• Title/Summary/Keyword: crevice corrosion

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Mechanical characteristic of overhead transmission lines by forest fires (화염에 노출된 가공송전선의 기계적.재료적 특성 검토)

  • Kang, J.W.;Jang, T.I.;Kim, B.K.;Park, C.G.;Bang, H.K.
    • Proceedings of the KIEE Conference
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    • 2002.07a
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    • pp.339-341
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    • 2002
  • The remaining life of ACSR exposed to the atmosphere for a long period may rely on deterioration caused by environmental indices such as atmospheric corrosion, galvanic corrosion, crevice corrosion and fatigue corrosion. One of reduction of useful life in overhead transmission lines built on the ridge of mountain is often caused by forest fires. This paper deals with investigation of strength deterioration performance of ACSR due to fires through several testing and analyzing data for both tension load and material analysis. Test samples are ACSR $480[mm^2]$ conductors, which are artificially fired to regular durations. As a result, it can be verified that tension load of ACSR are reduced by increasing fro duration. Hence, it is obvious that ACSR due to forest fires may lead to mechanical deterioration.

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Evaluation of Electrochemical Corrosion Characteristics for Hot-Dip Aluminized 304 Stainless Steel in Seawater (알루미늄 용융 도금된 304 스테인리스강의 해수 내 전기화학적 부식 특성 평가)

  • Chong, Sang-Ok;Park, Il-Cho;Han, Min-Su;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.48 no.6
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    • pp.354-359
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    • 2015
  • Stainless steel has poor corrosion resistance in marine environment due to the breakdown of a passive film caused by chloride. It suffers electrochemical corrosion like pitting corrosion, crevice corrosion, and stress corrosion crack (SCC) in marine environment. In general, it indicates that the passive film of $Al_2O_3$ has better corrosion resistance than that of $Cr_2O_3$ in seawater. This paper investigated the damage behavior 304 stainless steel and hot-dip aluminized 304 stainless steel in seawater solution. Various electrochemical experiments were carried out including potential measurement, potentiodynaimic experiment, Tafel analysis and galvanostatic experiment. As a result of anodic polarization experiment, higher pitting damage depth was indicated at 304 stainless steel than hot-dip aluminized 304 stainless steel. In addition, relatively higher corrosion current density was shown at hot-dip aluminized stainless steel as a result of Tafel analysis.

Electrochemical Corrosion Damage Characteristics of Austenite Stainless Steel and Nickel Alloy with Various Seawater Concentrations (오스테나이트계 스테인리스강과 니켈합금의 해수 농도 변화에 따른 전기화학적 부식 손상 특성)

  • Heo, Ho-Seong;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.20 no.5
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    • pp.281-288
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    • 2021
  • Due to advancement of the industry, operation of a device in a harsh environment is increasing. Especially, the marine environment contains Cl- ions which causes localized corrosion such as pitting and crevice corrosion of stainless steel and various metals. In this study, electrochemical corrosion behaviors of austenitic stainless steel (STS 316L) and nickel alloy (Inconel 600) with different seawater concentrations (fresh water, seawater, mixed water) were investigated. The STS 316L and Inconel 600 were etched in 10% oxalic acid and composed of an austenitic phase. Results of Tafel analysis in seawater showed that STS 316L and Inconel 600 presented the highest corrosion current densities of 7.75 × 10-4 mA/cm2 and 1.11 × 10-4 mA/cm2 and the most negative pitting potentials of 0.94 V and 1.06 V, respectively. The maximum damage depths and surface damage ratio by pitting corrosion increased with chloride concentration. The STS 316L had higher PREN than Inconel 600. However, the surface damage and weight loss of Inconel 600 were superior to STS 316L. It was difficult to compare the pitting resistance of STS 316L based on Fe and Inconel 600 based on Ni with PREN simply.

Cause of Corrosion and Evaluation of Material Corrosion Resistance on Underground Heat Transport Facilities Connected to Manhole (맨홀과 연결된 지하 열수송설비의 부식 원인 및 재질 내식성 평가)

  • Song, M.J.;Choi, G.;Kim, W.C.;Lee, S.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.35 no.4
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    • pp.193-202
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    • 2022
  • Manholes and underground spaces are installed to manage the buried heat transport pipes of the district heating system, and the corrosion damage of the equipment placed in this space often occurs. The purpose of this work is to identify locations with a high risk of corrosion damage in the air vent and to establish preventive measures based on precise analysis via sampling of heat transport pipes and air vents that have been used for about 30 years. The residual thickness of the air vent decreased significantly by reaching ~1.1 mm in thickness, and locations of 60~70 mm away from a transport pipe were the most vulnerable to corrosion. The energy dispersive X-ray spectroscopy (EDS) analysis was performed in the corroded oxides, and it was found that chloride ion was contained in the corrosion products. Anodic polarization tests were carried out on the air vent materials (SPPS250, SS304) with varying the amounts of chloride ions at two different temperatures (RT, 80℃). The higher concentration of chloride ions and temperature are, the lower corrosion resistances of both alloys are.

Corrosion behaviors of 18Cr Stainless Steels in Selective Catalytic Reduction Environments (Selective Catalytic Reduction (SCR) 환경에서 18% 크롬 스테인리스강의 부식 거동)

  • Heesan Kim
    • Corrosion Science and Technology
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    • v.22 no.3
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    • pp.175-186
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    • 2023
  • Effects of high-temperature environment and low-temperature environment on corrosion behaviours of 18Cr stainless steels (type 304L, type 441) in simulated selective catalytic reduction (SCR) environments were studied using weight loss test in each environment and rust analysis. With time to exposure to the high-temperature environment, type 441 was more resistant to corrosion than type 304L due to both higher diffusivity of Cr and lower thermal expansion coefficient in α-iron. The former provides a stable protective Cr2O3 layer. The latter leaded to low residual stress between scale and steel, reducing the spallation of the scale. With time to exposure to the low-temperature environment, on the other hand, type 304L was more resistant to corrosion than type 441. The lower resistance of type 441 was caused by Cr-depleted zone with less than 11% formed during the pre-exposure to a high-temperature environment, unlike type 304L. It was confirmed by results from the crevice corrosion test of sensitised 11Cr steel. Hence, to achieve higher corrosion resistance in simulated SCR environments, ferritic stainless steels having lower thermal expansion coefficient and higher diffusivity of Cr but containing more than 18% Cr are recommended.

Study on Corrosion Resistance Enhancement in STS 304 through Electrochemical Polishing (전해연마를 이용한 STS 304의 부식방지 효과 연구)

  • JaeHwan Oh;WooHyuk Kim;HyeWon Cho;ByungKwan Park;SangHwa Yoon;Bongyoung Yoo
    • Journal of the Korean institute of surface engineering
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    • v.57 no.3
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    • pp.221-224
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    • 2024
  • The 304 stainless steel has good corrosion resistance, so it is used in various industries. However, in an environment like seawater, stainless steel can be damaged by chloride ions, resulting in surface corrosion such as pitting and crevice corrosion. Electropolishing is a technique that smooths the surface and creates a passivation layer that can resist corrosion. In this study, electropolishing was applied as a surface finish to increase the smoothness of the metal surface and its corrosion resistance. We confirmed the topology of the electropolished surface of stainless steel by optical microscope and evaluated the corrosion resistance characteristics of electropolished stainless steel through a potentiodynamic experiment.

Development of an Electromagnetic Nondestructive Testing Method for the Prevention of Defects in Steam Generator Tubes at Nuclear Power Plant (원자력발전소 증기발생기 전열관의 결함발생 예방을 위한 전자기 비파괴 검사방법 개발)

  • Shin, Young-Kil
    • Proceedings of the KIEE Conference
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    • 1996.07a
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    • pp.83-85
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    • 1996
  • Major cause of defects in steam generator tubes at nuclear power plant is the accumulation of magnetite and other byproducts of corrosion in the crevice gap between support plates and tubes. Since damaged tubes result in contamination of the secondary coolant by the radioactive primary coolant, they represent a safety hazard. Early detection of magnetite buildup is, therefore, imperative in order to take remedial measures such as chemical flushing. Although the eddy current testing is being used for the inspection of steam generator tubes, the interpretation of resulting signals is generally a difficult task. This paper uses the phase of sensor coil emf as the test signal to find a way of easier signal interpretation. Numerical study using FEM shows that the shape of resulting signal is good for identifying the relative position of the probe to the support plate, and for discreminating the different shapes and degrees of magnetite buildup in the crevice gap region.

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SCC Inhibitors for SG Tube Materials in Nuclear Power Plants

  • Kim, Kyung-Mo;Lee, Eun-Hee;Kim, Uh-Chul
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.585-586
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    • 2006
  • Several chemicals were studied to suppress the damage due to stress corrosion cracking (SCC) of steam generator (SG) tubes in nuclear power plants. The effects on the SCC of the compounds, $TiO_2$, TyzorLA and $CeB_6$, were tested for several types of SG tubing materials. The test with the addition of $TiO_2$ and $CeB_6$ showed an effect in decreasing the SCC for the SG tubing material. However, $CeB_6$ caused some more SCC for Alloy 800. The penetration property into a crevice of the inhibitors was investigated by using Alloy 600 specimens with different gap.

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HVOF Thermal Sprayed AISI316-WC Coating Layer on Stainless Steel for PEMFC Bipolar Plate (고분자 전해질 연료전지용 분리판으로서 스테인리스강에 HVOF 용사된 AISI316-WC 코팅층)

  • Nam, Dae-Geun
    • New & Renewable Energy
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    • v.4 no.1
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    • pp.31-36
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    • 2008
  • Stainless steels have been widely considered as metallic bipolar plates, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the bipolar plates and the electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

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Characteristic of HVOF AISI316-WC Coating Layer on Stainless Steel Separator for PEMFC (고분자 전해질 연료전지용 스테인리스강 분리판의 HVOF AISI316-WC 코팅층 특성)

  • Nam, Dae-Geun;Kang, Nam-Hyun;Park, Yeong-Do;Kim, Young-Seok
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.1-5
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    • 2008
  • Stainless steels have been widely considered as metallic separators, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the separators and electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

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