the increment of the length of N-alkyl ester containing group. The isoelectric point was shown in the range of 4.44-5.20. It showed a tendency to lean toward the acidic site and its range was broadened as increase of the hydrophobic group length. A linear relationship between log cmc and the number of carbon atoms(N) in the hydrophobic alkyl chain was shown in the relative equation of log cmc=-1.75-0.1N, and the contribution rate of N on the standard free energy change in micellization, ${\bigtriangleup}({\bigtriangleup}G^{\circ}m)/{\bigtriangleup}N$, was calculated as -0.23 RT.

Synthesis and Surface Activities of Betaine Amphoteric Surfactant Having Ether Bond (에테르 결합을 가진 베타인계 양성계면활성제(兩性界面活性濟) 합성(合成) 및 계면활성(界面活性))

  • Cha, Kyung-On;Lee, Hi-Jong;Kim, Yong-In
    • Journal of the Korean Applied Science and Technology
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    • v.9 no.1
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    • pp.63-71
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    • 1992
  • Four novel amphoteric surfactants of N-alkoxyethylcarboxybetaine series were synthesized via Schotten-Baurnman reaction between four alkyl chlorides contaning 10, 12, 14 and 16 carbon atoms in their N-alkyl group and dimethylaminoethanol to give the intermediate products, alkoxyethyldimethylamine, Quaternization of these intermediates was permitted to form 2-(alkoxyethyldimethylarnmonio) acetates, whose structures were identified by elemental analysis. IR spectrophotometry and $^1$Hnmr spectrometry. The yield of the final products was shown in the range of $74{\sim}77%$ based on the yield of the intermediate products, Surface tension of the aqueous solution of the final products was measured. and the critical micelle concentrations(cmc) were shown in the range of $2.82{\times}10^{-3}{\sim}2.67{\times}10^{-6}$mol/l, and the surface thension at erne was 35${\sim}$43dyne/cm. Cmc was lowered gradually by the increase of carbon numbers in N-alkyl ether containing group. The isoelectric point was shown in the range of 4.08${\sim}$6.03. It showed a tendency to lean toward the acidic site and its range was broadened as increase of the hydrophobic group length. A linear relationship between log erne and the number of carbon atoms(N) in the hydrophobic alkyl chain was shown in the relative equation of log cmc=2.49-0.50N.

A Numerical Study of the Residual Hydrogen Concentration in the Weld Metal (용접금속 잔류수소농도의 수치해석 연구)

  • Yoo, Jinsun;Ha, Yunsok;S.R., Rajesh
    • Journal of Welding and Joining
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    • v.34 no.6
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    • pp.42-46
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    • 2016
  • Hydrogen assisted cracking (HAC) is one of the most complicated problem in welding. Huge amount of studies have been done for decades. Based on them, various standards have been established to avoid HAC. But it is still a chronic problem in industrial field. It is well known that the main causes of the hydrogen crack are residual stress, crack susceptible micro structures and a certain critical level of hydrogen concentration. Even though the exact generating mechanism is unclear till today, it has been reported that the hydrogen level in the weld metal should be managed less than a certain amount to prevent it. Matsuda studied that the residual hydrogen level in the weld metal can be varied even if the initial hydrogen content is same. It is also insisted in this report that the residual hydrogen concentration is in stronger correlation with hydrogen crack than the initial hydrogen content. But, in practical point of view, the residual hydrogen is still hard to consider because measuring hydrogen level is time and cost consuming process. In this regard, numerical analysis is the only solution for considering the residual hydrogen content. Meanwhile, Takahashi showed the possibility of predicting the residual hydrogen by a rigorous FE analysis. But, few commercial software suitable for solving the weld metal hydrogen has been reported yet. In this study, two dimensional thermal - hydrogen coupled analysis was developed by using the commercial FE software MARC. Since the governing equation of the hydrogen diffusion is similar to the heat transfer, it is shown that the heat transfer FE analysis in association with hydrogen diffusion property can be used for hydrogen diffusion analysis. A series of simulation was performed to verify the accuracy of the model. For BOP (Bead-On-Plate) and the multi-pass butt welding simulations, remaining hydrogen contents in the weld metal is well matched with measurements which are referred from Kim and Masamitsu.

Estimating the rating curve of irrigation canals in the Cheongju Sindae area

  • Mikyoung Choi;Inhyeok Song;Heesung Lim;Hansol Kang;Hyunuk An
    • Korean Journal of Agricultural Science
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    • v.51 no.1
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    • pp.79-86
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    • 2024
  • As the frequency and intensity of heavy rains increase, the vulnerability of agriculture to disasters also increases. Consequently, there is a need to improve flood and inundation predictions. To enhance the accuracy of inundation predictions, it is essential to monitor water level and discharge data within agricultural areas. This study was conducted to monitor water levels and rainfall in the Cheongju Sindae area from 2022 to 2023, and the data was utilized as input and validation data for agricultural inundation modeling. Four irrigation drainage canals were installed to a square-shaped concrete structure where the water level gauge is. It was then confirmed that the water level rises with rainfall. The flow velocities were monitored during periods of heavy rainfall. The rating curve, which estimates water level and flow velocity based on observations, was estimated using the software K-HQ. The resulting curve was presented with the Coefficient of Determination (R2). K-HQ was also used to calculate the equation for the rating curve, taking outliers into account at each data point. Outliers were extracted and the rating curve was recalculated. As the coefficient of determination of three out of four stations exceeded 0.95, the estimated rating curve may be considered reliable for discharge estimation. This study provides critical data for enhancing agricultural inundation modeling accuracy and drainage improvement projects.