• Title/Summary/Keyword: critical association concentration

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A Study on the Sediment Deposition Height Computation at Gunsan Port Using EFDC (EFDC를 이용한 군산항의 유사 퇴적고 계산에 관한 연구)

  • Lee, Dong Joo;Park, Young Ki
    • Journal of Korea Water Resources Association
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    • v.46 no.5
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    • pp.531-545
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    • 2013
  • This paper was considered on the applicability of EFDC KUNSAN_SEDTRAN MODEL (2012) to calculate Gunsan Port sediment deposition height efficiently and to use for grasping its aspects quantitatively and providing its prevention measures reasonably based on well-known 3-dimensional EFDC sediment transport module. This model was calibrated and verified with various measured field data of A Report of Hydrological Variation on Kum River Estuary (2004). Due to the model calibration and relevant literature investigation for cohesive sediment parameters, settling velocity (WS), critical deposition stress (TD), reference surface erosion rate (RSE), critical erosion stress (TE) were identified as 2.2E-04m/s, 0.20 $N/m^2$, 0.003 $g/s{\cdot}m^2$, 0.40 $N/m^2$ respectivly on this model. In order to examine the applicability and precision of the model computation, the calculated model data of sediment deposition height at 13 stations for 71 days and suspended-sediment concentration at 2 stations, inner port and outer port for 15 days were compared and analyzed with the measured field data. As a result, the model applicability for sediment deposition height simulation was evaluated as NSE coefficient 0.86 and the precision for suspended-sediment concentration computation was evaluated as time averaged relative error (RE) 23%.

Two Paths of Korea's Clustering: Centralized De-concentration and Regionalized Concentration

  • Lee, Shi-Chul
    • World Technopolis Review
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    • v.1 no.2
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    • pp.129-140
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    • 2012
  • This paper presents, from a broad perspective, the manner in which various types of clusters and options for regional development have evolved in Korea over the past decade, with particular emphasis on who have taken initiative in establishing the clusters. Characterized by not only progress but also setbacks, two distinctive patterns have emerged: centralized de-concentration and regionalized concentration. Both the Korean government and numerous localities have continuously extended efforts to create different clusters, technology parks, special districts, etc. In many cases, local or regional governments have competed intensely for clusters to be located in their jurisdictions; in particular, concerted efforts to convince national governments to set up special districts have been witnessed. On the other hand, major localities have made their own efforts to generate large- and small-scale clustering projects. It remains to be seen how different outcomes or effectiveness these two approaches will make in the future. Following the review of relevant literature and practices, I examine the well-known national campaign and projects in the previous administration in Korea in the context of 'de-concentration' of economic values and resources. Thereafter, other cases initiated mostly by local governments are discussed; some of these clustering efforts and regional projects have fared well thus far, but some haven't. In the case of Daegu, the progress of some critical projects, such as the Daegu Technopolis and a Free Economic Zone, is elaborated.

Effectiveness of critical velocity method for evacuation environment in a railroad tunnel at fire situation (철도터널 내 화재 시 대피환경 확보를 위한 임계속도 산정식의 유효성 평가)

  • Lee, Seung-Chul;Lee, Jae-Heon;Lee, Seung-Ho
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.6 no.1
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    • pp.51-59
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    • 2004
  • The effectiveness of one dimensional critical velocity method for evacuation environment at 10MW fire size in a railroad tunnel have been investigated in this paper by three dimensional CFD method. It was performed to evaluate the evacuation environment in terms of temperature distribution, visible distance distribution and CO concentration at some tunnel inlet velocity, 1m/s, 2m/s (near critical velocity), and 3m/s. At all inlet velocity, passenger should give away downward the flow direction because the inlet velocity can not afford to sufficient evacuation environment for passengers. In case of 3m/s inlet velocity, however, the evacuation environment for passengers is better than the other cases. To provide more safe evacuation environment on fire situation, tunnel inlet velocity should be larger than critical velocity.

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The effect of grid number and the location and size of the fire source on the critical velocity in a road tunnel fire (도로터널 임계풍속 산정에 격자개수 및 화원의 크기와 위치가 미치는 영향)

  • Lee, Seung-Chul;Kim, Sang-Il
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.14 no.3
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    • pp.183-195
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    • 2012
  • This study conducted comparative analysis to estimate critical velocity in tunnel fire under variation of grid number and the location and size of the fire source using three-dimensional computational fluid dynamics. In the target tunnel, by one-dimensional way, the calculated critical velocity in the tunnel, 2.22 m/s was estimated, if appling hydraulic diameter, instead of the tunnel height. According to six numerical analysis, each grid number has different position, temperature, and CO concentration of back-layering. In the case of the subject, the case 1 with 0.84 million grid was found to be the most ideal. According to the location and size of the fire source, after three cases for three-dimensional numerical analysis was performed, it is resulted that the location and size of the fire source affect the critical velocity, because air velocity distribution, temperature distribution and CO concentration distribution showed different each case. This is due to the difference of heat exchange area and locations. Therefore, it is necessary to decide appropriate grid number, and the location and size of the fire source for processing techniques through comparison with actual experiment results and three-dimensional analysis.

Use of Undecorticated Sunflower Cake as a Critical Protein Supplement in Sheep and Goats Fed Wheat Straw

  • Dutta, Narayan;Sharma, K.;Naulia, Uma
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.6
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    • pp.834-837
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    • 2002
  • The effect of undecorticated sunflower cake (USFC) as critical protein supplement was assessed and compared with deoiled groundnut cake (DGNC) in adult goats and sheep. The animals were fed a basal diet of wheat straw ad libitum and supplemented with either USFC or DGNC to meet their protein requirement for maintenance. Total dry-matter intake by sheep and goats (g/kg $BW^{0.75}$) on USFC was similar to their counterparts on DGNC supplemented group. However, while intake of cake moiety was significantly (p<0.05) higher in USFC, the intake of wheat straw was significantly (p<0.05) higher by animals on DGNC. Digestibility of various nutrients, except lower crude protein digestibility by goats in USFC group, did not differ significantly between animals given DGNC or USFC. DCP and TDN concentration (% DM) was comparable in sheep and goats irrespective of dietary supplement. Similarly, the intake (g/kg $W^{0.75}$) of DCP, DDM, DOM, and TDN was similar between DGNC and USFC in both sheep and goats. It may be concluded that undecorticated sunflower cake is comparable to deoiled groundnut cake as a critical protein supplement to the roughage based diet of small ruminants.

Facile synthesis and characteristics of monodispersed ZnGa2O4 microsphere via solvothermal method (용매열합성법을 통한 단분산된 ZnGa2O4 구형 입자의 제조 및 특성)

  • Woo, Moo Hyun;Kang, Bong Kyun;Yoon, Dae Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.3
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    • pp.109-114
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    • 2016
  • Monodispersed $ZnGa_2O_4$ microspheres were synthesized by a facile two-step process consisting of a solvothermal method and calcination process. The prepared monodispersed $ZnGa_2O_4$ microspheres were aggregated into 3D microstructures by self-assembly with a large number of small $ZnGa_2O_4$ particles generated in nucleation. This nucleation and self-assembly making hierarchical microstructures were depended on the concentration of PEG (polyethylene glycol) due to CAC (critical aggregation concentration) theory. And also we controlled the amount of zinc acetate to make pure $ZnGa_2O_4$ phase. Additionally, to fix the optimized calcination condition, sample was characterized by TG-DTA to prove the thermal property in the calcination process and by FT-IR to identify the changes of functional group bonding between each element of the $ZnGa_2O_4$ precursor and oxide calcined at $900^{\circ}C$ for 1 h.

A Study on the Critical Duration of Design Rainfall in Midsize Catchment (중규모 하천유역에서 설계강우의 임계지속기간에 관한 연구)

  • Park, Jong-Young;Shin, Chang-Dong;Lee, Jung-Sik
    • Journal of Korea Water Resources Association
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    • v.37 no.9
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    • pp.695-706
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    • 2004
  • This study is to propose the temporal pattern of design rainfall which causes maximum peak discharge, and to analyze the relation of catchment characteristics and critical durations for gauged midsize catchment. Hydrologic analysis has done over the 44 midsize catchments with 50-5,000$\textrm{km}^2$. The type of temporal pattern of design rainfall which causes maximum peak discharge has resulted in Huff's 4 quartile distribution method for effective rainfall(AMC III) The peak discharges of 24hr rainfall duration are similar to those of critical duration for 50-600$\textrm{km}^2$, and the peak discharges of 48hr rainfall duration are similar to those of critical duration for 600-5,000$\textrm{km}^2$. Therefore, if the proper rainfall intensity formula is selected, 24hr or 48hr rainfall duration may be regarded as the critical duration of midsize catchment. A simple regression equation is derived by using a catchment area and critical duration with high correlation for the case of effective rainfall(AMC III). Therefore, it can be used to determine the critical duration of ungauged catchment with 50-5,000$\textrm{km}^2$. Also, dimensionless regression equation is derived by using characteristic values of unit hydrograph.

A Numerical Model for Cohesive Suspended Load Movement (점착성 부유사 이동에 관한 수치모형)

  • 안수한;이상화
    • Water for future
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    • v.23 no.1
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    • pp.119-127
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    • 1990
  • The concentration of cohesive suspended sediment is determined by the circulation of water and the material dispersion. The equations of the two-dimensional, depth-integrated dispersive transport are the Reynolds equation, continuity equation, and advection-dispersion equation based on the Fick's law. A finite difference method has been applied to two models of circulation and dispersion transport. The circulation model is solved by the explicit scheme and the dispersion transport model is solved by multi-operational scheme. It is investigated wheter advective terms are included when the equation of circulation is applied to the model. For advection-dispersion equation, it was also investigated about variations of suspended sediment concentration with respect to the critical shear stresses.

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Amphiphilic graft copolymers: Effect of graft chain length and content on colloid gel

  • Nitta, Kyohei;Kimoto, Atsushi;Watanabe, Junji;Ikeda, Yoshiyuki
    • Biomaterials and Biomechanics in Bioengineering
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    • v.2 no.2
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    • pp.97-109
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    • 2015
  • A series of amphiphilic graft copolymers were synthesized by varying the number of graft chains and graft chain lengths. The polarity of the hydrophobic graft chain on the copolymers was varied their solution properties. The glass transition temperature of the copolymers was in the low-temperature region, because of the amorphous nature of poly (trimethylene carbonate) (PTMC). The surface morphology of the lyophilized colloid gel had a bundle structure, which was derived from the combination of poly(N-hydroxyethylacrylamide)( poly(HEAA)) and PTMC. The solution properties were evaluated using dynamic light scattering and fluorescence measurements. The particle size of the graft copolymers was about 30-300 nm. The graft copolymers with a higher number of repeating units attributed to the TMC (trimethylene carbonate) component and with a lower macromonomer ratio showed high thermal stability. The critical association concentration was estimated to be between $2.2{\times}10^{-3}$ and $8.9{\times}10^{-2}mg/mL$, using the pyrene-based fluorescence probe technique. These results showed that the hydrophobic chain of the graft copolymer having a long PTMC segment had a low polarity, dependent on the number of repeating units of TMC and the macromonomer composition ratio. These results demonstrated that a higher number of repeating units of TMC, with a lower macromonomer composition, was preferable for molecular encapsulation.

Synthesis and Solution Properties of Fluorinated Amphiphilic Polyacrylamide (불화계 양친매성 폴리아크릴아마이드의 합성과 용액거동)

  • Zhao, Fangyuan;Du, Kai;Yi, Zhuo;Du, Chao;Fang, Zhao;Mao, Bingquan
    • Polymer(Korea)
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    • v.39 no.3
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    • pp.403-411
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    • 2015
  • A series of hydrophobically associating fluorinated amphiphilic polyacrylamide copolymers with remarkably high heat resistance and salt tolerance were synthesized by free radical micellar copolymerization, using acrylamide (AM) and sodium 2-acrylamido-tetradecane sulfonate ($AMC_{14}S$) as amphiphilic monomers, and 2-(perfluorooctyl) ethyl acrylate (PFHEA) as hydrophobic monomer. The structure of the terpolymer was characterized by FTIR, $^1H$ NMR and $^{19}F$ NMR. The solution properties of the terpolymers were investigated in details, and the results showed that the terpolymer solution had strong intermolecular hydrophobic association as the concentration exceeded the critical association concentration 1.5 g/L. The terpolymer solution possessed high surface activity, viscoelasticity, excellent heat resistance, salt tolerance and shearing resistance. The viscosity retention rate of copolymer solution was as high as 59.9% under the condition of fresh wastewater, $85^{\circ}C$ and a 60-days aging test.