• Title/Summary/Keyword: critical concentration

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A Study on Characteristics of Exhaust Gas Emissions of Water-Bunker Oil Mixed by Homogenizer (균질기에 의해 혼합된 물-벙커유의 배기가스 배출 특성에 관한 연구)

  • Choi, Jung-Sik;Han, Sang-Goo;Choi, Jae-Hyuk;Park, Sang-Kyun;Park, Ro-Seong;Kim, Dae-Hun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.19 no.5
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    • pp.518-524
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    • 2013
  • In this study, we conducted a study on characteristics of exhaust gas emissions from boiler when water-bunker oil mixed by homogenizer was burned in boiler. The results showed that NOx concentration and CO concentration of the homogenized bunker oil was decreased by 19% and 54% compared to pure bunker oil pretreatment was not being performed. And, in the case of water-bunker A oil, the NOx concentration was decreased with increasing water mixing ratio in bunker A oil. In particular, the NOx concentration in exhaust gas of 20 %water-80 %bunker A oil decrease by 45 % compared with pure bunker-A. However, the CO concentration in exhaust gas of 20 %water-80 %bunker A oil shows irregular changes. This means that the mixing of water more than a certain amount can cause a decrease in combustion performance. From this result, it can be found that critical mixing ratio of water in bunker A oil for normal combustion is 15% in this study. Deposition amount of soot that is collected in the vicinity of the chimney was decreased with increasing water mixing ratio.

A Study on the Critical Duration of Design Rainfall in Midsize Catchment (중규모 하천유역에서 설계강우의 임계지속기간에 관한 연구)

  • Park, Jong-Young;Shin, Chang-Dong;Lee, Jung-Sik
    • Journal of Korea Water Resources Association
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    • v.37 no.9
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    • pp.695-706
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    • 2004
  • This study is to propose the temporal pattern of design rainfall which causes maximum peak discharge, and to analyze the relation of catchment characteristics and critical durations for gauged midsize catchment. Hydrologic analysis has done over the 44 midsize catchments with 50-5,000$\textrm{km}^2$. The type of temporal pattern of design rainfall which causes maximum peak discharge has resulted in Huff's 4 quartile distribution method for effective rainfall(AMC III) The peak discharges of 24hr rainfall duration are similar to those of critical duration for 50-600$\textrm{km}^2$, and the peak discharges of 48hr rainfall duration are similar to those of critical duration for 600-5,000$\textrm{km}^2$. Therefore, if the proper rainfall intensity formula is selected, 24hr or 48hr rainfall duration may be regarded as the critical duration of midsize catchment. A simple regression equation is derived by using a catchment area and critical duration with high correlation for the case of effective rainfall(AMC III). Therefore, it can be used to determine the critical duration of ungauged catchment with 50-5,000$\textrm{km}^2$. Also, dimensionless regression equation is derived by using characteristic values of unit hydrograph.

Estimation of Optimum Application Rate of Nitrogen Fertilizer Based on Soil Nitrate Concentration for Tomato Cultivation in Plastic Film House (토양의 질산태 질소 검정에 의한 시설재배 방울토마토의 질소 적정시비량 추정)

  • Kang, Seong-Soo;Hong, Soon-Dal
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.2
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    • pp.74-82
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    • 2004
  • This study was conducted to estimate the optimum application rate of fertilizer N based on $NO_3-N$ concentration in soils for tomato (Lycopersicon esculentum Mill.) cultivation in plastic film house. Tomato plants were cultivated with and without fertilizer in twelve soils which have different concentrations of $NO_3-N$ ranging from 46 to $344mg\;kg^{-1}$. Dry weight (DW) of above-ground part of tomato with no fertilizer ranged from 28.9 to $112.5g\;plant^{-1}$, depending on N-supplying capability of soils. The soil $NO_3-N$ was positively correlated with DW ($r=0.83^{**}$) and N uptake ($r=0.78^{**}$) by tomatoes in no fertilizer treatment, and negatively correlated with fertilizer effciencies resulted from the differences of DW and N uptake between fertilized and non-fertilized plot. The relationships between soil $NO_3-N$ concentration and DW, N uptake, and fertilizer efficiency were analyzed to determine the critical levels of soil $NO_3-N$ for tomato cultivation. The limit critical levels of soil $NO_3-N$ were estimated to be more than $280mg\;kg^{-1}$ for no application of fertilizer N and to be less than $50mg\;kg^{-1}$ for recommended application of fertilizer N. These critical levels of soil $NO_3-N$ were nearly the same as those calculated from regression equation between electrical conductivity(EC) and soil nitrate for critical levels of EC in recommendation equation of fertilizer N for tomato under the plastic film house by NationaI Institute of Agricultural Science and Technology. Consequently, the optimal application rate of ferdilizer N for tomato cultivation in the soils containing $NO_3-N$ concentration between $280mg\;kg^{-1}$ and $50mg\;kg^{-1}$ was estimated by the equation Y = -0.4348X+121.74, where Y is the percent(%) to the recommended application rate of N fertilizer and X is the soil $NO_3-N$ concentration ($mg\;kg^{-1}$).

Optimization of Production Conditions of Biosurfactant from Bacillus sp. and its Purification (Bacillus sp.에 의한 생물계면활성제의 생산 및 그의 성질)

  • Kim, Jin-Sook;Song, Hee-Sang;Chung, Nam-Hyun;Bang, Won-Gi
    • Applied Biological Chemistry
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    • v.48 no.2
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    • pp.109-114
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    • 2005
  • A bacterium capable of emulsifying hydrocarbon, n-hexadecane, and decreasing surface tension of the culture media using oil collapsing method was isolated. The bacterium was partially identified as Bacillus sp. and named BJS-51. n-Hexadecane was the most effective carbon source for production of biosurfactant. Surface tension was decreased from 76 dyne/cm to 31 dyne/cm and CMD (critical micelle dilution) had the highest value of 5.7 at 3% n-hexadecane. Ammonium phosphate was the most effective nitrogen source, when C/N ratio was 60, surface tension and CMD were 29 dyne/cm and 9.2, respectively. Optimum pH and temperature were 7.2 and $30^{\circ}C$, respectively. Produced biosurfactant was extracted and purified using organic solvent extraction method and preparative HPLC systems. After analysis by various color reaction, this biosurfactant was identified as lipopolysaccharide. Surface tension and CMC (critical micelle concentration) of purified biosurfactant were 27 dyne/cm and 0.08 g/l, repectively. CMD was 9.2, so the yield of biosurfactant was about 0.74 g/l at the optimal conditions. The biosurfactant was very stable at wide range of $pH\;2{\sim}12$ with surface tension $29{\sim}31\;dyne/cm$ and showed $29{\sim}30\;dyne/cm$ of surface tension after heat treatment at $100^{\circ}C$ for 60 min.

Water Deficit in Salt- and Drought- stressed Rice (Oryza sativa L.) Seedlings (염과 건조처리에 따른 벼 유묘의 수분결핍)

  • Kang, Dong-Jin;Ishii, Ryuichi;Lee, In-Jung
    • Current Research on Agriculture and Life Sciences
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    • v.21
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    • pp.1-9
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    • 2003
  • Plants are often subjected to periods of soil and atmospheric water deficit during their life cycle. To find critical levels for identification of tolerant rice variety to salt- and drought-stresses, we investigated the water deficiency in the leaf of a Dongjinbyeo (DJ) cultivar, identified as intolerant variety, subjected to NaCl- and Polyethylene glycol 6000 (PEG)- treatments. The relative water content and water potential in leaf of DJ plant sharply declined along the high concentration and time after treatment in NaCl- and PEG-treated rice plants. To elucidate the method of simple screening of tolerant variety to salt- and drought-stresses, we examined the relationship between relative water content and water potential of leaves in NaCl- and PEG-treated rice plants. The relationship between relative water content and water potential in leaf of DJ plant showed the highest correlation in 80 mM NaCl-treatment, and showed high correlation only 8% PEG treatment. These results indicate that the critical level of salt stress for screening of tolerant rice was 80 mM NaCl at 48 h after NaCl treatment, and the critical concentration of drought stress for screening of tolerant rice was 8% PEG at 96 h after PEG treatment.

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Steady Shear Flow Properties of Aqueous Poly(Ethylene Oxide) Solutions (폴리에틸렌옥사이드 수용액의 정상유동 특성)

  • Song, Ki-Won;Kim, Tae-Hoon;Chang, Gap-Shik;An, Seung-Kook;Lee, Jang-Oo;Lee, Chi-Ho
    • Journal of Pharmaceutical Investigation
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    • v.29 no.3
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    • pp.193-203
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    • 1999
  • In order to investigate systematically the steady shear flow properties of aqueous po1y(ethylene oxide) (PEO) solutions having various molecular weights and concentrations, the steady flow viscosity has been measured with a Rheometrics Fluids Spectrometer (RFS II) over a wide range of shear rates. The effects of shear rate, concentration, and molecular weight on the steady shear flow properties were reported in detail from the experimentally measured data, and then the results were interpreted using the concept of a material characteristic time. In addition, some flow models describing the non-Newtonian behavior (shear-thinning characteristics) of polymeric liquids were employed to make a quantitative evaluation of the steady flow behavior, and the applicability of these models was examined by calculating the various material parameters. Main results obtained from this study can be summarized as follows: (1) At low shear rates, aqueous PEO solutions show a Newtonian viscous behavior which is independent of shear rate. At shear rate region higher than a critical shear rate, however, they exhibit a shear-thinning behavior, demonstrating a decrease in steady flow viscosity with increasing shear rate. (2) As an increase in concentration and/or molecular weight, the zero-shear viscosity is increased while the Newtonian viscous region becomes narrower. Moreover, the critical shear rate at which the transition from the Newtonian to shear-thinning behavior occurs is decreased, and the shear-thinning nature becomes more remarkable. (3) Aqueous PEO solutions show a Newtonian viscous behavior at shear rate range lower than the inverse value of a characteristic time $1/{\lambda}_E$, while they exhibit a shear-thinning behavior at shear rate range higher than $1/{\lambda}_E$. For aqueous PEO solutions having a broad molecular weight distribution, the inverse value of a characteristic time is not quantitatively equivalent to the critical shear rate, but the power-law relationship holds between the two quantities. (4) The Cross, Carreau, and Carreau-Yasuda models are all applicable to describe the steady flow behavior of aqueous PEO solutions. Among these models, the Carreau-Yasuda model has the best validity.

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Improvement of the Ammonia Analysis by the Phenate Method in Water and Wastewater

  • Park, Ga-Eun;Oh, Ha-Na;Ahn, Sam-Young
    • Bulletin of the Korean Chemical Society
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    • v.30 no.9
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    • pp.2032-2038
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    • 2009
  • The amount of phenol and NaOH for the colorimetric determination of ammonia in Korean standard methods (KSM) is found to be highly excessive compared to the standard methods of several other countries. The absorbance of indophenol formed by the Berthelot reaction for ammonia analysis was measured under the various reaction conditions classified in experiment groups 1, 2, 3, 4 and KSM and American standards methods (ASM), and the relationships between the absorbance of indophenol and concentration of ammonia were compared. The amount of phenol can be reduced to 10 g (current 25 g in KSM) and NaOH can be reduced to 1.76 g (current 11 g in KSM) for the preparation of 200 mL phenate solution, and the absorbance sensitivity increased. The concentration of the phenol and NaOH correlatively affect the pH of the solution, which is a critical variable in achieving the maximum sensitivity and rapid and stable color development.

Behavior of Chloride Binding in Hardened Cement Pastes (Forcused on $C_3A$ content) (시멘트 경화체내 염화물의 고정화 성상 ($C_3A$ 함유량을 중심으로))

  • 임순지;소형석;소승영;박홍신;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.87-92
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    • 1994
  • The main objective of this study is to determine the critical chloride ion concentrations in the pore solutions causing depassivation of steel reinforcement in concrete made with cements of different $C_3A$ contents. Cement pastes with water-ratio of 0.5 were prepared using four cements with $C_3A$ contents of 0.46, 5.97, 9.14, and 9.65 percent. The pastes were allowed to hydrate in sealed containers for 28days and then objected to pore solution expression. The expressed pore fluids were analyzed for chloride and hydroxyl ion concentrations. It was found that the free cholride concentration in the pore solution decreases significantly with an increase in the $C_3A$ content of the cement. With increasing level of chloride addition, although the alsolute amount of bound chloride increase, the ratio of bound to total chlorides decreases.

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A Study on the Measurement of Quantity of Light and Resolving Power of a Hand-made Lens (실험 렌즈의 광량과 해상력 측정)

  • 강현덕
    • Journal of the Korean Graphic Arts Communication Society
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    • v.14 no.1
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    • pp.89-114
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    • 1996
  • Liquid crystal-polymer composite(LCPC) films consisting of a continuous LC phase embedded in a three-dimensional network of polymer matrix are formed by photopolymerization-induced phase separ on. The LCPC films are switched from a light-scattering stats to a highly transparent stats on the application of electric fields. Since the alignment of LC molecular determines the electro-optical properties of films, the requirement for good contrast is to generate the nematic phase at high concentration. On the other hand, the concentration of UV-curable monomer must be increased above some critical value to from the flexible matrix of unbounded polymer. The mixing ratio of LC and UV-curable monomer affects the electro-optical and viscoelastic properties of LCPD films in two opposing ways. By controlling the phase separation process, at an LC fraction of 0.7, the maximum performance of LCPC films has been achieved, the response time of which is 2ms on the application of electric fields.

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Characterization of CNT-ink and fabrication of a cold cathode using jet-printing technique.

  • Lee, Dae-Sik;Lim, Seong-Chu;Lee, Young-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1532-1534
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    • 2008
  • Aquesous carbon nanotubes (CNTs) solutions were prepared using SDS (sodium dodecyl sulfonate) and NADDBS (sodium dodecylbenzene sulfonate). Our inks are found to have the viscosity of 1-2 cps. In addition, the surface tension of inks inversely decreased with increasing surfactant concentration and then saturated at critical micelle concentration (CMC). The low surface tension at CMC gave rise to lower contact angles on Indium layers, resulting in larger printable feature sizes. In the fabrication of cold cathode, jet-printing is feasible to modify and scale up the cathode structures. These feasibilities could contribute jet-printing method to be more adaptable for making large-area cold cathodes.

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