• 제목/요약/키워드: critical concentration

검색결과 1,321건 처리시간 0.029초

Pool boiling heat transfer of a copper microporous coating in borated water

  • Jun, Seongchul;Godinez, Juan C.;You, Seung M.;Kim, Hwan Yeol
    • Nuclear Engineering and Technology
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    • 제52권9호
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    • pp.1939-1944
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    • 2020
  • Pool boiling heat transfer of a copper microporous coating was experimentally studied in borated water with a concentration of boric acid from 0.0 to 5.0 vol percent (vol%) to determine the effect of boric acid on boiling heat transfer in water. A high-temperature, thermally conductive microporous coating (HTCMC) was created by sintering copper powder with an average particle size of 67 ㎛ onto a 1 cm × 1 cm plain copper surface with a coating thickness of ~300 ㎛ within a furnace in a vacuum environment. The tests showed that the nucleate boiling heat transfer coefficient (NBHT) of HTCMC became slightly less enhanced as the concentration of boric acid increased but the NBHT coefficient values were still significantly higher than those of the plain surface. The critical heat flux (CHF) values from 0 to 1.0 vol% were maintained at ~2,000 kW/㎡, and then, they gradually decreased down to ~1,700 kW/㎡ as the concentration increased further to 5.0 vol%. It is believed that the micro-scale pores of the HTCMC were partially blocked by the high boric acid concentration during the nucleate boiling such that the small bubbles were not effectively created using the HTCMC reentrant cavities as the boric acid concentration increased.

Meteorological Field Generation Method for CALPUFF Model

  • Park, Ji-Hoon;Park, Geun-Yeong
    • 통합자연과학논문집
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    • 제11권1호
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    • pp.30-38
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    • 2018
  • CALPUFF is one of the recommended air pollution models by EPA with AERMOD. It has been used to simulate the ambient concentration of critical air pollutants as well as non-critical pollutants such as persistent organic matters and the organic materials causing odor. In this model, the air pollutants go through dispersion, transportation, chemical reaction, and deposition process. These mechanisms are significantly influenced by meteorological condition. This study produces the meteorological field in three different methods for the simulation of $SO_2$ using CALPUFF: 1) CALMET model by using both ground-level and aerological observation, 2) CALMET model by using MM5 results with NCEP/NCAR reanalyzed data, 3) CALMET model by using MM5 results in which FDDA is applied with NCEP/NCAR reanalyzed data as well as the meteorological data of Korea Meteorological Administration. As a result of CALPUFF model, the resolved concentration of $SO_2$ showed different behaviors in three cases. For the first case, the fluctuation of SO2 concentration was frequently observed while the fluctuation is reduced in the second and third cases. In addition, the maximum concentration of $SO_2$ in the first case was about 2~3 times higher than the second case, and about 4~6 times higher than the third case. These results can be caused by the accuracy of the resolved meteorological field. It is inferred that the meteorological field of the first case could be less accurate than other two cases. These results show that the use of correct meteorological data can improve the result of dispersion model. Moreover, the contribution of various sources such as point, line, and area sources on the ambient concentration of air pollutant can be roughly estimated from the sensitivity analysis.

폴리에틸렌옥사이드 수용액의 동적 점탄성 (Dynamic Viscoelastic Properties of Aqueous Poly(Ethylene Oxide) Solutions)

  • 송기원;배준웅;장갑식;노동현;박영훈;이치호
    • Journal of Pharmaceutical Investigation
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    • 제29권4호
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    • pp.295-307
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    • 1999
  • Using a Rheometries Fluids Spectrometer (RFS II), the dynamic viscoelastic properties of aqueous poly(ethylene oxide) (PEO) solutions in small amplitude oscillatory shear flow fields have been measured over a wide range of angular frequencies. The angular frequency dependence of the storage and loss moduli at various molecular weights and concentrations was reported in detail, and the result was interpreted using the concept of a Deborah number De. In addition, the experimentally determined critical angular frequency at which the storage and loss moduli become equivalent was compared with the calculated characteristic time (or its inverse value), and their physical significance in analyzing the dynamic viscoelastic behavior was discussed. Finally, the relationship between steady shear flow and dynamic viscoelstic properties was examined by evaluating the applicability of some proposed models that describe the correlations between steady flow viscosity and dynamic viscosity, dynamic fluidity, and complex viscosity. Main results obtained from this study can be summarized as follows: (1) At lower angular frequencies where De<1, the loss modulus is larger than the storage modulus. However, such a relation between the two moduli is reversed at higher angular frequencies where De>l, indicating that the elastic behavior becomes dominant to the viscous behavior at frequency range higher than a critical angular frequency. (2) A critical angular frequency is decreased as an increase in concentration and/or molecular weight. Both the viscous and elastic properties show a stronger dependence on the molecular weight than on the concentration. (3) A characteristic time is increased with increasing concentration and/or molecular weight. The power-law relationship holds between the inverse value of a characteristic time and a critical angular frequency. (4) Among the previously proposed models, the Cox-Merz rule implying the equivalence between the steady flow viscosity and the magnitude of the complex viscosity has the best validity. The Osaki relation can be regarded to some extent as a suitable model. However, the DeWitt, Pao and HusebyBlyler models are not applicable to describe the correlations between steady shear flow and dynamic viscoelastic properties.

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해송의 생육을 저해하는 Ca/Al 및 Mg/Al의 한계 비율 (Critical Ratios of Ca/Al and Mg/Al in Nutrent Solution Limiting Growth of Pinus thunbergii)

  • 이위영;양재의;박창진;장용선;옥용식
    • 한국토양비료학회지
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    • 제37권5호
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    • pp.329-335
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    • 2004
  • Acid deposition in forest adjacent to the industrial complexes causes soil acidification resulting in the leaching of cations, decreases of buffering capacity and increases of toxic metal concentrations such as Al, Fe, Mn and Cu in soil solution. Changes of nutrient availability equilibria by acid deposition have been known to retard the growth of pine trees. Objective of this research was to assess the critical ratios of Ca/Al and Mg/Al limiting the growth of Pinus thunbergii in the hydroponic culture. The Ca concentration and Ca/Al ratio in stalks of pine tree were increased as increasing Ca/Al molar ratio in the nutrient solution, but were not changed when the Ca/Al molar ratio was adjusted to greater than 1. Growth of Pinus thunbergii was inhibited at the Ca/Al molar ratio lower than l due to the Ca deficiency. The molar ratios of Ca/Al in the needles of Pinus thunbergii showed the similar tendency with the stalks. This indicated that Ca/Al molar ratio of 1 in the growth media was the critical level limiting the growth of Pinus thunbergii. Concentration of Mg and Mg/Al molar ratios in the stalks of pine tree were increased as increasing Mg/Al molar ratio in nutrient solution. Molar ratios of Mg/Al in the needles were increased as increasing Mg/Al ratios in nutrient solution up to 0.83, which was the critical level limiting the growth of Pinus thunbergii.

폐 침윤을 동반한 급성 중증 환자의 기관지 폐포 세척액에서 측정한 Pre-B-Cell Colony-Enhancing Factor의 임상적 유용성 (Clinical Utility of Pre-B-Cell Colony-Enhancing Factor in Bronchoalveolar Lavage Fluid of Acute Critical Ill Patients with Lung Infiltrates)

  • 이광하;홍상범
    • Tuberculosis and Respiratory Diseases
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    • 제67권5호
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    • pp.402-408
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    • 2009
  • Background: Pre-B-cell colony enhancing factor (PBEF) has been suggested as a novel biomarker in sepsis and acute lung injury. We measured the PBEF in bronchoalveolar lavage (BAL) fluid of acute critically ill patients with lung infiltrates in order to evaluate the clinical utility of measuring PBEF in BAL fluid. Methods: BAL fluid was collected by bronchoscope from 185 adult patients with lung infiltrates. An enzyme-linked immunosorbent assay was then performed on the collected fluids to measure the PBEF. Results: Mean patient age was 59.9 ${\pm}$14.5 years and 63.8% of patients were males. The mean concentration of PBEF in BAL fluid was 17.5 ${\pm}$88.3 ng/mL, and patients with more than 9 ng/mL of PBEF concentration (n=26, 14.1%) had higher Acute Physiology and Chronic Health Evaluation (APACHE) II and Sequential Organ Failure Assessment (SOFA) scores on the BAL exam day. However, there were no significant differences in clinical characteristics between survivors and non-survivors. In patients with leukocytosis (n=93) seen on the BAL exam day, the linear regression analysis revealed a significant, positive relationship between PBEF and APACHE II ($r^2$=0.06), SOFA score ($r^2$=0.08), Clinical Pulmonary Infection Score ($r^2$=0.05), and plateau pressure in patients on ventilators ($r^2$=0.07) (p<0.05, respectively). In addition, multivariate regression analysis with PBEF as a dependent variable showed that the plateau pressure ($r^2$=0.177, p<0.05) was correlated positively with PBEF. Conclusion: The PBEF level in the BAL fluid may be a useful, new biomarker for predicting the severity of illness and ventilator-induced lung injury in critically ill patients with lung infiltates and leukocytosis.

Unusual Non-magnetic Metallic State in Narrow Silicon Carbon Nanoribbons by Electron or Hole Doping

  • Lou, Ping;Lee, Jin-Yong
    • Bulletin of the Korean Chemical Society
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    • 제33권3호
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    • pp.763-769
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    • 2012
  • We investigated the width (N) dependence on the magnetization of N-ZSiC NR with electron and hole doping on the basis of systematic DFT calculations. The critical values of the upper and down critical concentration to give the maximum and zero magnetic moment at edge Si/C atoms by electron/hole doping ($x_{up,e}$, $x_{down,e}$, $x_{up,h}$, and $x_{down,h}$) depend on the width of N-ZSiC NR. Moreover, due to $x_{up,e}\;{\neq}\;x_{up,h}$ and $x_{down,e}\;{\neq}\;x_{down,h}$, the electron and hole doping effect are asymmetry, i.e, the critical electron doping value ($x_{down,e}$) is smaller than the critical hole doping value ($x_{down,h}$) and is almost independent of the width of NZSiC NR though the other critical values of the electron and hole doping that influence the magnetization of N-ZSiC NR depend on the width. It was also found that at $x_{down,e}$ or $x_{down,h}$ doping, the N-ZSiC NR turns into unusual non-magnetic metallic state. The magnetic behavior was discussed based on the band structures and projected density of states (PDOS) under the effect of electron/hole doping.

화재진압시간에 따른 콘크리트의 염해저항성 평가 (Evaluation of Salt Damage Resistance of Concrete according to Fire Control Time)

  • 이준해;박동천
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2020년도 봄 학술논문 발표대회
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    • pp.109-110
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    • 2020
  • In the event of a fire, fire engines usually arrive within 15 minutes and become a fire suppressor. In this paper, an analytical model was established to evaluate the salt damage resistance of concrete according to fire suppression time, and the concentration of salt inside the concrete after fire was measured and the time to reach the critical concentration was assessed by how short.

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Biological Aerated Filter에서 유입 질소농도에 따른 아질산화 특성 (Nitritation Characteristics Depending on Influent Nitrogen Concentration in a Biological Aerated Filter)

  • 유익근
    • 한국물환경학회지
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    • 제30권1호
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    • pp.1-7
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    • 2014
  • The purpose of this study was to investigate the nitrification characteristics of biological aerated filter (BAF) packed with ceramic media, especially focusing on nitrite build-up during nitrification. When increasing the nitrogen load above $1.63kgNH_4{^+}-N/m^3{\cdot}d$, ammonium removal efficiency decreased to less than 60% and the nitrite ratio ($NO_2{^-}-N/NO_x-N$) of higher than 75% was achieved due to the inhibitory free ammonia (FA, $NH_3-N$) concentration and oxygen limitation. FA inhibition, however, is not recommended strategy to promote nitrite build-up since FA concentration in the reactor is coupled with decreased ammonium removal efficiency. Nitrite ratio in the effluent was also affected by aeration rate and influent ammonium concentration. Ammonium oxidation was enhanced at a higher aeration rate regardless of influent ammonium concentration but, the nitrite ratio was dependent on both aeration rate and influent ammonium concentration. While a higher nitrite ratio was obtained when BAFs were fed with $50mgNH_4{^+}-N/L$ of influent, the nitrite ratio significantly decreased for a greater influent concentration of $200-300mgNH_4{^+}-N/L$. Taken together, aeration rate, influent ammonium concentration and FA concentrations kept in the BAF were found to be critical variables for nitrite accumulation in the BAF system.

Diagnostic Value of Interleukin 21 and Carcinoembryonic Antigen Levels in Malignant Pleural Effusions

  • Bunjhoo, Hansvin;Wang, Zheng-Yun;Chen, Hui-Long;Cheng, Sheng;Xiong, Wei-Ning;Xu, Yong-Jian;Cao, Yong
    • Asian Pacific Journal of Cancer Prevention
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    • 제13권7호
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    • pp.3495-3499
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    • 2012
  • The aim of this study was to evaluate the diagnostic value of interleukin 21(IL-21) and carcinoembryonic antigen (CEA) in tuberculous pleural effusions (TPEs) and malignant pleural effusions (MPEs). Pleural effusion samples from 103 patients were classified on the basis of diagnosis as TPE (n=51) and MPE (n=52). The concentration of IL-21 was determined by ELISA. Lactate dehydrogenase (LDH), adenosine dehydrogenase (ADA) and CEA levels were also determined in all patients. A significant difference was observed in the levels of ADA and CEA (P<0.01), but not in the levels of LDH (P>0.05) between TPE and MPE. The concentration of IL-21 in MPE was significantly higher compared to TPE (P<0.01). With a threshold value of 4.32 pg/ml, IL-21 had a sensitivity of 76.9% (40/52) and a specificity of 80.4% (41/51). Combined detection of IL-21 and CEA had a sensitivity of 69.2% (36/52) and a specificity of 92.2% (47/51). These two markers can contribute to the differential diagnosis of MPEs.

설계홍수량 산정에 따른 임계지속시간의 적용성에 관한 연구 (A Study on the application of Critical Rainfall Duration for the Estimation of Design Flood)

  • 장성모;강인주;이은태
    • 한국습지학회지
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    • 제6권3호
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    • pp.119-126
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    • 2004
  • 임계지속시간의 산정은 유효우량 산정과 단위 유량도 및 강우분포를 이용한 유출모형 그리고 도달 시간등을 고려하여 산정하도록 되어 있으나 기저유출에 대한 자료가 절대적으로 부족하여 SCS 유효우량 선정법과 빈도 분석을 통한 확률강우량과 단위도법을 이용한 방법을 사용하고 있다. 최근의 수문실무에 있어서 설계홍수량의 산정에 있어서 임계지속시간의 개념이 사용되고 있으나 명확한 기준이 없어 무작위적으로 사용되고 있는 실정이다. 따라서 본 연구는 치수목적의 설계홍수량 산정에 있어서 여러 가지 수문학적인 인자에 따른 임계지속시간의 변화를 파악하여 적용성을 알아보고 이에 맞는 회귀식을 산출하여 수문인자에 따른 편차를 정량화하여 실무의 수문설계에 적용이 용이하도록 하는데 목적이 있다. 본 연구에서 유역특성인자와 CN값 산정에는 GIS프로그램인 ArcView를 이용하여 산출하였으며 유출계산은 WMS Model에서 제공하는 HEC-1 Module을 이용하여 본 연구를 시행하였다. 또한 확률강우량의 재현기간, 강우의 시간적 분포특성, 유역의 토양 및 토지이용 특성과 도달시간의 변화에 따른 임계지속시간의 변동 추이를 살펴보고 이를 정량적으로 분석하여 각 인자간의 상관관계를 알아보았다. 그 결과를 살펴보면 형상계수, 유역평균고도, CN값은 첨두 유출량 및 임계지속시간 산정에 있어 그다지 큰 영향을 미치지 못하는 것으로 나타났으며 유역면적, 유역경사, 하천연장에 큰 영향을 받는 것으로 나타났다. 상관계수의 산정결과 재현기간과 강우분포에 대해서는 첨두 홍수량이, 도달시간과 선행토양함수조건에 대해서는 임계지속시간이 좀 더 영향을 받는 것으로 나타났다.

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