• Title/Summary/Keyword: critical means

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The Substitution Mechanism of $[CoCl(Hedta)]^-$ ion by Ethylenediamine in the Presence of $Hg^{2+}$ ion ($Hg^{2+}$이온의 존재하에서 $[CoCl(Hedta)]^-$ 이온에 대한 에틸렌디아민과의 치환반응기구에 관한 연구)

  • Sang-Mock Lee;Dong-Jin Lee;Myung-Ki Doh
    • Journal of the Korean Chemical Society
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    • v.31 no.6
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    • pp.534-541
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    • 1987
  • The study of reaction mechanism for the substitution of ethylenediamine (en) for Cl and Hedta from $[CoCl(Hedta)]^-$ in the presence of $Hg^{2+}$ ion was carried out by uv and CD spectra. From the kinetic data, we proposed that the first ethylenediamine be substituted through the associative reaction path by means of interaction of $Hg^{2+}$ ion with Co(III), and that the second and the third ethylenediamine be substituted stepwise. From the optical purities of $[Co(en)_3]^{3+}$ which was formed after reaction, we suggested the critical stereochemical step and new substitution reaction paths.

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Developing an On-line Scheduling System for Increasing Effectiveness of Public Research Facility (공공기관 연구시설장비 효율성 향상을 위한 온라인 일정계획 시스템 개발)

  • Lee, Chae-Yun;Kim, Ki-Hong;Shin, Seung-Jun
    • Journal of the Korea Safety Management & Science
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    • v.19 no.1
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    • pp.181-189
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    • 2017
  • The systematic management of technology infrastructure increasingly becomes critical as it represents the driving power for creating competitive advantage of nations and enterprises. In this sense, public facility and equipment, which is one major asset of technology infrastructure, should be managed effectively, systematically and efficiently to increase its overall equipment effectiveness. However, the manual and off-line communication was the unique way to communicate between the suppliers who provide facilities in the public sector and the customers who utilize the facilities in the industrial sector. This communication way caused invisibility of available usage time and increase of idle time, thereby decreasing the equipment effectiveness. This paper presents an web-based scheduling system that enables real-time collaboration and information sharing for increasing the equipment effectiveness. The designed system performs scheduling, facility management, order management and customer relationship management in an on-line platform, and carries out the processing and storing of relevant information in an integrated database. The paper includes a development approach to identify business process models and standardized system models by using object-modeling technique. The deliverable of the present work will contribute to increasing the equipment effectiveness by enhancing visibility, transparency and predictability by means of the integration with a legacy Enterprise Resource Planning.

EXPERIMENTAL STUDY ON THE CHARACTERISTICS OF RIVERBED MATERIALS USING AN ULTRASONIC SENSOR

  • Yeo, Woon-Kwang;Jang, Bok-Jin;Lee, Jong-Kook;Kim, Young-Bin
    • Water Engineering Research
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    • v.7 no.1
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    • pp.21-28
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    • 2006
  • The scouring process is complex and subject to many factors. Recently, experiments for real-time bridge scour monitoring have been active as means for a more reliable scour prediction. Riverbed materials are an important factor in bridge scouring; therefore, an accurate estimation of riverbed material is critical in predicting a scour. As a part of this approach, an ultrasonic sensor, which can not only detect river bottom during floods but can also be installed lose to the underwater structures, was developed. This sensor is able to map the river bottom using an ultrasonic waves with the characteristics of the returning wave, reflected from an object or bottom ground. The reflected wave is unique according to the situations, or materials below. Therefore, it would be possible to identify the consisting materials of a riverbed if we could reveal each characteristic in the received signals. In this study, a preliminary experiment was performed in the laboratory to identify and classify received signals, which is unique to each material. The analysis of this experiment gives the graph, which makes it possible to identify materials of the river bottom through the ultrasonic signals. The proposed graph was verified through a comparison with the actual field data measured in river.

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Effect of the voltage lead configurations on AC Loss Measurement in a Single Layer High-Tc Superconducting Model Cable (전압리드의 배치가 단층 고온초전도 모델케이블의 교류손실 측정에 미치는 영향)

  • 류경우;정재훈;황시돌;김석환
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.51 no.12
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    • pp.670-675
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    • 2002
  • AC loss is an important issue in the design of high-T$_{c}$ superconducting Power cables. The cables consists of a number of Bi-2223 tapes wound on a former. In such cables tapes have different critical current characteristics intrinsically. And they are electrically connected to each other and current leads by soldering. These make loss measurements considerably complex, especially for short samples of laboratory size. Special cautions are required in the positioning of voltage leads for measuring the true loss voltage. In this work the at losses in a single layer model cable have been experimentally investigated for different contacts and arrangements of voltage leads. The results show that the losses are not dependent on both arrangements and contact positions of the voltage leads. This implies that loss flux is only in a cylindrical conductor section. The measured losses also agree well with those based on a monoblock model and are independent of frequencies. This means that the measured AC loss of the model cable is purely hysteretic in nature.e.

Experimental Investigation on the Highly N2-diluted CH4-O2 Flame Stabilization in an Axially Two-section Porous Medium (축방향 2단 다공체 내 N2로 과다 희석된 CH4-O2 화염의 안정화에 관한 실험적 연구)

  • Kim, Seung Gon;Lee, Dae Keun;Noh, Dong-Soon;Ko, Chang-Bog
    • 한국연소학회:학술대회논문집
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    • 2013.06a
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    • pp.45-46
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    • 2013
  • Stabilization characteristics of highly $N_2$-diluted $CH_4-O_2$ flame in an axially two-section porous inert medium were experimentally investigated for its application to the waste gas scrubber in semiconductor manufacturing processes. The flame behaviors were observed with respect to the fuel and $N_2$ flow rates and the equivalence ratios. As a result, four kinds of flame behaviors such as stable, flashback crossing the interface, blowout and sudden extinction were observed. It was also found that there exists two flame regime divided by a critical fuel flow rate. In addition, the flame stability was discussed based on the $N_2$ index which means the abatement capacity of our combustor in scrubbing the waste gas from the semiconductor processes.

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Microstructural Evolution of Electromagnetically Stirred Al alloy Billet During Isothermal Reheating at the Solid-liquid State (전자기 교반한 알루미늄합금 빌렛의 재가열시 고액공존구역에서의 조직변화)

  • Lee, Dock-Young
    • Journal of Korea Foundry Society
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    • v.28 no.3
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    • pp.129-135
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    • 2008
  • The reheating stage of electromagnetically stirred Al billet is a critical factor in the thixoforming process. When reheated to the solid-liquid state, the microstructure evolves to a more globular and more homogeneous structure by a coarsening mechanism, the kinetics depending on the initial microstructure. Microstructural evolution has been characterized by conventional parameters (mean size of particle and shape factor) as a function of holding time in the solid-liquid state. The aim of this study is to report experimental results concerning microstructural evolution in the solid-liquid state of electromagnetically stirred Al billet. The material was elaborated in the form of continuously cast bars solidified with electromagnetic stirring to degenerate the dendritic structure. The choice of the reheating conditions is determined by a dendritic ripening and coalescence mechanism, involving variations of both the shape and size of the particles. The reheating time has to be long enough to allow a minimum degree of spheroidizing, but has to be limited as much as possible in order to avoid excessive ripening. The optimum microstructure was obtained at the reheating temperature of near $584^{\circ}C$ and the holding time of 5 min. The only means of combining high productivity with good casting quality was to use feedstock billets whose microstructure showed rapid transformation characteristics.

A New Upper Layer Decoding Algorithm for MPE-FEC based on LLR (LLR 기반의 MPE-FEC 상위계층 복호 방식)

  • Kim, Chul-Seung;Kim, Min-Hyuk;Park, Tae-Doo;Kim, Nam-Soo;Jung, Ji-Won
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.13 no.10
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    • pp.2227-2234
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    • 2009
  • DVB-SSP is a new broadcasting system for hybrid satellite communications, which supports mobile handheld systems and fixed terrestrial systems. An upper layer, including erasure Reed-Solomon error correction combined with cyclic redundancy check. However, a critical factor must be considered in upper layer decoding. If there is only one bit error in an IP packet, the entire IP packet is considered as unreliable bytes, even if it contains correct bytes. If, for example, there is one real byte error, in an IP packet of 512 bytes, 511 correct bytes are erased from the frame. Therefore, this paper proposed upper layer decoding methods; LLR-based decoding. By means of simulation we show that the performance of the proposed decoding algorithm is superior to that of the conventional one.

Electrical and Mechanical Properties in High Tc Superconducting Wires for HTSC Cable (고온 초전도 케이블용 선재의 특성해석에 관한 연구)

  • Kim, Seng-Hyun;Jang, Hyun-Man;Jeong, Jong-Man;Kim, Young-Seok;Baek, Seung-Myong
    • Proceedings of the KIEE Conference
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    • 1998.11a
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    • pp.382-385
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    • 1998
  • To be applied to electrical equipment HTSC tapes have to endure external stress and so on. The critical current density has been shown depending on the mechanical properties, strain and bending stress. AC loss reduction is primary concern in the development of such high-efficiency equipment. AC losses in Bi-2223 silver-sheathed tapes, both single and multi-filamentary, were investigated by means of AC magnetization techniques. The results were compared with the hysteresis loss equation based on Bean model and the eddy current loss equation. The AC loss of the mono-filamentary tape was the hysteresis. On the contrary, the AC loss of the multi-filamentary tape was substantially dominated by the eddy current loss in the Ag matrix.

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Customer Satisfaction Measurement Model Based on QFD

  • Liu, Yumin;Xu, Jichao
    • International Journal of Quality Innovation
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    • v.4 no.2
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    • pp.101-122
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    • 2003
  • With the development of the American Customer satisfaction index (ACSI), research on customer satisfaction measurement or evaluation methods have become significant in the last decade. Most of international customer satisfaction barometers or indices are evolved based on the cause and effect relationship model of ACSI. Of critical importance to validity of customer satisfaction indices is how to construct a measurement attribute or indicator model and provide an effective implementation method effectively. Quality Function Deployment (QFD) is a very useful tool for translating the customer voice into product design through quality engineering. In fact, this is a methodology for measuring and analyzing evaluation indicators by their relationship matrix. In this paper, we will make an effort to integrate the framework of QFD into the measurement problem of customer satisfaction, and also develop a new multi-phase QFD model for evaluation of Customer Satisfaction Index (CSI). From the houses of quality in this model, the evaluation indicators impacting on customer's global satisfaction are identified by means of their relationship matrix. Then the evaluation indicator hierarchy and its measurement method for the customer satisfaction index are presented graphically. Furthermore, survey data from the Chinese automobile maintenance sector and a relevant case study are utilized to show the implementation method of the QFD model used to measure and analyze of customer satisfaction.

Osteoclast Activity and Osteoporosis

  • Kim, Hong-Hee
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 2001.04a
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    • pp.103-112
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    • 2001
  • Bone homeostasis is maintained by a balance between activities of osteoblasts(bone forming cells) and osteoclasts (bone resorbing cells). The activities of these cells are closely regulated by multiple factors including hormones and cytokines. The cessation of estrogen at menopause disrupts the balanced regulation and is the main cause of osteoporosis in postmenopausal women. Recent molecular biological studies led to a discovery of tumor necrosis factor(TNF) and TNF receptor families genes that play critical roles in the regulation of osteoclast formation and function. RANKL (receptor activator of nuclear factor kappa B ligand; also called ODF, TRANCE, and OPGL) expressed on cells supporting osteoclast is essential for osteoclast differentiation, activation, and survival. RANK, the counter-receptor for RANKL, is expressed on progenitor and mature osteoclasts. The interaction between RANKL and RANK is requlated by a soluble decoy receptor OPG (osteoprotegerin). Gene knock out studies of these molecules showed profound effects on bone. These results prompted development of new strategies for treatment of bone diseases. Inhibition of osteoclast activity by blocking the RANKL-RANK interaction using OPG is being attempted. Research on the signaling pathways of RANK is also actively carried out. Screening natural products that inhibit the RANKL-RANK interaction or the activity of obteoclasts would be another effective means to a new drug target for bone resorbing diseases.

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