• 제목/요약/키워드: critical concentration

검색결과 1,321건 처리시간 0.026초

준설토의 침강형태에 관한 연구 (Settling Mode of the Dredged Soil)

  • 윤상묵;장병욱;차경섭
    • 한국농공학회지
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    • 제45권1호
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    • pp.63-73
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    • 2003
  • The settling of the dredged soil may vary with mineral composition, grain size distribution, initial water content and salt concentration of suspension of the site. A series of settling column test was performed to investigate the behaviour of solid suspension material from dredging and reclamation. Settling mode was divided into four types from the observation of interface and settling curves of clay minerals and marine clay samples, and the relationship charts of salt concentration and the initial water content were established to use in the dredging operation with any salt concentration. The critical initial water content which was defined as a threshold of zone settling and the consolidation settling was varied with salt concentration of water and was proportional to the plasticity of soil in sea water.

${\alpha}$-아미노카프르산의 Micelle 형성을 위한 한계농도에 관하여 (On the Micellization of ${\alpha}$-Amino Capric Acid)

  • 유지용;장세헌
    • 대한화학회지
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    • 제10권4호
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    • pp.161-165
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    • 1966
  • The critical concentrations of ${\alpha}$-amino capric acid for micelle formation have been determined by the surface tension measurements in both acidic and alkaline solutions, and also by the dye titration using Rhodamine B in alkaline solutions. The critical micelle concentrations obtained by the two methods show the good agreements within experimental errors. Since ${\alpha}$-amino acid is an ampholyte, it may aggregate to form the micelles in both more acidic and basic media than its isoelectric point. It is found that the basic media are rather preferable for the micelle formation than the acidic media. The effect of gegen ions upon the critical concentration for micelle formation in alkaline media is similar to that expected from the salt effect on the CMC (Critical Micelle Concentration).

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침지형 분리막 여과공정에서 운전조건에 따른 임계플럭스에 대한 연구 (Effects of Operation Parameters on Critical Flux During Submerged-Type Membrane Filtration System)

  • 김준성;안규홍
    • 상하수도학회지
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    • 제16권6호
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    • pp.717-725
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    • 2002
  • A bench-scale submerged-type membrane filtration system (SMFS) was constructed to study a feasibility of membrane filtration for solid-liquid separation in water and wastewater treatment processes. In the case of applying the SMFS to a biological wastewater treatment process, so-called membrane bioreactor, aeration underneath membrane modules is usually employed in order to provide oxygen demand for microbial growth as well as to control membrane fouling. A study was investigated the effects of operation parameters by aeration intensity, feed concentration, foulant type and airlift pore size on critical flux. Critical flux tends to increase with aeration rate. Optimal aeration flow rate was found to be 10 L/min/module. Feed concentration and foulant type has a significant effect on membrane fouling and filtration performance. But downward position and pore size of airlift has no a significant effects on membrane fouling and filtration performance.

Dodecylpyridinium Chloride의 micelle 形成의 熱力學變數 (Thermodynamic Parameters for Micelle Formation of Dodecylpyridinium Chloride)

  • 한만운
    • 대한화학회지
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    • 제10권2호
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    • pp.103-108
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    • 1966
  • The effect of temperature on the critical micelle concentration of dodecylpyridinium chloride has been determined by electrical conductance method over the range from $5^{\circ}C\;to\;50^{\circ}C$. The values of the change in heat content, ${\Delta}H_m$, and the other thermodynamic parameters have been estimated using the equation of temperature dependence on the critical micelle concentration for the same temperature range. The significance of these thermodynamic quantities and their relations to the various current theories of micelle forming processes were discussed.

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界面活性劑 Hexadecyl Trimethyl Ammonium Bromide의 C. M. C. 의 溫度效果 (The Effect of Temperature on the Critical Micelle Concentration of Hexadecyl Trimethyl Ammonium Bromide)

  • 이근무
    • 대한화학회지
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    • 제13권1호
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    • pp.1-4
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    • 1969
  • Temperature effect on the critical micelle concentration of hexadecyl trimetyl ammonium bromide over the range of $2^{\circ}-50^{\circ}C$ has been investigated by the method of electrical conductivity. The values obtained have been formulated as a power series in T. Several thermodynamic parameters have been calculated for the temparature range examined and their values have been discussed in the light of current theories on the participation of solvent in micelle formation.

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POSITIVE SOLUTION AND GROUND STATE SOLUTION FOR A KIRCHHOFF TYPE EQUATION WITH CRITICAL GROWTH

  • Chen, Caixia;Qian, Aixia
    • 대한수학회보
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    • 제59권4호
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    • pp.961-977
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    • 2022
  • In this paper, we consider the following Kirchhoff type equation on the whole space $$\{-(a+b{\displaystyle\smashmargin{2}{\int\nolimits_{{\mathbb{R}}^3}}}\;{\mid}{\nabla}u{\mid}^2dx){\Delta}u=u^5+{\lambda}k(x)g(u),\;x{\in}{\mathbb{R}}^3,\\u{\in}{\mathcal{D}}^{1,2}({\mathbb{R}}^3),$$ where λ > 0 is a real number and k, g satisfy some conditions. We mainly investigate the existence of ground state solution via variational method and concentration-compactness principle.

아세탈형(型) 비(非)이온성(性) 계면활성제(界面活性劑)의 점탄성(粘彈性)에 관한 연구(硏究) (Studies on the Viscoelasticities of Acetal Type Nonionic Surfactants)

  • 손주환;이승렬;남기대;김유배
    • 한국응용과학기술학회지
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    • 제5권1호
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    • pp.53-62
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    • 1988
  • Properties of aqueous solution, that is, the viscosities and solubilities of benzene were observed in relation to critical micelle concentration of each alkyl aldehyde polyoxyethylene glycol acetal type surfactant. These showed that the mininum points in specific viscosity/concentration-concentration curves were corresponded with the critical micelle concentration obtained by surface tension and appeared the remarkable increase of non-Newtonics according to the increase of the number of carbon in hydrophobic groups. The fluidity of non-Newtonics is not observed by a little increase of the degree of polymerization in polyoxyethylene glycol groups.

질산칼슘 처리 농도에 따른 수축견사의 구조특성 (Structural Characterization of Silk Fiber Treated with Calcium Nitrate)

  • 이광길;이용우
    • 한국잠사곤충학회지
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    • 제39권2호
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    • pp.186-196
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    • 1997
  • The IR crystallinity index of Calcium nitrate treated silk fiber decreased proportionally to the concentration of calcium nitrate. A partial change of conformation was observed in the concentration of over 46.4-47.6% changing from $\beta$-sheet or to random coil in the crystalline region. This is in coincidence with the result of crystallinity index, which was started to be reduced in the concentration range of 46.4-47.6%. A same trend was observed for the X-ray order factor, birefringence, degree of orientation and surface structure. These structural parameters were remarkably changed on the treatment of silk fibers with concentration of 46.4-17, 6% calcium nitrate. Therefore, it seems that there exists a critical concentration of calcium nitrate in affection the structure and morphology of silk fibers. According to the examination of surface morphology, the fine stripe was observed in the direction of fiber axis at 46.4% concentration. However, the treated concentration was exceeded by 47.6%, the cracks were appeared severely on the fiber surface in the transverse direction as well as fiber axis direction. This result might be related to the tensile properties, specially a tenacity of silk fibers. As a result of quantitative analysis of a dilute acid hydrolysis, three different regions, which are known as a amorphous, semi-crystalline and crystalline region, could be obtained. The hydrolysis rate curves were different with various concentrations of treatment and the relative contents of each region could be calculated.

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계면활성제 특성에 따른 나노입자 분산안정도 향상 연구 (The Effects of the Surfactant Type on the Nanofluids Stability)

  • 강치훈;홍성욱;강용태;구준모
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2008년도 동계학술발표대회 논문집
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    • pp.275-280
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    • 2008
  • The effects of the surfactant type, i.e., CTAB(cationic), SDS(anionic), and GA(polymeric), on the stability of 0.1 vol.% $Al_2O_3$ nanofluids were investigated. The changes in size and zeta potential of nanoparticles in nanofluids with pH, surfactant concentration, and time were experimentally observed. The nanofluids adding CTAB, which ionizes of the same charge with the bare particle surface, was found to have the best stability regardless of the surfactant concentration, whereas those with SDS became unstable under low surfactant concentration conditions, i.e. lower than the critical micellel concentration(CMC), before the charge reversal occurred. With higher SDS concentration over CMC, they became stable. Gum Arabic, which had been used often to stabilize the nanofluids, was also tested. In result, it was found that the type and concentration of surfactants to add should be selected considering pH and the sign of the bare particle surface charge.

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Fatty alcohol을 이용한 음이온 술폰산계 계면활성제의 합성 및 물성 (Synthesis and Properties of Anionic Sulfonate Surfactants Using Fatty Alcohol)

  • 조정은;신혜린;정노희
    • 한국응용과학기술학회지
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    • 제35권3호
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    • pp.579-586
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    • 2018
  • 본 연구에서는 지방 알코올을 이용하여 탄소 길이에 따른 술폰산계 음이온 계면활성제를 합성하였으며, 합성한 계면활성제들의 구조를 FT-IR과 $^1H$ NMR 분석을 통하여 확인하였다. 음이온 계면활성제의 임계미셀농도(critical micelle concentration: cmc)는 $10^{-5}{\sim}10^{-3}mol/L$이며, 임계미셀농도에서의 표면장력 값은 26~32 mN/m이었다. 합성한 술폰산계 계면활성제의 분자당 최소 영역값은 $1.68{\sim}1.30nm^2$이다. 음이온 계면활성제의 분자당 최소 영역이 감소하였다. 합성한 계면활성제의 물성은 임계 미셀농도, 기포력, 유화력, 접촉각을 측정하였다.