• Structural Engineering and Mechanics
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• 제43권2호
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• pp.211-223
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• 2012

This paper deals with large deformation post-buckling of a linear-elastic and hygrothermal beam with axially nonmovable pinned-pinned ends and subjected to a significant increase in swelling by an alternative method. Analytical approximate solutions for the geometrically nonlinear problem are presented. The solution for the limiting case of a string is also obtained. By coupling of the well-known Maclaurin series expansion and orthogonal Chebyshev polynomials, the governing differential equation with sinusoidal nonlinearity can be reduced to form a cubic-nonlinear equation, and supplementary condition with cosinoidal nonlinearity can also be simplified to be a polynomial integral equation. Analytical approximations to the resulting boundary condition problem are established by combining the Newton's method with the method of harmonic balance. Two approximate formulae for load along axis, potential strain for free hygrothermal expansion and periodic solution are established for small as well as large angle of rotation at the end of the beam. Illustrative examples are selected and compared to "reference" solution obtained by the shooting method to substantiate the accuracy and correctness of the approximate analytical approach.

• 한국반도체및디스플레이장비학회:학술대회논문집
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• 한국반도체및디스플레이장비학회 2002년도 추계학술대회 발표 논문집
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• pp.123-126
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• 2002

For the mold die sticking mechanism, the major explanation is that EMC filler of silica wears die surface roughened, which results in increase of adhesion strength. As big differences in experimental results from semiconductor manufacturers are dependent on EMC models, however, chemisorptions or acid-base interaction is apt to be also functioning as major mechanisms. In this investigation, the plasma source ion implantation (PSII) using $O_2$, $N_2$, and $CF_4$ modifies sample surface to form a new dense layer and improve surface hardness, and change metal surface condition from hydrophilic to hydrophobic and vice versa. Through surface energy quantification by measuring contact angle and surface ion coupling state analysis by Auger, major governing mechanism for sticking issue was figured out to be a complex of mechanical and chemical factors.

• 마이크로전자및패키징학회지
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• 제9권4호
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• pp.31-34
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• 2002

For the mold die sticking mechanism, the major explanation is that the silica as a filler in EMC (epoxy molding compound) wears die surface to be roughened, which results in increase of adhesion strength. As the sticking behavior, however, showed strong dependency on the EMC models based on the experimental results from different semiconductor manufacturers, chemisorption or acid-base interaction is apt to be also functioning as major mechanisms. In this investigation, the plasma source ion implantation (PSII) using $O_2, N_2$, and $CF_4$ modifies sample surface to form a new dense layer and improve surface hardness, and change metal surface condition from hydrophilic to hydrophobic or vice versa. Through surface energy quantification by measuring contact angle and surface ion coupling state analysis by Auger, major governing mechanism for sticking issue was figured out to be a complex of mechanical and chemical factors.

• BMB Reports
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• 제31권2호
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• pp.149-155
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• 1998

The N199H variant of the EcoRI endonuclease has about twice the catalytic activity of the wild-type. A comparison of their biochemical characteristics, using synthetic oligonucleotides 5'-dAAAACTTAAGAAAAAAAAAAA-3' (KA) and 5'-dTTTTTGAATTCTTTTTTTTTT-3' (KT), helps to define the cleavage reaction pathway of these enzymes. Both EcoRI and EcoRI variant N199H were found to cleave singlestranded KA or KT about three times faster than the double-stranded forms, although the KT oligonucleotide was more susceptible. Using the ssDNA substrate in kinetic analyses, lower $K_m$ values were obtained for the N199H variant than for the wild-type at low (50 mM), as well as high (200 mM), sodium chloride concentrations. This difference between the endonucleases is attributed to a grealter accessibility for tbe substrate by the variant, and also a higher affinity for the DNA backbone. It also appears that the relative activities of the two enzymes, particularly at high ionic strength, are proportional to their populations in the monomeric enzyme form. That is, according to gel filtration data, half of the N199H molecules exist as monomers in 200 mM NaCl, whereas those of the wild-type are mainly dimeric. Consequently, the Asp199 residue of the EcoRI endonuclease may be implicated in the protein-protein interaction leading to dimerization, as well as in coupling to DNA substrates. In summary, it is proposed that active monomeric endonuclease molecules, derived from the dimeric enzyme, recognize and form a complex with a single stranded form of the DNA substrate, which then undergoes nucleophilic substitution and cleavage.

• Bulletin of the Korean Chemical Society
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• 제19권6호
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• pp.654-660
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• 1998

$[Fe^{II}Fe^{III}BPLMP(OAc)_2](BPh_4)_2$ (1), a new model for the reduced form of the purple acid phosphatases, has been synthesized by using a dinucleating ligand, 2,6-bis[((2-pyridylmethyl)(6-methyl-2-pyridylmethyl)amino) methyl]-4-methylphenol (HBPLMP). Complex I has been characterized by X-ray diffraction method as having (μ-phenoxo)bis(acetato)diiron core. Complex 1 was crystallized in the monoclinic space group C2/c with the following cell parameters: a=41.620(6) Å, b=14.020(3) Å, c=27.007(4) Å, β=90.60(2)°, and Z=8. The iron centers in the complex 1 are ordered as indicated by the difference in the Fe-O bond lengths which match well with typical $Fe^{III}-O\; and\; Fe^{II}-O$ bond lengths. Complex 1 has been studied by electronic spectral, NMR, EPR, SQUID, and electochemical methods. Complex 1 exhibits strong bands at 592 nm, 1380 nm in $CH_3CN$ (ε = 1.0 × 103 , 3.0 × 102). These are assigned to $phenolate-to-Fe^{III}$ and intervalence charge-transfer transitions, respectively. Its NMR spectrum exhibits sharp isotropically shifted resonances, which number half of those expected for a valence-trapped species, indicating that electron transfer between $Fe^{II}\;and\;Fe^{III}$ centers is faster than NMR time scale. This complex undergoes quasireversible one-electron redox processes. The $Fe^{III}_2/Fe^{II}Fe^{III}\;and\;Fe^{II}Fe^{III}/Fe^{II}_2$ redox couples are at 0.655 and -0.085 V vs SCE, respectively. It has $K_{comp}=3.3{\times}10^{12}$ representing that BPLMP/bis(acetate) ligand combination stabilizes a mixed-valence $Fe^{II}Fe^{III}$ complex in the air. Complex 1 exhibits a broad EPR signal centered near g=1.55 which is a characteristic feature of the antiferromagnetically coupled high-spin $Fe^{II}Fe^{III}$ system $(S_{total}=1/2)$. This is consistent with the magnetic susceptibility study showing the weak antiferromagnetic coupling $(J= - 4.6\;cm^{-1},\; H= - 2JS_1{\cdot}S2)$ between $Fe^{II}\; and \;Fe^{III}$center.

• 대한전기학회논문지
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• 제41권5호
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• pp.517-524
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• 1992

In this study, 0.10Pb(SbS11/2TSnS11/2T)OS13T-(0.90-x)PbZrOS13T (0.25 x 0.40) ceramics were fabricated by the atmospheric method. The sintering temperature and time were 1250[$^{\circ}C$] and 2[2hr], respectively. The structureal, dielectric and piezoelectric properties with composition of PbTiOS13T were studied. As the results of XRD ans SEM, the crystal structure of a specimen was rhombohedral, lattice constant and average grain size were decreased with increasing the contents of PbTiOS13T. Relative dielectric constant and Curie temperature were increased with increasing the contents of PbTiOS13T, 0.10PSS-0.40PT-0.50PZ specimen had the highest values of 904 and 265[$^{\circ}C$], respectively. In increasing of PbTiOS13T contents form 25[mol%] to 40[mol%], piezoelectric charge constant and electromechanical coupling factors were increased form 114[pC/N] to 142[pC/N], 17[%] to 24[%] and mechanical quality factor were decreased with increasing the contents of PbTiOS13T. In the 0.10PSS-0.40PT-0.50PZ specimens, those values were 14.2[kV/cm] and 9.43[x10S0-6TC/cmS02T], resectively.

• Advances in materials Research
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• 제6권1호
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• pp.45-63
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• 2017

In this article, static deflection and buckling of functionally graded (FG) nanoscale beams made of porous material are carried out based on the nonlocal Timoshenko beam model which captures the small scale influences. The exact position of neutral axis is fixed, to eliminate the stretching and bending coupling due to the unsymmetrical material change along the FG nanobeams thickness. The material properties of FG beam are graded through the thickness on the basis of the power-law form, which is modified to approximate the material properties with two models of porosity phases. By employing Hamilton's principle, the nonlocal governing equations of FG nanobeams are obtained and solved analytically for simply-supported boundary conditions via the Navier-type procedure. Numerical results for deflection and buckling of FG nanoscale beams are presented and validated with those existing in the literature. The influences of small scale parameter, power law index, porosity distribution and slenderness ratio on the static and stability responses of the FG nanobeams are all explored.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2007년도 춘계학술대회논문집
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• pp.46-50
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• 2007

The nuclear power plant's turbine-generator system had been suffered form some problems, such as high shaft vibration, generator casing crack, stator coil water leakage, high $H_2$ gas consumption rate. Those kinds of problems were related to high vibration. So nuclear plant decided to replace generator in order to reduce rotor high vibration and high thermal sensitivity. A series of effort to reduce turbine-generator vibration was carried out as followings, first of all, replacement of generator, analysis of turbine-generator vibration, LP B rotor shop balancing, improvement of LP B/Gen coupling run-out, improvement of Generator basement and field balancing. Finally the nuclear turbine-generator's shaft vibration was reduced below $60{\mu}m$ from over $200{\mu}m$ which is very excellent vibration in nuclear turbine-generator in Korea.

• 한국연소학회지
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• 제6권2호
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• pp.15-22
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• 2001

A pressure-based, unstructured finite volume method has been applied to couple the chemical kinetics and fluid dynamics and to capture effectively and accurately the steep gradient flame field. The pressure-velocity coupling is handled by two methodologies including the pressure-correction algorithm and the projection scheme. A stiff, operator-split projection scheme for the detailed nonequilibrium chemistry has been employed to treat the stiff reaction source terms. The conservative form of the governing equations are integrated over a cell-centered control volume with collocated storage for all transport variables. Computations using detailed chemistry and variable transport properties were performed for two laminar reacting flows: a counterflow hydrogen-air diffusion flame and a lifted methane-air triple flame. Numerical results favorably agree with measurements in terms of the detailed flame structure.

• 한국군사과학기술학회지
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• 제2권1호
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• pp.110-120
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• 1999

본 논문은 흡습환경에서 온도변화를 겪는 무한히 긴 속빈 실린더의 시간변화에 따른 흡습열 응력 변화에 관해서 연구한 것이다. 평면변형률 가정에 기초한 흡습열탄성론의 방정식이 열과 습기 사이의 연성효과를 고려하여 수립되었다. 시간경과에 따른 흡습열 응력을 구하기 위한 완전한 형태의 해가 연성분리기법과 변수분리방법을 이용하여 구하였으며, 온도와 습도 집중치의 분포를 포함한 수치적인 적용 예에 대한 결과를 분석하였다. 시간경과에 따른 흡습열 특성이 직교이방성 속빈원통벽에서 변위와 응력의 변화 및 분포에 미치는 영향을 함께 제시하였다.