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http://dx.doi.org/10.12925/jkocs.2018.35.3.579

Synthesis and Properties of Anionic Sulfonate Surfactants Using Fatty Alcohol  

Cho, Jung-Eun (Dept. of Engineering Chemistry, Chungbuk National University)
Shin, Hye-Lin (Dept. of Engineering Chemistry, Chungbuk National University)
Jeong, Noh-Hee (Dept. of Engineering Chemistry, Chungbuk National University)
Publication Information
Journal of the Korean Applied Science and Technology / v.35, no.3, 2018 , pp. 579-586 More about this Journal
Abstract
In this study, surfactants were synthesized using fatty alcohols of 8, 10, 12 and 14 carbon chains length. The structures of the synthesized surfactants was confirmed by FT-IR and $^1H$-NMR analysis. The surface tension of the diluted surfactant was measured as 26~32 mN/m depending on the carbon length and the critical micelle concentration was measured as $10^{-3}{\sim}10^{-5}mol/L$.The minimum value per molecule of the synthesized sulfonic acid surfactant is 1.68 to $1.30nm^2$. The physical properties of the synthesized surfactants were determined by measuring the critical micelle concentration, foaming power, emulsifying stability, and contact angle.
Keywords
Fatty alcohol; Anionic surfactant; Critical micelle concentration; Foaming property; Emulsion stability;
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1 J.S. Park, J.C. Lim, "Inverstigation on a zwitterionic surfactant having ethylene oxide", Appl. Chem. Eng., Vol.10, No.2 pp. 605-608, (2006).
2 R. Yao, J. Qian, H. Li, A. Yasin, Y. Xieb, H. Yang, "Synthesis and high-performance of a new sarcosinate anionic surfactant with a long unsaturated tail". RSC Adv., Vol.4, pp. 2865-2872 (2014).   DOI
3 N.H Jeong, S.S. Park, H.K. Jeong, K.H. Cho, K.D. Nam, "The synthesis of anionic oligomer surfactant with ${\alpha}$-sulfo alkanoic acid", J. of Korean Ind. & Eng. Chemistry., Vol.4, No.2 pp. 381-392 (1993).
4 Y. Jin, S. Tian, J. Guo, X. Ren, X. Li , S. Gao . "Synthesis, characterization and exploratory application of anionic surfactant fatty acid methyl ester sulfonate from waste cooking oil". J Surfactants Deterg. Vol.19, pp. 467-475 (2016).   DOI
5 Cserhati T, Forgacs E, Oros G. "Biological activity and environmental impact of anionic surfactants". Environment International. Vol.28, No.5 pp. 337-348 (2002).   DOI
6 S. Lee, B.J. Kim, J.G. Lee, J.C. Lim, "Synthesis and Characterization of Interfacal Properties of sorbitan Laurate surfactant", Appl. Chem. Eng., Vol.22, No.1 pp. 37-44 (2011).
7 Matthew J. Scott, Malcolm N. Jones, "The biodegradation of surfactants in the environment", Biochimica et Biophysica Acta., Vol.1508, No.1 pp. 235-251 (2000).   DOI
8 D.H. Kim, S.K. Chang, S.W. Park, "Surfactants", J Anal Sci Technol., Vol.13, No.2 pp. 27-48 (2000).
9 J.C. Lim, B.J. Kim, K.Y. Choi, "A study on synthesis of glycidol based nonionic surfactant", Korean Chem. Eng. Res., Vol.50, No.2 pp. 282-291 (2012).   DOI
10 Geng T, Zhang C, Jiang Y, Ju H, Wang Y, "Synergistic effect of binary mixtures contained newly cationic surfactant: Interaction, aggregation behaviors and application properties", J. Mol. Liq., Vol.232, pp. 36-44 (2017).   DOI
11 Rybinski W, Hill K, "Alkyl polyglycosides-properties and applications of a new class of surfactants". Angew Chem Int Ed., Vol.37, pp. 1328-1345 (1998).   DOI
12 Raney KH, "Optimization of nonionic/anionic surfactant blends for enhanced oily soil removal". J Am Oil Chem Soc., Vol.68, No.7 pp. 525-531 (1991).   DOI
13 KS M ISO 696, Surface active agents measurement of foaming power modified Ross-Miles method (2008).
14 H.C. Kang, B.M. Lee, J.H. Yoon, M.J. Yoon, "Synthesis and surface-active properties of new photosensitive surfactants containing the azobenzene group". J Colloid Interface Sci., Vol.231, No.2 pp. 255-264 (2000).   DOI
15 M. Zhou, J. Zhao, X. Wang, J. Jing, L. Zhou, "Synthesis and characterization of novel surfactants 1,2,3-tri(2-oxypropylsulfonate-3-alkylether-propoxy) propanes". J Surfactants Deterg., Vol.16, pp. 665-672 (2013).   DOI
16 M.M. El-Shahawi, A.A.S. Shalaby, A.M.E.D. Gabre, A.E.H.M. Ghonim, "Surface active properties and biological activities of novel anionic surfactant based on oxapyridazinone derivatives". J. Surfactants Deterg., Vol.19, pp. 137-144 (2016).   DOI