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Enhanced Electrical Properties of Light-emitting Electrochemical Cells Based on PEDOT:PSS incorporated Ruthenium(II) Complex as a Light-emitting layer

  • Gang, Yong-Su;Park, Seong-Hui;Lee, Hye-Hyeon;Jo, Yeong-Ran;Hwang, Jong-Won;Choe, Yeong-Seon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.139-139
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    • 2010
  • Ionic Transition Metal Complex based (iTMC) Light-emitting electrochemical cells (LEECs) have been drawn attention for cheap and easy-to-fabricate light-emitting device. LEEC is one of the promising candidate for next generation display and solid-state lighting applications which can cover the defects of current commercial OLEDs like complicated fabrication process and strong work-function dependent sturucture. We have investigated the performance characteristics of LEECs based on poly (3, 4-ethylenedioxythiophene):poly (styrene sulfonate) (PEDOT:PSS)-incorporated transition metal complex, which is tris(2, 2'-bipyridyl)ruthenium(II) hexafluorophosphate in this study. There are advantages using conductive polymer-incorporated luminous layer to prevent light disturbance and absorbance while light-emitting process between light-emitting layer and transparent electrode like ITO. The devices were fabricated as sandwiched structure and light-emitting layer was deposited approximately 40nm thickness by spin coating and aluminum electrode was deposited using thermal evaporation process under the vacuum condition (10-3Pa). Current density and light intensity were measured using optical spectrometer, and surface morphology changes of the luminous layer were observed using XRD and AFM varying contents of PEDOT:PSS in the Ruthenium(II) complex solution. To observe enhanced ionic conductivity of PEDOT:PSS and luminous layer, space-charge-limited-currents model was introduced and it showed that the performances and stability of LEECs were improved. Main discussions are the followings. First, relationship between film thickness and performance characteristics of device was considered. Secondly, light-emitting behavior when PEDOT:PSS layer on the ITO, as a buffer, was introduced to iTMC LEECs. Finally, electrical properties including carrier mobility, current density-voltage, light intensity-voltage, response time and turn-on voltages were investigated.

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Role of Atmospheric Purification by Trees in Urban Ecosystem -in the Case of Yongin- (도시생태계 수목의 대기정화 역할 -용인시를 사례료-)

  • 조현길;안태원
    • Journal of the Korean Institute of Landscape Architecture
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    • v.29 no.3
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    • pp.38-45
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    • 2001
  • This study quantified annual $CO_2$, SO$_2$ and NO$_2$ uptake and annual $O_2$ production by trees in Yongin´s urban ecosystem, and explored values of urban tree plantings in atmospheric purification. Woody plant cover was only 7.7% with planting density of 1. trees/100$m^2$, and the tree-age structure was largely characterized by a young, growing tree population. Annual per capita pollutant emissions from fossil fuel consumption were 7.3t/yr for $CO_2$, 7.6kg/yr for SO$_2$, and 26.6kg/yr for NO$_{x}$. Carbon dioxide storage per unit urban area by trees was 13.1t/ha and the economic value for $CO_2$ storage was ₩6.6millions/ha. Annual atmospheric purification was 2.0t/ha/yr for $CO_2$ uptake, 2.0kg/ha/yr for SO$_2$ uptake, 4.0kg/ha/yr for NO$_2$ uptake and 1.5t/ha/yr for $O_2$ production, and the annual economic value for the atmospheric purification was ₩1.5millions/ha/yr. Urbantrees stored an amount of $CO_2$ equivalent to about 3.1% of the total annual $CO_2$ emissions, and annually offset total $CO_2$ emissions by 0.5%. Annual SO$_2$ and NO$_2$ uptake by trees equaled 0.5% of total SO$_2$ emissions and 0.3% of total NO$_{x}$ emissions, respectively. Urban trees also played an important role through producing annually 9.2 of the $O_2$ requirement for Yongin´s total population, despite relatively poor tree plantings. Future active plantings and greenspace enlargement in the study city could enhance the role of atmospheric purification by urban trees. The results from this study are expected to be useful in emphasizing environment benefits of urban trees, and in urging the continuous necessity for tree planting and management budget.get.

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The Features of Asian Dust Events Originated in Manchuria (만주에서 발원한 황사현상 (II) -2001년 이후 사례를 중심으로-)

  • Kim, Sumin;Chun, Youngsin;Kim, Seung-Bum
    • Atmosphere
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    • v.20 no.3
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    • pp.273-286
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    • 2010
  • The northeast part of China(hereafter Manchuria) is one of Asian dust source regions along with Gobi, Inner Mongolia and Loess Plateau. In this study, a geographical survey over the area was carried out to determine its soil characteristics in June 2009. It revealed that some parts of the area, especially near Keerchin desert, consist of alkali clay soil mixed up with sand. Manchuria, where is a vast cornfield, can be a potential source region of Asian dust from fall to following spring after harvesting. The frequency of Asian dust over the region from 1996 to 2009 was examined using 3-hourly GTS SYNOP data and it showed that the occurrence of Asian dust over the region is high in the springtime. It was also revealed that snow cover is the key parameter affecting on the frequency through the analysis of NCEP reanalysis data. To scrutinize the path and structure of Asian dust from Manchuria, the event on 3~4 April 2008 and 25 January 2010 were intensively investigated with regard to features of synoptic weather patterns, satellite imagery, airstream, naked eye-observations, concentrations of PM10, 2.5 and 1.0. For this case, the Asian dust from the area reached to Korea less than a day. However, the duration time of the dust in Korea was short (< 7 hours). The average of hourly PM10 reached up to $340{\mu}g/m^{3}$ at Baengnyeondo during the period. The high PM2.5 and PM1.0 concentrations were also observed at several sites in Korea, indicating that air pollutants could be transported along with the dust.

Evaluation of Chloride Penetration in Concrete with Ground Granulated Blast Furnace Slag considering Fineness and Replacement Ratio (고로슬래그 미분말 콘크리트의 분말도 및 치환율에 따른 염해 저항성 평가)

  • Lee, Hyun-Ho;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.1
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    • pp.26-34
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    • 2013
  • Durability performance in RC structures varies significantly with changes in cover depth and mix proportions. GGBFS (Ground Granulated Blast Furnace Slag) is very effective mineral admixture and widely used for an improved resistance to chloride attack. In this paper, characteristics such as porosity, compressive strength, and diffusion coefficient are evaluated in GGBFS concrete with 30~70% of replacement ratio and $4,000{\sim}8,000cm^2/g$ of fineness. Through the tests, more dense pore structure, higher compressive strength, and lower diffusion coefficient are obtained in GGBFS concrete, which are evaluated to be more dependent on replacement ratio than fineness. With increasing curing period from 3 to 91 days, porosity decreases to 77.47% and strength increases to 373% in GGBFS concrete. Chloride diffusion coefficient in GGBFS concrete decreases to 64.4% compared with that in OPC concrete, which shows significant improvement of durability performance.

The characteristics of DROS magnetometer and MCG measurement (DROS 자력계의 동작특성 및 심자도 측정)

  • Kang, C.S.;Lee, Y.H.;Kwon, H.;Kim, J.M.;Yu, K.K.;Park, Y.K.;Lee, S.G.
    • Progress in Superconductivity
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    • v.8 no.2
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    • pp.164-168
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    • 2007
  • We developed a SQUID magnetometer based on Double Relaxation Oscillation SQUID(DROS) for measuring magnetocardiography(MCG). Since DROS provides a 10 times larger flux-to-voltage transfer coefficient than the conventional DC-SQUID, simple flux-locked loop electronics could be used for SQUID operation. Especially, we adopted an external feedback to eliminate the magnetic coupling with adjacent channels. When the DROS magnetometer was operated inside a magnetically shielded room, average magnetic field noise was about 5 $fT/^{\surd}Hz$ at 100 Hz. Using the DROS magnetometer, we constructed a multichannel MCG system. The system consisted of 61 magnetometers are arranged in a hexagonal structure and measures a vertical magnetic-field component to the chest surface. The distance between adjacent channels is 26 mm and the magnetometers cover a circular area with a diameter of 208 mm. We recorded the MCG signals with this system and confirmed the magnetic field distribution and the myocardinal current distribution.

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Sulfide Mineralization in the Huronian Sediments in the Cobalt Area, Ontario, Canada (캐나다 온타리오주 코발트 지역의 휴로니안 퇴적암에 발달한 황화물 광화작용에 관한 연구)

  • Kim, Won-Sa
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.3 s.49
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    • pp.139-151
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    • 2006
  • Base metal sulfides occur in the Huronian sedimentary rocks that cover the Archean volcanic rocks in the Cobalt area, Ontario, Canada. They are mostly concentrated in the basal conglomerate which was formed in the pre-Huronian basin structure. Sulfide occurrence can be grouped as massive sulfide clasts in the basal and Coleman conglomerate, disseminated sulfides throughout the sediments, and disseminated sulfides near Ag-Co-Ni-As carbonate veins. Detrital mechanism can explain features such as angularity of sulfide fragments and graded bedding of dissemnated sulfides. Sulfides concentrated near carbonate veins are probably of hydrothermal origin. Nearby strata-bound type massive sulfide ore deposits and mineralized interflow units are the most probable sources for syngenetic sulfides. This is supported by the angularity of sulfide fragments, presence of massive sulfide boulders which are identical in mineralogy and texture to the strata-bound type sulfide deposits in the Archean basement, and a similar composition of sphalerite in the Archean volcanic rocks and Huronian sedimentary rocks. Some sulfide grains, especially in sandstones and argillites, were undergone recrystallization during the intrusion of the Nipissing diabase.

An Experimental Study on Evaluation Methods for Scaling Resistance of Cement Concrete Pavement (시멘트 콘크리트 포장의 스케일링 저항성 평가방법에 관한 실험적 연구)

  • Lee, Hyeon-Gi;Oh, Hong-Seob;Sim, Jong-Sung;Shim, Jae-Won
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.3
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    • pp.30-38
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    • 2015
  • In cold-climate regions, deicing agents is used for smooth traffic on the road due to freezing and snowdrift in winter. The use of de-icing salts has resulted in the accelerated scaling damage of concrete with salt damage under freezing and thawing condition. Scaling is the deterioration of concrete where in the paste-mortar structure delaminates in flakes from the surface of the concrete. Due to such damage, concrete pavement causes various problems such as early deterioration according to the decrease in the thickness of cover concrete and user's stability issues. Accordingly, various tests and evaluation methods have been suggested in order to evaluate these phenomena in other countries. However, there have been no regulations for the evaluation method in South Korea, and related studies are also very rare. Therefore, in this study, the evaluation methods proposed by each institution and country were investigated and the experiments were performed according to each regulation, followed by the comparison and analysis of the results. Furthermore, this study aims to suggest the optimized experimental method adopted to domestic field through the discussion of such experimental methods and results.

An International Comparative Study of Upper Secondary Home Economics Education -Curriculum Analaysis Approach- (고등학교 가정과 교육의 국제비교연구 -교육과정을 중심으로-)

  • 윤인경
    • Journal of Korean Home Economics Education Association
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    • v.1 no.1
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    • pp.33-42
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    • 1989
  • By the comparative analysis of high school Home Economics curricula in the U.S., Japan and Taiwan, this study first attempts to understand the current Home Economics education and to access its treads for each country. Based on the findings of the analysis, the study also seeks to get the major implications of the analysis for the betterment of the Korea Home Economics Education. The main sources of information and data analyzed here are: 1) curricula for both Oklahoma and Ohio state as representatives of the U.S.; 2) Home Economics Teaching Guidelines in Japan; and 3) Home Economics curriculum in Taiwan. Content Analysis technique is applied in this study. The major elements of contents include:1) structure of the curriculum; 2) subject name; 3) unit (time) allotment; 4) goals; 5) subject areas and content composition; and 6) other related characteristics for the implementation of the curriculum. Summarized results of the study outline as follows: 1) Home Economics is offered as independently required subject with equal status to Mathematics, Science, and Social Studies subject in all three countries; 2) Sex discrimination is prohibited both in the U.S. and Taiwan, while in Japan sex equity is not secured for Home Economics educations; 3) Time allotment for Home Economics in Japan and Taiwan is similiar to that in Korea;4) Subject areas cover such fields as Foods and Nutrition, Clothing and Textiles, Home Management, and Human Development in all three countries, which is similiar to those of Korea. In addition, Consumer Education and Career Education are also covered in the U.S., whereas in Japan Child Care is offered; and 5) Curriculum can be utilized as instructional planning material due to the clear specification of instructional methods, materials, and evaluation methods on the curriculum, especially in the U.S. and Taiwan.

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An Experimental Study on Principal Factors for Non-destructive Test of Detecting Steel bars (비파괴 철근탐사의 주요 영향인자에 관한 실험적 연구)

  • Oh, Kwang Chin;Kim, Jong Ho;Rhee, Jong Woo;Lee, Yun Hyang
    • Journal of Korean Society of societal Security
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    • v.3 no.1
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    • pp.25-32
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    • 2010
  • Detecting rebars in side the concrete structures is one of the important steps in assessing condition of the structure. In order to determine the detection capability of locating rebars inside the concrete, two types of equipments, which use radar system and electromagnetic system each, were tested. Four concrete specimens which have the dimensions of $1,000mm(length){\times}300mm(width)$ with different thickness and diameter of steel bars were applied. A series of testing was achieved after drying in air for 90 days, immersed in water for 3, 24, 48 hour and 28 day. From the experimental outcome, it is shown that error is increased as the diameter of rebar enlarge in case of electromagnetic method. In case of radar method, the detection of embedded rebars in deep is good in the view of reliability. As moisture content increase from 3.6% to 5.5%, the relative permittivity of concrete test specimens show tendency to increase, too. Therefore, it is shown that moisture content is one of the major contributing factors to determine the relative permittivity. And the relative permittivity regression equation is suggested.

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Carbonation Analysis of Bridge Structures in Urban Area Based on the Results of the Field Test (현장실험결과를 활용한 국내 도심지 교량구조물의 탄산화 해석)

  • Kim, Hun-Kyom;Kim, Sung-Bo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.4
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    • pp.111-118
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    • 2010
  • Reinforced steel corrosion due to concrete carbonation is one of main factors on the durability of RC structure. The carbonation velocity have an effect on carbon dioxide density, concrete quality and structural shape. Specially, these problems have increased in urban area. This study investigates the carbonation status of the bridges and quantifies the effect of carbonation based on various domestic field data. The failure probability of durability is evaluated on the basis of reliability concept. According to experimental results of the carbonation depth, the carbonation depth increased with structural age and carbonation velocity decreased with high strength of concrete. In most cases, the failure probability of durability by carbonation was more than 10%. Also, The results requires the minimum cover thickness of 70-80mm for target safety index(${\beta}$=1.3) proposed by Korean concrete specification.